The Effect of Addition of Polysaccharide Materials on the Morphology of Freeze Fracture Surface of Natural Rubber Latex Films

Abstract:

Sago starch, amylose and amylopectin were used as fillers in natural rubber (NR) latex compounds. The compound was prevulcanized at 80 °C until chloroform number 2-3 was achieved. The effect of the fillers on the NR latex film mechanical properties (tensile properties and tear strength), and crosslink density were obtained. The fractured surface of the films was captured via scanning electron microscope (SEM) Zeiss Supra 35 VP. The results shown the addition of fillers reduced the tensile strength and elongation at break of the NR latex films but increased in the films tear strength. The swelling index of the films increased, indicating lower crosslink density possessed by the polysaccharide filled films. From the SEM micrograph, the addition of sago starch and amylose produced an uneven freeze fractured surface similar to the control starch films. Meanwhile, for films reinforced with amylopectin, the smooth surface is obtained indicating poor interfacial adhesion between filler and NR latex matrix.

• Periodical: Solid State Phenomena (Volume 264)
• Pages: 220-223
• DOI: https://doi.org/10.4028/www.scientific.net/SSP.264.220
• Online since: September 2017
• Authors: A. Rashid Azura*, Muhamad Afiq Misman
• Keywords: Amylopectin, Amylose, Fractured Surface, Natural Rubber Latex, Sago Starch

References

[1] Ahmad, F. B., Williams, P. A., Doublier, J. L., Durand, S. and Buleon, A. (1999). Physico-chemical characterisation of sago starch, Carbohydrate Polymers, 38, 361-370.

DOI: 10.1016/s0144-8617(98)00123-4

[2] Ratnayake, W. S. and Jackson, D. S. (2007). A new insight into the gelatinization process of native starches, Carbohydrate Polymers, 67, pp.511-529.

DOI: 10.1016/j.carbpol.2006.06.025

[3] Shujun, W., Jiugao, Y., & Jinglin, Y. 2005. Preparation and characterization of compatible thermoplastic starch/polyethylene blends. Polymer Degradation and Stability, 87(3), p.395–401.

DOI: 10.1016/j.polymdegradstab.2004.08.012

[4] Afiq, M. M. and Azura, A. R. (2013). Utilization of starch to accelerate the growth of degrading microorganisms on the surface of natural rubber latex films, Journal of Chemistry and Chemical Engineering, 7, pp.137-144.

[5] Weber, T., Zanchet, A., Brandalise, R. N., Crespo, J. S., and Nunes, R. C. R. (2008). Grinding and Characterization of Scrap Rubbers Powders. Journal of Elastomers and Plastics, 40, pp.147-159.

DOI: 10.1177/0095244307082487

[6] Ichazo, M.N., Albano, C., Hernández, M., González, L. and Peña, J. (2011). Characterization of natural rubber/cassava starch/maleated natural rubber formulations, Revista Latinoamericana de Metalurgia y Materiales, 31, 1, pp.71-84.

[7] Siti Nuraya, A. S., Baharin, A., Azura, A. R., Mas Rosemal Hakim, M. H., Mazlan, I., Adnan, M., Nooraziah, A. A., (2012).

[8] Arayapranee, W. and Rempel, G.L. (2013a). Effects of polarity on the filler-rubber interaction and properties of silica filled grafted natural rubber composites, Journal of Polymers, Volume 2013, pp.1-9.

DOI: 10.1155/2013/279529