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Online since: August 2006
Authors: Yoshiyuki Yokogawa, Katsuya Kato, Sindhu Seelan
Introduction : In recent years, many support matrices and couplings chemistries have been developed and made commercially available for use in protein immobilization.
Syntheses of well-ordered hexagonal mesoporous silica structures with tunable large uniform pore sizes between 46 and 100 Å are possible by use of amphiphillic block copolymers [8,9] as organic structure-directing agents.
Such an isotherm is attributed to the presence of mesoporous structure.
Online since: January 2013
Authors: Wei Ping Gao, Rui Duan Li
It is ideal system structure thermodynamically and it is ideal device for saving investment in equipment and energy.
We obtained optimum operating conditions and equipment structure parameters in different feed composition and temperature.
Annual costs as the objective function, considering the investment in equipment and operating costs of the distillation column, calculated the total annual cost of the structure of the different distillation column, the lowest annual total cost is the Optimal choice.
Industrial Engineering Chemistry Research.2010,49:1333-1342
Online since: February 2014
Authors: Nurhanna Badar, Rusdi Roshidah, Mawar Hazwani Jasimin, Norlida Kamarulzaman, Muhd Firdaus Kasim
INTRODUCTION Materials of unique sizes, structures and morphology are expected to find various novel applications.
Recently, many investigations have been carried out concerning structural properties of metastable Al2O3 such as σ, η and γ because of their high specific surface areas and the large number of defects in their crystalline structure which is important in catalysis [2- 7].
(Star (*) is corresponding to Al2ZnO4 structure and square (▪) is corresponding to α-Al2O3) Fig. 2.
Andersson: Controlling The Formation and Stability of Alumina Phases (Plasma and Coatings Physics Division, Department of Physics, Chemistry, and Biology, Linköping University, SE-581 83 Linköping, Sweden 2005)
Online since: August 2008
Authors: Naratip Vittayakorn, N. Phungjitt, Theerachai Bongkarn
Vittayakorn3,c 1 Department of Physics, Faculty of Science, Naresuan University, Phitsanulok, Thailand 2 Department of Physics, Faculty of Science, Uttaradit Rajabhat University, Uttaradit, Thailand 3 Department of Chemistry, Faculty of Science, King Mongkut's Institute of Technology Ladkrabang, Bangkok,Thailand a reseachcmu@yahoo.com, bnalinee_amp@hotmail.com, cnaratipcmu@yahoo.com Keywords: Barium zirconate titanate, Microstructure, Phase formation, Solid state reaction Abstract.
However, the detail of calcined temperatures affected crystal structure and morphology evolution of [Ba(ZrxTi1-x)O3] powders, which synthesis by solid state reaction method have been reported yet.
To a first approximation, this phase has a cubic perovskite type structure in the space group Pm-3m (no.221) Figure 1.
The calcination temperatures have a strong influence on the crystal structure, homogeneity and the unit cell volume of the calcined powders.
Online since: July 2013
Authors: Yang Xue, Jian Biao Feng, Jing Lin, Yuan Li
To ensure the actual water level of that power is consistent with the setting value, the valve in the Chemistry and Volume Control (RCV) system varies as the change of the actual power.
Fig.1 The principle of pressurizer water level control system The structure and principle analysis of ADRC Let us take a second-order system for example.
The structure of the second-order ADRC is shown in Figure 3.
The ESO’s discrete dynamic equation is: (4) and (5) Fig.3 The structure of the second-order ADRC Nonlinear State Error Feedback Law and Real-Time Dynamic Feedback Linearization.
Online since: February 2012
Authors: Ling Na Sun, Wen Wen Tang
Preparation of Layered Double Hydroxides Nanomaterails via the Anionic Surfactant Lingna Sun1,*, Wenwen Tang2 1School of Chemistry and Chemical Engineering, Shenzhen University, Shenzhen, 518060, P.
Up to date, some groups have reported the syntheses of LDHs with ordered structures.
The phase composition and structure of the products were examined by X-ray powder diffraction (XRD) (see Figure 1).
These micro-nano structures are formed from self-assembly of nanoplates in a spontaneous process in solvothermal system with surfactant (SDBS).
