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Chemical Interaction of Phosphates M^II₂P₄O₁₂with Melted M^ICl or M^INO₃(M^I – Li, Na, K; M^II – Mg, Co, Ni, Zn)
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HomeSolid State PhenomenaSolid State Phenomena Vol. 230Chemical Interaction of Phosphates MII2P4O12 with...

Chemical Interaction of Phosphates M^II₂P₄O₁₂with Melted M^ICl or M^INO₃(M^I – Li, Na, K; M^II – Mg, Co, Ni, Zn)

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Abstract:

The interaction in the systems M^II₂P₄O₁₂-M^ICl (M^INO₃) (M^I – Li, Na, K; M^II – Mg, Co, Ni, Zn) was investigated in temperature range 1073-673 K. The conditions of formation phosphates: Li₃PO₄, M^IM^IIPO₄ (M^I – Na, K), Na₄M^II₃(PO₄)₂P₂O₇, Na₉Co₃(PO₄)₅ have been established. Obtained crystalline phases have been investigated using X-ray powder diffraction, Diffuse reflectance, Raman and FTIR spectroscopy and scanning electron microscopy methods.

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Periodical:

Solid State Phenomena (Volume 230)

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297-302

DOI:

https://doi.org/10.4028/www.scientific.net/SSP.230.297

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Online since:

June 2015

Authors:

Oksana V. Livitska, Nataliya Yu. Strutynska, Igor V. Zatovsky, Nikolay S. Slobodyanik

Keywords:

Complex Phosphates, Diffuse Reflectance Spectra, FTIR Spectroscopy, RAMAN, Salt Melts

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