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Online since: August 2011
Authors: Li Hua Wang
Introduction The Schiff base compounds constitute an important class of ligand which has been extensively investigated in coordination chemistry mainly due to their facile synthesis and easily tunable steric, electronic, and catalytic properties.
They are also useful in constructing supramolecular structures [1-2].
Online since: October 2010
Authors: Xue Gang Luo, Ai Xia Lu, Yang Luo, Jian Ye
The water absorbency increased with the increase of the amount of initiator, because more graft polymerization occurred and more stable network structures formed.
Flory:Principle of polymer chemistry.
Online since: December 2013
Authors: Shou Zhi Pu, Yong Jun Tang, Hong Yan Xu
Synthesis and Photochromism studies of 1-(2-methyl-3-benzothiophenyl)-2-[2-methyl-5-(4-azidomethyl)-3-thienyl]perfluorocyclopentene Yongjuan Tang, Hongyan Xu and Shouzhi Pu* Jiangxi Key Laboratory of Organic Chemistry, Jiangxi Science and Technology Normal University Nanchang 330013, P.R.China pushouzhi@tsinghua.org.cn Keywords: Diarylethene, Photochromism, Electrochemical Abstract: An unsymmetrical photochromic diarylethene 1-(2-methyl-3-benzothiophenyl)- 2-[2-methyl-5-(4-azidomethyl)-3-thienyl] perfluorocyclopentene was synthesized, and its optoelectronic properties were also investigated.
The structures of diarylethene 1o were confirmed by 1H NMR (400 MHz, CDCl3, TMS): δ 2.13 (s, 3H, -CH3), 2.32 (s, 3H, -CH3), 4.51(s, 2H, -CH2), 6.58 (s, 1H, thiophene-H), 7.32 (d, 1H, J = 8 Hz), 7.44-7.51 (m, 2H, J = 8 Hz), 7.65 (d, 1H, J = 8 Hz) Scheme 2.
Online since: August 2016
Authors: Pavla Rovnaníková, Jana Zahálková
Study of the effect of diatomite as a partial replacement of cement in cement pastes ZAHALKOVA Jana1,a, ROVNANIKOVA Pavla1,b 1Brno University of Technology, Faculty of Civil Engineering, Institute of Chemistry, Veveří 331/95, 602 00 Brno, Czech Republic azahalkova.j@fce.vutbr.cz, brovnanikova.p@fce.vutbr.czl Keywords: Diatomite, amorphous SiO2, pozzolanic activity, cement, mechanical properties.
There are many reasons for the use of diatomite in filtration such as; its high porosity and bulk volume, its porous and permeable structure, its resistance to chemicals and high purity, large filtration surface area, its good adsorption properties especially for oils and micro-organisms [3].
Online since: July 2013
Authors: Liang Rong Zhao, Ping Shen, Xu Qin Zhan, Ming Xun Yan, Chang Ying Yang
A highly selective chemosensor probe for Ag+ in 50% THF/H2O Liangrong Zhao, Ping Shen, Xuqin Zhan, Mingxun Yan, Changying Yang* College of Chemistry and Life Science, Three Gorges University, Yichang 443002, China yangcy12@gmail.com Keywords: Diethyl6-anilino-5H-2,3-dithia-5,7-diazacyclopenta(cd)indene-1,4-dicarboxylate (D1); Deprotonation; Chemosensor; Ag+ Abstract.
Structures of D1.
Online since: May 2007
Authors: Ho Kun Kim, Jin Koo Park, Jong Kil Kim
Recovery of Silica and Sodium Fluoride from Hexafluorosilicic Acid and Sodium Silicate Jong-Kil Kim 1,a, Jin-Koo Park2,b and Ho-Kun Kim 1,c 1 Dept. of Applied Chemistry, Hanyang University, Ansan, 425-791, Korea 2 Korea Institute of Limestone & Advanced Materials, Danyang 395-903, Korea a k3289@hanyang.ac.kr, bsky3013@hanmail.net, chkkim@hanyang.ac.kr Keywords: Sol-gel process; nanoporous silica; hexafluorosilicic acid, sodium silicate Abstract.
