Electrical and Dielectrical Propeties of Gas-Sensor Resistive Type Bi2Sn2O7

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Abstract:

Polycrystalline samples of Bi2Sn2O7 have been synthesized by conventional solid-state reaction method. According to the X-ray powder diffraction research, our sample co-existing of two polymorphs phases: cubic and rhombic, concurrently. The real dielectric permeability Re (ε) monotonic grows versus temperature and the imaginary dielectric permeability Im (ε) nonmonotonic is increased at the heating. There are maxima at Т=450 K on both temperature dependences Im (ε) and Re (ε) reveal. Anomalies in the temperature dependence of electrical resistivity at temperatures are found and to be correlated with the α→ β structural phase transition temperature.

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Solid State Phenomena (Volume 215)

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503-506

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April 2014

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© 2014 Trans Tech Publications Ltd. All Rights Reserved

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[1] C.A. Mims, A.J. Jacobson, R.B. Hall, J.T. Levandowski, J. Catalysis 153 (1995) 197.

Google Scholar

[2] L. Moens,P. Ruiz, B. Delmon, M. Devillers, Catalysis Lett. 46 (1997) 93.

Google Scholar

[3] G.S.V. Coles, S.E. Bond, G. Williams, J. Mat. Chem. 4 (1994) 23.

Google Scholar

[4] G. S. Devi, S. V. Manorama, V. J. Rao, J. Electrochemical Soc. 145 (1998) 1039.

Google Scholar

[5] Shannon, R.D., Beirlein, J.D., Gillson, J.L., et al. J. Phys. Chem. Solids 41 (1980) 117–122.

Google Scholar

[6] Roth, R.S., J. Res. Natl. Bur. Stand. 56 (1956) 17–25.

Google Scholar

[7] Levin, E.M. and Roth, R.S., J. Res. Natl. Bur. Stand., Sect. A 68 (1964) 197–206.

Google Scholar

[8] Vetter, G., Queyroux, F., and Gilles, J. -C., Mater. Res. Bull. 13 (1978) 211- 216.

Google Scholar

[9] Brisse, F. and Knop, O., Can. J. Chem. 46 (1968) 859–873.

Google Scholar

[10] Aron Walsh and Graeme W. Watson. Chem. Mater. 19 (2007) 5158-5164.

Google Scholar

[11] I.R. Evans, J.A.K. Howard, J.S.O. Evans J. Mater. Chem. 13 (2003) 2098–2103.

Google Scholar

[12] B.J. Kennedy, Ismunandar, M.M. Elcombe, Mater. Sci. Forum 278 (1998) 762.

Google Scholar

[13] A. Salamat, A.L. Hector, P.F. McMillan, C. Ritter, Inorg. Chem. 50 (2011) 11905.

Google Scholar

[14] R.X. Silva, C.W.A. Paschoal, R.M. Almeida, M. Carvalho Castro Jr., A.P. Ayala, Jeffrey T. Auletta, Michael W. Lufaso. Vibrational Spectroscopy 64 (2013) 172– 177.

DOI: 10.1016/j.vibspec.2012.05.009

Google Scholar