Studies on Tensile Properties of Compatibilized and Uncompatibilized Low-Density Polyethylene/Jackfruit Seed Flour (LDPE/JFSF) Blends at Different JFSF Content

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Abstract:

Currently, natural fillers seem to be the suitable materials in polymer industry, which have emerged as a viable and abundant replacement for the relatively high-cost and non-renewable conventional fillers. However, the direct introduction of natural fillers into polymer matrix could effect negatively on some properties. Therefore, the aim of this work is to evaluate the influence of jackfruit seed flour (JFSF) (before and after compatibilization) on the tensile properties of (LDPE/JFSF) blends. Different JFSF content (5, 10, 15 and 20 wt.%) with (63-100 𝜇𝑚) particle size were prepared in this work. Twin-screw extruder at 150°C and 50rpm screw speed followed by hot-compress machine at 150°C and 10MPa pressure were used respectively to produce (LDPE/JFSF) blends. Adipic acid (AA) solution was added as a compatibilizer into all blends equally (25wt% AA into 75wt% JFSf). The changes of tensile and morphological properties were investigated. Results shown decreasing on tensile strength and elongation at break of LDPE/JFSF and LDPE/JFSF/AA as JFSF increased. In contrast, Young’s modulus increased up to 10 wt.% of JFSF and then decreased. However, the addition of Adipic acid, particularly for JFSF 5wt.% has improved the tensile properties of LDPE/JFSF blends. The SEM micrographs showed the agglomeration at high JFSF content (20 wt%) which in turn effected negatively on the tensile properties. However, the blends show homogeneous surfaces as AA added.

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Solid State Phenomena (Volume 264)

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120-123

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September 2017

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© 2017 Trans Tech Publications Ltd. All Rights Reserved

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[1] I. Kyrikou, D. Briassoulis. Biodegradation of agricultural plastic films: a critical review. J. Polym. Environ. 15 (2007) 125-150.

DOI: 10.1007/s10924-007-0053-8

Google Scholar

[2] K. Balaed, N.Z. Noriman, O.S. Dahham, S.T. Sam, R. Hamzah, M.F. Omar. Characterization and properties of low-linear-density polyethylene/Typha latifolia composites. Int. J. Polym. Anal. Charact (2016) 1-9.

DOI: 10.1080/1023666x.2016.1183336

Google Scholar

[3] T. Theivasanthi, M. Alagar. An insight analysis of nano sized powder of jackfruit seed. " arXiv preprint arXiv 1110 (2011).

DOI: 10.5101/nbe.v3i3.p163-168

Google Scholar

[4] D. Bikiaris, J. Prinos, K. Koutsopoulos, N. Vouroutzis, E. Pavlidou, N. Frangis, C. Panayiotou. LDPE/plasticized starch blends containing PE-g-MA copolymer as compatibilizer. Polym. Degrad. Stab. 59 (1998) 287-291.

DOI: 10.1016/s0141-3910(97)00126-2

Google Scholar

[5] O.S. Dahham, N.Z. Noriman, K. Husin, S.T. Sam, M.F. Omar, A.M. Mustafa Al Bakri, R. H. Rosniza. The Effects of Trans-Polyoctylene Rubber (TOR) on the Properties of Acrylonitrile Butadiene Rubber/Recycled Natural Latex Gloves (NBR/NRL-G) Compounds. Applied Mechanics and Materials. 815 (2015).

DOI: 10.4028/www.scientific.net/amm.815.59

Google Scholar

[6] R.A. Majid, H. Ismail, R.M. Taib. Effects of polyethylene-g-maleic anhydride on properties of low density polyethylene/thermoplastic sago starch reinforced kenaf fibre composites. Iran. Polym. J. 19 (2010) 501-510.

DOI: 10.1016/b978-0-08-102160-6.00014-7

Google Scholar

[7] O.S. Dahham, N.Z. Noriman, S.T. Sam, N.M. Al-Samarrai, Z. Shayfull, Z., A.M. Alakrach, S.A. Elnaid. The influence of Rice Husk Fiber on The Properties of Epoxidized Natural Rubber/Rice Husk Compounds. MATEC Web of Conferences. 78 (2016) 01075.

DOI: 10.1051/matecconf/20167801075

Google Scholar

[8] O.S. Dahham, N.Z. Noriman, S.T. Sam, H. Rosniza, N.A.S. Marwa, Z. Shayfull, A.M. Alakrach. The Effects of Trans-Polyoctylene Rubber (TOR) as a Compatibilizer on The Properties of Epoxidized Natural Rubber/Recycled Silicone Catheter (ENR-25/rSC) Vulcanizate. MATEC Web of Conferences. 78 (2016).

DOI: 10.1051/matecconf/20167801076

Google Scholar

[9] M. Abdelmouleh, S. Boufi, M.N. Belgacem, A. Dufresne. Short natural-fibre reinforced polyethylene and natural rubber composites: effect of silane coupling agents and fibres loading. Compos. Sci. Technol. 67 (2007) 1627-1639.

DOI: 10.1016/j.compscitech.2006.07.003

Google Scholar