Electrochemical Properties of cpTi with Modified Surface Used for Implants in Blood and Vascular System

Article Preview

Abstract:

In their works the authors presented results of tests conducted for titanium Grade4 after its surface modification with the application of anodic oxidation and sol-gel (SiO2 layer) methods. In order to verify the usefulness of the obtained surface layers potentiodynamic and impedance tests have been carried out. They have been conducted with the use of measurement set equipped with the POSTAT 302n potentiostat with the FRA2 attachment for impedance tests. Measurements have been taken in an environment simulating human blood – artificial serum having temperature of T = 37 degrees Centigrade. To identify phenomenon occurring at phases border samples have been subjected to 28-day exposition in the artificial serum. It has been found that in the case of anodic oxidation the value of voltage of 100 V has an advantageous influence on electrochemical properties of modified surfaces. On the other hand, in the case of the sol-gel method thin layer of SiO2 baked at temperature T = 430 degrees Centigrade has been characterised by the most advantageous set of electrochemical properties. The knowledge of proper parameters of creating of surface layers has direct influence on the product quality and thus, appropriate course of patient therapy process.

You might also be interested in these eBooks

Info:

Periodical:

Solid State Phenomena (Volume 227)

Pages:

487-490

Citation:

Online since:

January 2015

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2015 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] S. Areva, V. Aaritalo, S. Tuusa, M. Jokinen M, M. Linden, T. Peltola, Sol-Gel-derived TiO2–SiO2 implant coatings for direct tissue attachment, Part I & II: design, preparation and characterization. J. Mater. Sci. Mater. Med. 18 (2007) 1633-1642.

DOI: 10.1007/s10856-007-3064-z

Google Scholar

[2] B. Surowska, J. Bienias, M. Walczak, K. Sangwal, Microstructure and mechanical properties of ceramic coatings on Ti and Ti-based alloy. Appl. Surf. Sci. 238 (2004) 288-294.

DOI: 10.1016/j.apsusc.2004.05.219

Google Scholar

[3] N. Huang, P. Yang, Y. Leng, J. Chen, H. Sun, J. Wang. et al, Hemocompatibility of titanium oxide films, Biomater. 24 (2003) 2177-2187.

DOI: 10.1016/s0142-9612(03)00046-2

Google Scholar

[4] J. Li, T. Shinke, L. Pendyala, S. Geva, J. Chen, X. Yin, A. Venegoni, N. Chronos, K. Robinson, Novel thin-strut, bioabsorbable sol-gel coated, low-dose paclitaxel-eluting stent: evaluation in porcine coronary arteries, Cardiovasc. Revasculariz. Medic. 10(3) (2008).

DOI: 10.1016/j.carrev.2009.04.025

Google Scholar

[5] D. Grygier, W. Dudziński, T. Wiktorczyk, K. Haimann, Effect of silica precursors-type on mechanical properties of sol-gel coatings, Acta Bioeng. Biomech. 10(1) (2008) 21-29.

Google Scholar

[6] F. Chai,A. Ochsenbein, M. Traisne, R. Busch, J. Breme, H. Hildebrand, Improving endothelial cell adhesion and proliferation on titanium by sol-gel derived oxide coating, J. Biomed. Mater. 92 (2010) 754-765.

DOI: 10.1002/jbm.a.32399

Google Scholar

[7] J. Szewczenko, J. Jaglarz, M. Basiaga, J. Kurzyk, Z. Paszenda, Optical methods applied in thickness and topography testing of passive layers on implantable titanium alloys, Opt. Appl. 43 (2013) 173-180.

Google Scholar

[8] M. Basiaga, W. Walke, Z. Paszenda, P. Karasiński, Research on electrochemical properties SiO2 layer, intended for contact with blood, deposited by sol-gel method. Europ. Cells Mater. 26 (2013) 157.

Google Scholar

[9] ASTM F2129 – Electrochemical Corrosion Testing of Surgical Implants (Standard Test Methodfor Conducting Cyclic Potentiodynamic Polarization Measurementsto Determine the Corrosion Susceptibility of Small Implant Devices).

DOI: 10.1520/f2129

Google Scholar

[10] W. Kajzer, A. Kajzer, Potentiodynamic and EIS studies of plates used in  treatment of anterior surface deformity of chest. Przegl. Elektrotech. 12 (2013) 275-279.

Google Scholar

[11] N. Ibris, J.C.M. Rosca: EIS study of Ti and its alloys in biological media, J. Electroanal. Chem. 526 (2002) 53-62.

Google Scholar