To get purer silica and NaF, the concentration ratios of the initial compounds were controlled, and then investigated the physical(surface and pore structures) properties of the obtained silica.
Online since: May 2011
Authors: Jun Ang Liu, Yuan Hao He
Fig.1 Thermal stability of crude CDA The influence of pH on CDA stability The pH can change of enzyme conformation and the active site of enzyme molecule structure.
[7] Roberts GAF. in: Chitin Chemistry, Macmillan Press, U.K. (1992)
Online since: July 2014
Authors: Shou Zhi Pu, Jing Jing Liu, Hong Jing Jia
Synthesis and Properties Study of 1-(2,4-dimethoxyl-5-pyrimidinyl)-2-[2-methyl-5-(9-phenanthrene)-3-thienyl]perfluorocyclopentene Jingjing Liu, Hongjing Jia and Shouzhi Pu* Jiangxi Key Laboratory of Organic Chemistry, Jiangxi Science and Technology Normal University Nanchang 330013, P.R.China pushouzhi@tsinghua.org.cn Keywords: Diarylethene, Photochromism, Pyrimidine, Fluorescence.
The structure of diarylethene 1o was confirmed by 1H NMR (400 MHz, CDCl3, TMS): δ 2.13 (s, 3H, -CH3), 3.78 (s, 3H, -OCH3), 3.98 (s, 3H, -OCH3), 7.02 (s, 1H, thiophene-H), 7.51-7.65 (m, 4H, benzene-H), 7.71 (s, 1H, benzene-H), 7.81 (d, 1H, J = 8.0 Hz, benzene-H), 8.07 (d, 1H, J = 8.0 Hz, benzene-H), 8.32 (s, 1H, pyrimidine-H), 8.61 (d, 1H, J = 8.0 Hz, benzene-H), 8.63 (d, 1H, J = 8.0 Hz, benzene-H).
Online since: July 2014
Authors: Guan Ming Liao, Shou Zhi Pu, Chun Hong Zheng, Dan Dan Xue
Research on Photochromic Compounds with Synthesis and Photochromism of 1-(2-methyl-3-benzofuryl)-2-{2-methyl-5-[4-formyloxyethyl (Rhodamine-B)] phenyl-3-thienyl} Perfluoroyclopentene Dandan Xue, Guanming Liao, Chunhong Zheng* and Shouzhi Pu Jiangxi Key Laboratory of Organic Chemistry, Jiangxi Science and Technology Normal University, Nanchang 330013, P.R.China zch722108@126.com Keywords: Diarylethene; Photochromism; Rhodamine B; Photochromic reaction kinetics Abstract.
The structure of compound 1o was confirmed by 1H NMR (400 MHz, CDCl3): δ 1.07 (t, 12H, J = 7.0 Hz), 1.83 (s, 3H), 2.07 (s, 3H), 3.20–3.25 (m, 8H), 3.54 (t, 2H, J = 6.0 Hz), 3.94 (t, 2H, J = 6.0 Hz), 6.11–6.14 (m, 2H), 6.30 (d, 2H, J = 1.2 Hz), 6.38 (s, 2H), 6.99–7.01 (m, 1H), 7.16 (s, 1H), 7.21 (s, 1H), 7.33–7.40 (m, 5H), 7.44 (s, 1H), 7.46 (s, 1H), 7.83 (s, 1H), 7.85–7.88 (m, 2H).
Online since: May 2004
Authors: Filiz Çinar Şahin, Onuralp Yucel, S. Erçayhan, Bora Derin
Yücel1 1 Istanbul Technical University, Faculty of Chemistry and Metallurgy, Department of Metallurgical and Material Engineering, 34469, Maslak, Istanbul, Turkey 2 Istanbul Technical University, Prof.
Having wurtzite structure and being made up of relatively light elements, it was predicted and experimentally verified that AlN should have a high thermal conductivity value.