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Online since: October 2006
Authors: Pavlo Kisly, Igor Fesenko, Mykola Novikov
The AlN nanopowder is plasmachemically synthesized at the Institute of
Inorganic Chemistry of the Latvian Academy of Sciences.
In addition, during the liquid-phase recrystallization, the yttrium oxide removes the oxygen impurity from the AlN structure, thus increasing the ceramics heat conductivity (Table 3).
The structure of the composites produced by pressureless sintering in a nitrogen atmosphere is the AlN ceramic matrix with uniformly distributed grains of molybdenum (Fig. 1) or another conductive second phase.
In addition, during the liquid-phase recrystallization, the yttrium oxide removes the oxygen impurity from the AlN structure, thus increasing the ceramics heat conductivity (Table 3).
The structure of the composites produced by pressureless sintering in a nitrogen atmosphere is the AlN ceramic matrix with uniformly distributed grains of molybdenum (Fig. 1) or another conductive second phase.
Online since: June 2007
Authors: Yoo Hang Kim, Eun Yi Kim, Chin Myung Whang, Mi Young Yoon
Formation of Spherical and Rod-Shaped TiO2 Nanocrystals
Prepared by Reverse Micelle Method
1Eun Yi Kim, 1Mi Young Yoon, 2Yoo Hang Kim and 1Chin Myung Whanga
1
Department of Materials Science and Engineering, Inha University,
2
Department of Chemistry, Inha University,
253 Yongheun-dong, Nam-gu, Incheon 402-751, Korea
a
Corresponding author : cmwhang@inha.ac.kr
Keywords: reverse micelle, solvothermal process, TiO2, carboxylic acid
Abstract.
The carboxylic acid of long hydrocarbon chain helps to form a stable reverse micelles structure in non-polar ether.
Micro-structured studies were carried out by transmission electron microscope (TEM, Philips, CM200), field emission scanning electron microscope (SEM, Hitachi, S-4200) and atomic force microscope (AFM, PSIA, XE-150).
The carboxylic acid of long hydrocarbon chain helps to form a stable reverse micelles structure in non-polar ether.
Micro-structured studies were carried out by transmission electron microscope (TEM, Philips, CM200), field emission scanning electron microscope (SEM, Hitachi, S-4200) and atomic force microscope (AFM, PSIA, XE-150).
Online since: January 2017
Authors: Siti Halimah Sarijo, Monica Limau Jadam, Faizah Md Saleh
ZAF synthesized at the optimum condition (0.3 M) shows pure phase of material with good crystallinity as shown by well-defined sharp reflection peaks [6] indicating a pure phase, well-ordered nanolayered structure.
Fig.1 PXRD patterns (inset is molecular structure of fenoprofen) (a) and FTIR spectra (b) for ZAFs synthesized at different concentration of fenoprofen ranging from 0.1 M to 0.3 M Thermal Analysis Fig. 2 shows thermal decomposition, TGA/DTG curves of ZAL, pure fenoprofen and ZAF synthesized using 0.3 M fenoprofen.
O’Hare, Intercalation chemistry of layered double hydroxide: Recent developments and applications, J.
Fig.1 PXRD patterns (inset is molecular structure of fenoprofen) (a) and FTIR spectra (b) for ZAFs synthesized at different concentration of fenoprofen ranging from 0.1 M to 0.3 M Thermal Analysis Fig. 2 shows thermal decomposition, TGA/DTG curves of ZAL, pure fenoprofen and ZAF synthesized using 0.3 M fenoprofen.
O’Hare, Intercalation chemistry of layered double hydroxide: Recent developments and applications, J.
Online since: July 2015
Authors: Hai Yun Shen, Qiu Hua Yang, Qian Nan Li, Yan Xia Han
Synthesis, Characterization and Optical Property
of KLaF4:Ce3+ Nano Particle
Yanxia Han1, a, Qiannan Li2,b , Haiyun Shen3,c and Qiuhua Yang4,d
1Department of Chemistry, School of Science, Tianjin University, Tianjin, 300072, China
ahan_yanxia@126.com, bqiannan2012@126.com, cshenhaiyun2006@163.com,
dqiuhuay@tju.edu.cn
Keywords: KLaF4:Ce3+, co-precipitation method, luminescent properties.