Online since: August 2009
Authors: Yuan Hua Lin, Guo Jing Li, Shu Jin Zhao, Ao Mei, Jin Le Lan
Ca2Co2O5,another layered calcium cobalt oxide with ordered oxygen vacancies has the similar structure with Ca3Co4O9[12,13].By conntrst with Ca2Co2O5, Ca3Co4O9 possesses 25% calcium vacancies.
Strong (00l) reflections can be observed in Fig.1(a,b,c), showing the formation of a textured structure in the Ca2Co2O5 samples. 10 20 30 40 50 60 70 (d) Intensity(a.u.) 2θ / ο (006) (005) (004) (003) (002) (c) (b) (a) Ca2Co2O5 Co3O4 CaCo2O4 Fig. 1 The XRD patterns of Ca2Co2O5 ceramics sintered at (a) 750°C,SPS (b) 800°C,SPS (c) 850°C,SPS and (d) Ca2Co2O5 powder calcined at 750°C for 2h Fig. 2 illustrates the SEM micrographs of fractured surfaces of the ceramic samples.As seen,the sintered ceramics consist of sheet-like grain of 0.5~2µm and the grain is obviously oriented.
Ca3Co4O9 is unconventional semiconductor and strongly electron-correlated compound.This feature for Ca2Co2O5 samples is due to its unique electronic structure[14].
Journal of Solid State Chemistry.178(2005),p.2186.
Online since: August 2013
Authors: Cheng Jun Wang, Ping Jiang, Xin Xin, Wen Zeng
However, flame radiation and soot concentration are mainly influenced by fuel properties, combustor operating conditions and combustor structure etc.
Considering of the complex combustor structure, the simulation combustor model is simplified and contained one nozzle as computational area, as shown in Fig 1.
Fig. 1 Combustor structure diagram Numerical solution method The numerical simulation of combustor model was investigated with three-dimensional numerical method.
Because fuel change will affect fuel droplet pulverization and evaporation rate, the chemistry of the fuel itself will change the combustion efficiency, flame temperature and soot concentration.
Online since: April 2011
Authors: Yu Lin Yang, Xiang Ni Yang, Li Qin Wang, Rui Jun Zhang, Yang Han
Synthesis and Characterization of ZnO Nanoparticles in the Method of Precipitation Liqin Wang1,2,a, Xiangni Yang1, Yang Han1, Ruijun Zhang2, Yulin Yang3 1Hebei Key Laboratory of Applied Chemistry, College of Environmental and Chemical Engineering, Yanshan University, Qinhuangdao, Hebei, 066004, China 2 State Key Laboratory of Metastable Materials Science and Technology, Yanshan University, Qinhuangdao, Hebei, 066004, China 3 College of Mechanical Engineering, Yanshan University, Qinhuangdao, Hebei, 066004, China awangliqin@ysu.edu.cn Keywords: ZnO, Nanoparticles, Precipitation, Photocatalyst, Degradation Abstract.
The morphology and crystal structure, photocatalytic and degradation property for the methyl orange aqueous solution were studied, and the obtained ZnO nanoparticles had perfect properties.
The crystal structure of ZnO particles was determined by X-ray powder diffractometer (XRD) of D/MAX-rB, which was radiated by Cu Kα.
It indicated as-prepared ZnO nanoparticles had integrated crystal structure.
Online since: August 2014
Authors: Qi Dan Ling, Lu Ying Liang, Wen Wang, Wei Wang, He Min Zheng, Zong Xiong Xu, Yong Kun Lei, Hong Yu Lin
Besides molecular design and synthesis methods, nanometer-scale morphology and molecular-scale crystallinity (crystal structures, π-π stacking distance and conjugation length) are also critical for charge carrier mobility as well as enhanced device performance5.
The P3HT with this one-dimensional anisotropy of the branch nanowires structure can offer direct and fast access to the hole due to its high order.
The emergence of the [100] and [020] peaks suggests that the P3HT nanowires consist of a stack of P3HT backbones, adopting the edge-on structures in which P3HT backbones are aligned parallel to the substrate, as illustrated in Figure 2b.
McCullough, The Chemistry of Conducting Polythiophenes, Adv.