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Online since: September 2013
Authors: Ying Juan Fu, Meng Hua Qin, Shou Juan Bian
One of their most attractive features is the capacity to generate well-defined polymer structures.
The general chemical structure of RAFT agent and the mechanism of RAFT polymerization Scheme 2.
Associated with click chemistry Combining RAFT technology with highly orthogonal click chemistry can be employed as a powerful tool for macromolecular design.
Perrier: Nature Chemistry Vol. 2(2010), p. 811-820 [6] R.T.A.
Cai: Journal of Polymer Science: PartA: Polymer Chemistry Vol. 43(2005), p. 6379-6393 [8] H.T.
Online since: December 2023
Authors: Xia Zhu, Hidekazu Goto, Ryoya Shiraishi, Hiromichi Toyota, Yukiharu Iwamoto, Kosuke Okamoto
For the quantum chemistry calculation, energy barrier and kinetic energy for a carbon atom intrudes into a model cluster has been calculated with an ab-initio computational chemistry software package, Gaussian.
In addition, since the periodicity of the crystal structure on the steel surface is lost by drilling, the cluster model is a valid model for the drilled surface.
Quantum chemistry calculation software Gaussian was used for the calculations.
The hypotheses (A) and (B) were examined by the quantum chemistry calculation and experimental.
For the quantum chemistry calculation, five model clusters with different atomic compositions were prepared, each energy change ΔE and Eb were calculated with an ab-initio computational chemistry software package, Gaussian.
Online since: August 2011
Authors: Yong Zhou, Zhi Guo Hu
Synthesis of chiral Amphiphilic Graft Copolymer PBTQMO-g-MPEO Yong Zhou1,a, ZhiGuo Hu2,b 1 College of Chemistry and Chemical engineering Xinxiang University, Xinxiang, Henan,453003 China 2 College of Chemistry and Environmental Science, Henan Normal University, Xinxiang 453007, China a chengshangzhou@yahoo.com.cn, b031045@htu.cn Keywords: chiral amphiphilic graft copolymers, quinine, "click" chemistry.
The fourier transform infrared spectrum(FTIR) and 1H nuclear magnetic resonance spectroscopy (1HNMR) were used to confirm its structure and composition.
In this work, we designed and synthesized an optically active amphiphilic graft copolymer bearing quinine pendants poly[3,3-bis(triazolyl-L-quinine) methyl oxetane]-g-poly(ethylene oxide) (PBTQMO-g-MPEO) using copolymer transformation and ‘‘click’’ chemistry (Scheme 1).
The gel permeation chromatography (GPC), 1HNMR spectra and fourier transform infrared spectrum(FTIR) were carried out to confirm its structure and composition.
Fig. 3 FTIR spectra of PBTQMO-g-MPEO Conclusions In summary, ‘‘click’’ chemistry was adopted to immobilize of 10,11-didehydro quinine onto azido-modified graft amphiphilic copolymer, which provided a convenient way to generate various optically active amphiphilic graft copolymers bearing quinine pendants.
Online since: December 2009
Authors: Zhi Xiong Huang, Min Xian Shi, Ming Zhang
The molecular structures of each isomer were evaluated on the basis of single point energy with zero point vibration correction.
And the stability of geometric configuration was carried on frequency analysis and determined by the related vibration frequency data. 2 Results and Discussions In the chain structure of polybutadiene, vinyl in 1, 4 polybutadiene structure are included in the chain, and in 1, 2 polybutadiene structure are include inside chain.
The chain structures of 1, 4 polybutadiene are regular shape, Syndiotactic1, 2-polybutadiene structure is more regular than the others of 1, 2 polybutadiene.
Structure and Non-isothermal Crystallization Kinetic of Syndiotatic1, 2-Polybutadiene.
Chinese Journal of Applied Chemistry, 2008,25(10):1233-1236
Online since: September 2019
Authors: Viktor A. Markov, Ivan Sokolov, Andrey Petrov
The structure of Na4 P2 O7 at 295 K Canadian Journal of Chemistry, 1972, 50, 2519-2526 [9] Van Weser.