KLaF4 has two kinds of cubic and hexagonal structure just like NaYF4, but higher stability than NaYF4.
R Liu[10] has prepared a cubic phase KLaF4:Er3+/Yb3+ nanocrystalline and core-shell structure by thermal decomposition, which is demonstrated strong fluorescence emission.
KLaF4 has two kinds of cubic and hexagonal structure just like NaYF4, but higher stability than NaYF4.
R Liu[10] has prepared a cubic phase KLaF4:Er3+/Yb3+ nanocrystalline and core-shell structure by thermal decomposition, which is demonstrated strong fluorescence emission.
Online since: August 2011
Authors: Xin Wen Li, Zhen Guo Liu, Hui Xuan Zhang, Ye Han
Synthesis and Characterization of Silicone-modified
Butyl Acrylate-Methyl Methacrylate Copolymer Latex
Ye Han1,a, Xinwen Li1,b, Zhenguo Liu2,c, Huixuan Zhang1,2,d
1Changchun University of Technology, Changchun 130012, China
2 Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022
ahy@mail.ccut.edu.cn, blixw@mail.ccut.edu.cn, cliuzg@mail.ccut.edu.cn, dzhanghx@mail.ccut.edu.cn
Keywords: Semi-continuous emulsion polymerization, D4, Low temperature resistance, Adhesive strength
Abstract:Silicone-modified butyl acrylate-methyl methacrylate copolymer latex was prepared via semi-continuous emulsion polymerization.
When D4 content was 2.5wt%, the adhesive strength was the highest, which was ascribed to the crosslinking structure of copolymer hindering the movement of molecular chain and bankrupt in wetting and mutual diffusion.
Reasons were as followed: with increasing the content of D4, crosslinked and net-like structures were favored due to polycondensation of D4, which prevented molecular chain movement.
When D4 content was 2.5wt%, the adhesive strength was the highest, which was ascribed to the crosslinking structure of copolymer hindering the movement of molecular chain and bankrupt in wetting and mutual diffusion.
Reasons were as followed: with increasing the content of D4, crosslinked and net-like structures were favored due to polycondensation of D4, which prevented molecular chain movement.
Online since: December 2011
Authors: Ying Ming Xie, Dao Ping Liu, Ni Liu, Ying Xia Qi, Jin Ming Gong, Tao Tang
That is because the pressure required for pure hydrogen hydrate formation is very high( about 200MPa at temperature below 250K), but it is reduced after adding additive such as TBAB or THF, TBAB or THF molecules occupied the large-cage and stabilized the hydrate structure while H2 molecules occupied the small-cage, which will reduce the hydrate formation pressure dramatically.
For TBAB-H2 semic-hydrate, the cation is encaged into the large cavities, while the anion is combined with water molecule by hydrogen bonds and form cage, which can stabilize the hydrate structure[6,7].
Progress in Chemistry, 2006, 18(2/3) : 200-210
For TBAB-H2 semic-hydrate, the cation is encaged into the large cavities, while the anion is combined with water molecule by hydrogen bonds and form cage, which can stabilize the hydrate structure[6,7].
Progress in Chemistry, 2006, 18(2/3) : 200-210
Online since: January 2012
Authors: Zhi Cheng Yu, Hao Yu Yuan, Jian Hua Liu
It was probably because that red 2-hydroxy chalcone was generated by ring-opening reaction of the extraction of flavonoids.
2.2.2 Effect of temperature on dye stability
Fig. 3 The effect of temperature on dye stability
As shown in Fig. 3, with the increasing of temperature, the dye absorbance had little changes, which illustrated that semen litchi dye can keep stable at higher temperatures.
