Synthesis and Mesophse Study on a Triphenylene-Based Polysiloxane

Chun Xiu Zhang; Jia Ling Pu; Hao Wu; Ao Zhang; Ming Xia Zhang; Gui Sen Fang

doi:10.4028/www.scientific.net/SSP.181-182.139

Paper Titles

Synthesis and Mesophase Properties of a Series of Chiral Rod-Like Polysiloxanes
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Synthesis of Conjugated Polythiophenes with Azobenzene Substitutes in the Side Chains
p.127

Synthesis and Property of Liquid Crystal Polymers Containing Photosensitive Groups
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Synthesis and Characterizations of a Rod-Like Liquid Crystal TBO16A
p.135

Synthesis and Mesophse Study on a Triphenylene-Based Polysiloxane
p.139

Synthesis and Characterization of Schiff’s Base Compounds with Octadecylaniline as End Group
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Hexabenzocoronene with Swallow-Tailed Substitutes: Synthesis, Characterization and Properties
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Thermal and Optical Properties of Main Chain Polymer Compose of Oligo-L-LA Segments and Biphenol Group
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Synthesis and Mesophases Study on 2-(8-bromooctanoic acid ester)-3,6,7,10,11-penta-pentyloxytriphenylene
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Synthesis and Mesophse Study on a Triphenylene-Based Polysiloxane

Abstract:

A side chain triphenylene-based polysiloxane were synthesized from 2-hydroxy-3-Methoxy-6,7,10,11–tetrapentyloxy-triphenylene.2-hydroxy-3-Methoxy-6,7,10,11–tetrapentyloxy triphenylene was synthesized via the common synthisis route including the Williamson Etherification of catechol, the iodination of 1,2-dipentyloxybenzene, the Ullman Coupling and the coupling of 3,3'-4,4'–tetrapentyloxy diphenyl and methoxy-phenol; 2-allyloxyl-3-Methoxy-6, 7, 10, 11–tetrapentyloxytriphenylene was synthesized by the etherification of 2-hydroxy-3-Methoxy-6,7,10, 11–tetrapentyloxytriphenylene and allyl bromide; the polysiloxane was synthesized by addition of 2-allyloxyl-3-Methoxy-6,7,10,11–tetrapentyloxytriphenylene and polydimethylsiloxane. The structures of the compounds were determined by FTIR and 1HNMR. Mesophase and their structural orders were determined using a polarized optical microscope and a differential scanning calorimeter.

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Solid State Phenomena (Volumes 181-182)

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139-142

DOI:

https://doi.org/10.4028/www.scientific.net/SSP.181-182.139

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Online since:

November 2011

Authors:

Chun Xiu Zhang, Jia Ling Pu, Hao Wu, Ao Zhang, Ming Xia Zhang, Gui Sen Fang

Keywords:

DSC Calorimetry, Mesophase, POM Picture, Triphenylene

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