Infrared and X-Ray Absorption Spectra of Cu2O and CuO Nanoceramics

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Abstract:

We present the results of the study of middle infrared absorption (MIR) and X-ray absorption (XAS) spectra of nanostructured CuO and Cu2O ceramics prepared by the high pressure torsion method from coarse-grain oxide powders. We have found that the MIR bands at ~140 meV in CuO and Cu2O nanoceramics are associated with the presence of Cu+ and Cu2+ ions, respectively. X-ray absorption spectra indicate an appearance of extra Cu2+ and Cu+ ions in nanoCu2O and nanoCuO ceramics, respectively.

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Solid State Phenomena (Volume 190)

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683-686

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June 2012

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© 2012 Trans Tech Publications Ltd. All Rights Reserved

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