2.3 Extracts component analysis
2.3.1 Qualitative chemical analysis
Table 3 The chemical analysis of semen litchi extract
Analysis
Method
Experimental phenomena
Tannins
1% FeCl3 solution
dark green precipitate
gelatin solution
precipitate
Flavonoids
1% AlCl3 solution
yellowish-brown precipitate
ethanol of 1% FeCl3
the color of dark green
2.3.2 Infrared spectroscopic analysis
Fig. 4 The infrared spectrum of semen litchi extract
Tannins and flavones are both natural polyphenols with common molecular structure containing hydroxyl, ester, aromatic ring and glycosidic bond [6].
The effect of the dye bath pH was attributed to the correlation between dye structure and silk fabric.
Acknowledgements The authors would like to express their sincere thanks to Zhejiang Provincial Top Key Academic Discipline of Applied Chemistry and Eco-Dyeing & Finishing Engineering and Zhejiang Provincial Key Innovation Team (Grant No.2010R50038).
The effect of the dye bath pH was attributed to the correlation between dye structure and silk fabric.
Acknowledgements The authors would like to express their sincere thanks to Zhejiang Provincial Top Key Academic Discipline of Applied Chemistry and Eco-Dyeing & Finishing Engineering and Zhejiang Provincial Key Innovation Team (Grant No.2010R50038).
Manganese-Doped CdGeAs2, ZnGeAs2 and ZnSiAs2 Chalcopyrites: A New Advanced Materials for Spintronics
Online since: December 2010
Authors: R.A. Szymczak, L.A. Koroleva, S.F. Marenkin, I.V. Fedorchenko, D.M. Zashchirinskii, B. Krzymanska, T.M. Khapaeva, A.S. Morozov
Lomonosov Moscow State University, Leninskie Gory, 119992 Moscow, Russia
2Institute of General and Inorganic Chemistry RAS, Leninskii pr.31, 119991 Moscow, Russia
3Institute of Physics PAS, Lotnicov al. 32/46, Warsaw 02668, Poland
a acp@mail.ru, b koroleva@phys.msu.ru, c fiz-denis@mail.ru, d marenkin@rambler.ru,
f fedorkin-san@rambler.ru, e szymr@ifpan.edu.pl
Keywords: spintronics, chalcopirites, Сurie temperature, superparamagnetic cluster, spontaneous magnetization.
These investigations will allow one to produce one-electron logic structure and spin-information systems using an electron spin as a memory cell: one spin – one information bit.
The origin of the ferromagnetism in diluted magnetic semiconductors has been investigated using the first-principles calculation of electronic structure in works [10].
These investigations will allow one to produce one-electron logic structure and spin-information systems using an electron spin as a memory cell: one spin – one information bit.
The origin of the ferromagnetism in diluted magnetic semiconductors has been investigated using the first-principles calculation of electronic structure in works [10].
Online since: April 2007
Authors: Chang Wei Cui, Yuan Deng, Lin Guo
Our method reported
here differs conceptually from all previous methods of forming porous films, it exploits a duplication
of the structure of porous alumina template.
The crystal structure of the porous films was examined by XRD.
Adamson: Physical Chemistry of Surfaces (5th ed, Wiley, New York, 1990).
The crystal structure of the porous films was examined by XRD.
Adamson: Physical Chemistry of Surfaces (5th ed, Wiley, New York, 1990).
Online since: November 2013
Authors: A.Z. Zainurul, C.H. Rosmani, Mohamad Rusop, Saifollah Abdullah, Mohd Nor Asiah, Mohd Husairi Fadzilah Suhaimi
The grain structure of film can be seen clearly from this AFM image.
We conclude that the optimum layers coated on glass substrate were 12 layers with exhibit the lowest emission peak which due to the lowest crystalline structure.
Journal of Physical Chemistry c 112 (2008) 11679-11684
We conclude that the optimum layers coated on glass substrate were 12 layers with exhibit the lowest emission peak which due to the lowest crystalline structure.
Journal of Physical Chemistry c 112 (2008) 11679-11684