The structural chemistry of phosphorus compounds // Topics in phosphorus chemistry. 1966.
Glass Physics and Chemistry, 2015, vol.41, No 6, pp.572-578
Glass Physics and Chemistry, 2015, vol.41, No 1, pp.35-41
Glass Physics and Chemistry, 2015, vol.41, No 1, pp.54-58
Online since: July 2021
Authors: Jan Šubrt, Pavel Dohnálek, Jaromír Jirkovský, Tereza Sázavská, Václav Pumpr, Hana Bíbová, Michaela Jakubičková, Martin Pusztai
Heyrovsky Institute of Physical Chemistry of the Czech Academy of Sciences.
Heyrovsky Institute of Physical Chemistry of the Czech Academy of Sciences.
Heyrovsky Institute of Physical Chemistry of the Czech Academy of Sciences.
Heyrovsky Institute of Physical Chemistry of the Czech Academy of Sciences.
Photocatalytic removal of nitrogen oxides via titanium dioxide, Environmental Chemistry Letters, vol. 2, 117–121
Online since: August 2014
Authors: Xiao Tao Zu, Q.P. Ding, Shi Fa Wang, Guang Ai Sun
In this paper, LaMnO3/α-Al2O3 magnetic nanocomposites were synthesized through using a soft-chemistry route.
The synthesis strategy in this work is based on a soft-chemistry process using a polyacrylamide gel route in which citric acid is employed as the chelating agent.
(iiii) The organics is decomposed during calcinations, and the frame-structure α-Al2O3 / LaMnO3 composites forms.
Other LaMnO3 nanoparticles are implanted in the porous α-Al2O3 inside to form complex structure.
XRD analysis indicated that the as-synthesized samples are rhombohedral α-Al2O3 and perovskite structure LaMnO3, suggesting that LaMnO3 /α-Al2O3 magnetic nanocomposites can be prepared by a soft-chemistry process and sintering at about 600 ˚C.
Online since: August 2010
Authors: Feng Wang, Chuan Wu, Ying Bai, Lian Wang, Feng Wu
Monoclinic Li3V2 (PO4)3/C cathode material has been synthesized by soft chemistry route and the electrochemical performance of this material was investigated.
The structure of the particles was characterized by X-ray diffraction (XRD).
Soft chemistry routes could provide intimate mixing of the reactants in molecular level and hence the product is of better homogeneity.
The structure of the product was characterized by X-ray diffraction analysis (XRD, Rigaku Ultimate IV) with Cu Kα radiation.
All diffraction peaks can be indexed to a monoclinic structure with space group P21/n.
Online since: August 2013
Authors: Hai Xing Liu, Jing Zhong Xiao, Qing Hua Zhang, Zhang Xue Yu, Kai Qi Ye, Huan Mei Guo, Guang Zeng
China 2Department of Physics, University of Coimbra, Coimbra 3004-516, Portugal 3State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, P.R.
China 4State Key Laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin University, Changchun 130012, P.R.
The structure of supramolecular are diverse, such as chain, layered, mesh, honeycomb and molecular lock structure.
The crystal data and structure refinement is shown in Table 1.
ZR2010BL025),Open Project of State Key Laboratory of Supramolecular Structure and Materials (No. sklssm201323)(Jilin University), State Key Laboratory of Inorganic Synthesis and Preparative Chemistry (No. 2011-13)(Jilin University).
Online since: September 2014
Authors: Qing Wang, Guang Xue Chen, Jing Lei Tai, Qi Feng Chen, Ming Hui He
Structure of the thiol-compounds was characterized by FT-IR, 1H-NMR.
Structure of the COMP was recorded with Nuclear Magnetic Resonance Spectrometer (AVANCE III 400, Brooke Company in Switzerland) and FT-IR (Spectrum 2000, Perkin Elmer).
Because the prepolymer had a relative neat structure contained polor ester, urethane and hydrogen bondings; which had greater cohesion and higher viscosity.
Structure of the COMP was characterized by FT-IR, 1H-NMR.
Radiation Physics and Chemistry. 2012(81)1332-1335 [5] Liu Hong-bo, Liu Heng-quan, Li Rong-xian, et al.