Hydrogen Diffusion Characteristics in the TRIP 800 C-Mn-Si Steel

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The presented paper is devoted to the study of hydrogen diffusion characteristics in the C-Mn-Si TRIP 800 steel. The steel was tested in three different states: in as-received state after hot and cold rolling and subsequent heat treatment; and furthermore after 5% and 10% tensile deformation. Hydrogen diffusion characteristics were studied by means of electrochemical permeation method. Two build up transients corresponding to lower and higher charging current densities as well as a decay transient were recorded during experiment. The lowest values of hydrogen diffusion coefficient (from 1 to 3.5.10-7 cm2.s-1) were observed during the first build up transient; the value of 3.5.10-7 cm2.s-1 corresponded to 10% tensile deformation. During the 2nd build up transient corresponding to the higher charging current density, hydrogen diffusion coefficients increased markedly reflecting thus the fact that hydrogen trapping was less pronounced. For decay transients hydrogen diffusion coefficients were situated between values obtained for the 1st and 2nd build up transients. In all studied states, a rather high sub-surface hydrogen concentration was observed during the 1st build up transient rising to 12.6 ppm of hydrogen in as-received state. The obtained results are explained taking into account steel microstructure and hydrogen trapping.

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Solid State Phenomena (Volume 227)

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259-262

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January 2015

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© 2015 Trans Tech Publications Ltd. All Rights Reserved

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[1] B. C. De Cooman, Structure-properties relationship in TRIP steels containing carbide-free bainite. Curr. Opin. Solid St. M. 8 (2004) 285-303.

DOI: 10.1016/j.cossms.2004.10.002

Google Scholar

[2] J. Sojka, V. Vodárek, I. Schindler, C. Ly, M. Jerome, P. Váňová, N. Ruscassier, A. Wenglorzová, Effect of hydrogen on the properties and fracture characteristics of TRIP 800 steels, Corros. Sci. 53 (2011) 2575-2581.

DOI: 10.1016/j.corsci.2011.04.015

Google Scholar

[3] C. Ly, Caractérisation d´aciers à très haute limite d´élasticité vis-à-vis de la fragilisation par l´hydrogène. Ph. D. Thesis. Ecole Centrale Paris, France, (2009).

Google Scholar

[4] S.J. Kim, D.W. Yun, D.W. Suh, K.Y. Kim, Electrochemical hydrogen permeation through TRIP steel under loading condition of phase transition, Electrochem. Commun. 24 (2012) 112-115.

DOI: 10.1016/j.elecom.2012.09.002

Google Scholar

[5] T. Zakroczymski, Adaptation of the electrochemical permeation technique for studying entry, transport and trapping of hydrogen in metals, Electrochim. Acta 51 (2006) 2261-2266.

DOI: 10.1016/j.electacta.2005.02.151

Google Scholar