The Influence of Pyrite on Galvanic Assisted Bioleaching of Low Grade Chalcopyrite Ores

Article Preview

Abstract:

The experiment focused on the effect of pyrite on the dissolution of the ore from Saindak copper mine in Pakistan. The MLA results showed that the ore mainly consisted of chalcopyrite, which was associated closely with pyrite. The bioleaching process and galvanic promotion experiments of pyrite on the copper extraction were investigated. The data revealed that copper recovery rate could be up to 97.8% after the bioleaching process by extreme thermophilic acidophilic organisms for 30 days at 65 OC. The temperature and redox potential were the controlled factors to recover copper from the Saindak mineral. The phylogenetic analyses of 16S rRNA gene fragments revealed that organisms related to Metallosphaera cuprina strain Ar-4 and Sulfolobus sp. HB59 were most dominant. Pyrite could accelerate the dissolution of chalcopyrite as one galvanic assistant substance, which would be strengthened by elevating the temperature or in the presence of microorganisms.

You might also be interested in these eBooks

Info:

Periodical:

Solid State Phenomena (Volume 262)

Pages:

93-98

Citation:

Online since:

August 2017

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2017 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] Y. Li, N. Kawashima, J. Li, A. P Chandra, A.R. Gerson, A review of the structure and fundamental mechanisms and kinetics of the leaching of chalcopyrite, Adv. Coll. Interf. Sci. 197–198 (2013) 1–32.

DOI: 10.1016/j.cis.2013.03.004

Google Scholar

[2] N. Hiroyoshi, M. Arai, H. Miki, M. Tsunekawa, T. Hirajima, A new reaction model for the catalytic effect of silver ions on chalcopyrite leaching in sulfuric acid solutions, Hydrometallurgy. 63 (2002) 257–267.

DOI: 10.1016/s0304-386x(01)00228-6

Google Scholar

[3] A. Ahmadi, M. Schaffie, J. Petersen, A. Schippers, M. Ranjbar, Conventional and electrochemical bioleaching of chalcopyrite concentrates by moderately thermophilic bacteria at high pulp density, Hydrometallurgy. 106 (2011) 84–92.

DOI: 10.1016/j.hydromet.2010.12.007

Google Scholar

[4] M. Khoshkhoo, M. Dopson, A. Shchukarev, A. Sandström, Electrochemical simulation of redox potential development in bioleaching of a pyritic chalcopyrite concentrate, Hydrometallurgy, 144–145(2014)7–14.

DOI: 10.1016/j.hydromet.2013.12.003

Google Scholar

[5] J. Bai, J.K. Wen, S.T. Huang, B. Wu, The bioleaching characteristics of chalcopyrite with different genetic types, Adv. Mat. Res. 825 (2013) 443–446.

DOI: 10.4028/www.scientific.net/amr.825.443

Google Scholar

[6] R.M. Ruan, X.Y. Liu, J.H. Chen, J.K. Wen, Industrial practice of a distinct bioleaching system operated at low pH, high ferric concentration, elevated temperature and low redox potential for secondary copper sulfide, Hydrometallurgy. 108 (2011).

DOI: 10.1016/j.hydromet.2011.03.008

Google Scholar

[7] X.Y. Liu, B.W. Chen, R.M. Ruan, J.K. Wen, Leptospirillum forms a minor portion of the population in Zijinshan commercial non-aeration copper bioleaching heap identified by 16S rRNA clone libraries and real-time PCR, Hydrometallurgy. 104 (2010).

DOI: 10.1016/j.hydromet.2010.03.024

Google Scholar

[8] J. Petersen, D.G. Dixon, Competitive bioleaching of pyrite and chalcopyrite, Hydrometallurgy. 83 (2006) 40–49.

DOI: 10.1016/j.hydromet.2006.03.036

Google Scholar

[9] J. Vilcáez, K. Suto, C. Inoue, Bioleaching of chalcopyrite with thermophiles: Temperature –pH–ORP dependence, Int. J. Miner. Process. 88 (2008) 37–44.

DOI: 10.1016/j.minpro.2008.06.002

Google Scholar

[10] J.A. Rojas-Chapana, H. Tributsch, Biochemistry of sulfur extraction in bio-corrosion of pyrite by Thiobacillus ferrooxidans, Hydrometallurgy. 59 (2001) 291–300.

DOI: 10.1016/s0304-386x(00)00185-7

Google Scholar