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Online since: July 2005
Authors: Františka Dorčáková, František Lofaj
The comparison of the effect of nitrogen and lanthanides on thermal shock resistance requires consideration of a structural parameter which characterizes changes of the glass network with the change of chemistry in general way.
Such parameters as cationic field strength or ionic radius of the corresponding RE modifier neglect changes of the glass structure due to the presence of nitrogen.
Density, though related to all species in the glass, is not specific concerning glass structure.
The increase of ∆T10 values of RE-oxynitride glasses in dependence on Cg can be explained by the nitrogen and RE modifier effects on glass structure cross-linking and tightening, respectively [6].
Tighter glass structure containing trivalent nitrogen and RE elements with smaller ionic radii would result not only in greater elastic radii and strength but also, in greater thermal shock resistance as indicated by the dependence of ∆T10 on Cg.
Online since: August 2010
Authors: Xin Min Xu, Xue Zhe Wei
So a single lithium cells require monitoring so that cell voltage does not exceed predefined limits of the chemistry.
Concrete speaking, the typical passive cell balancing is the resistor bleeding balancing (Fig. 1 shows the structure of the resistor bleeding balancing) and this method is also regarded as the most simple and straightforward balancing strategy.
So this method has the advantages of the simple structure, balance without precise measurement of the cell voltage.
the inductive charge transfer method The advantages of this method are obvious: simple structure with the same modules, large balancing current and high balancing efficiency, besides an adjacent pair of cells shares the same inductor.
Furthermore, it is easy for this structure to expand the number of the balancing cells.
Online since: February 2011
Authors: Jun Sheng Li, Hai Tao Cheng
According to the structure composition, silk protein is theoretically a natural surfactant, but doesn’t show any surface activities because of the insolubility of the silk in water.
Hydrolysis completely change the molecular structure of the protein, making the protein's hydrophobic and hydrophilic groups can simultaneously display.
As the silk fibroin salting process is a continuous process, the molecular structure and electric charge of silk protein alcium salt at different stage of dissolution are different.
Fig. 7 Effect of silk protein concentration (w/v) on Fig. 8 Effect of silk protein concentration (w/v) emulsification capacity of silk protein calcium salt on emulsification stability of silk protein calcium salt Conclusion According to the structure of silk protein, silk protein is theoretically a natural surfactant, but due to the insolubility of the silk in water, silk protein doesn’t show any surface activities.
Squire: Advances in Protein Chemistry Vo1.70 (2005), p.1 [2] G.
Online since: February 2014
Authors: Yong Hong Zhou, Li Qiang Zhang, Meng Zhang
Rosin acids, owing to their characteristic fused ring structure, are analogous to many aromatic compounds in rigidity[4].
It was found that the addition of multi-hydroxymethyl rosin ring structure could increase reaction activity of polyol, 10% compression strength, dimensional and thermal stability.
Study on thermal resistance of rigid polyurethane foam modified by rosin (I) - The Influence of Structures of Rosin Ester Polyols on Thermal Resistance Chemistry and Industry of Forest Products, 15(3), 1-6
Structures and physical properties of rigid polyurethane foam prepared with rosin-based polyol.
Online since: July 2019
Authors: B. Guruswamy, C. Shruthi, V. Ravindrachary, M. Mylarappa
Effect of SnO2 Nanoparticle Doping on Structural, Morphological and Thermal Properties of PVA-PVP Polymer Blend B Guruswamy1, V Ravindrachary1*, C Shruthi1, Mylarappa M2 1Department of Physics, Mangalore University, Mangalagangotri-574199, India 2Research centre Dept. of Chemistry, AMC Engineering College, Bangalore-560083, India.
Poly vinyl Pyrrolidone (PVP) is an amorphous polymer which is hygroscopic in nature and it attains complex formation ability, environmentally stable, easy processability, modest electrical conductivity, and more charge transport mechanism, these chemical structures induces extreme changes in electronic properties.
When PVA/PVP blend is formed, the interactions between the carbonyl group of PVP and the hydroxyl group of PVA takes place through the intermolecular hydrogen bonding which results in the formation of new structure.When such a blend is doped with metal oxide nanoparticles, microstructure and other macroscopic properties of the blend are altogether different from parent properties of the film.
Here it is clear that SnO2 nano particles are retain their crystal structure along with complex formation.
Fig. 3 (c,) also shows the bright regions, cluster formation and spike (needle-like) structures that are represents the added SnO2 dopant.
Online since: November 2012
Authors: Loic Hilliou, Mara Cunha, Gabriel Bernardo, Hartmut Wiggers, Rui N. Pereira
This is due to the fact that chloroform is highly volatile and therefore during spin coating, the film dries very quickly leading to a frozen structure (i.e. a structure without polymer chain mobility) after just a few seconds of spinning.
To the best of our knowledge, this is the first time that such oriented structure is pictured in hybrid photovoltaic composite films.
Thus a compromise between crystalline properties and morphology should be found by systematically measuring the photovoltaic efficiency of films which showed morphologies and crystalline properties approaching the theoretical optimal structure.
Sariciftci, Morphology of polymer/fullerene bulk heterojunction solar cells, Journal of Materials Chemistry, 16 (2006) 45-61
Online since: May 2015
Authors: Qiu Yu Zhang, Sarmad Ali, Nisar Ali, Bao Liang Zhang, Wajid Zaman
Nisar Ali1a, Zhang Qiuyu1b, Zhang Baoliang1c, Wajid Zaman2d, Sarmad Ali1e, 1Key Laboratory of Applied polymer Chemistry, School of Science, Northwestern Polytechnical University, Xi’an710072, China. 2School of Material Science & Engineering, Northwestern Polytechnical University, Xi’an 710072, China a.nisarali@mail.nwpu.edu.cn, bqyzhang@nwpu.edu.cn, cblzhang@nwpu.edu.cn, dwajid_zaman@yahoo.com, esarmad@mail.nwpu.edu.cn, Keywords: soap free emulsion polymerization, solvothermal process, magnetic composite nanoparticles, demulsification.
Asphaltene molecules have complex molecular structures, building on fused aromatic rings with saturated substituents and polar groups such as amine, hydroxyl, carboxyl, and sulfur-containing functional groups, making them amphiphilic [4,5].
The P(MMA-AA-DVB)/Fe3O4 nanoparticles show asymmetrical hybrid structure with two parts, gray color organic polymeric nanoparticles and black inorganic iron oxide.
This clearly demonstrates the dual, hybrid structure and amphiphilic and interfacially active nature and of P(MMA-AA-DVB)/Fe3O4 magnetic Janus nanoparticles.
This clearly demonstrates the asymmetrical hybrid structure and interfacial activity of Janus magnetic nanoparticles.
Online since: September 2007
Authors: V. Spasojević, V. Ćosović, A. Grujić, J. Stajić-Trošić, N. Talijan
Talijan 1,e 1 Institute of Chemistry, Technology and Metallurgy, Njegoševa 12, 11000 Belgrade, Serbia 2 Vinča Institute of Nuclear Sciences, PO Box 522, 11001 Belgrade, Serbia a vlada@tmf.bg.ac.yu, bgruja@tmf.bg.ac.yu, cjtrosic@tmf.bg.ac.yu, d vojas@vin.bg.ac.yu, entalijan@tmf.bg.ac.yu Keywords: Heat treatment, Interactive intergranular mechanism, Magnetic properties, Nanocomposite, Phase composition.
Research activates in development of nanocomposite permanent magnetic materials based on melt-spun Nd-Fe-B alloys with reduced Nd content are directed towards two goals: optimization of process parameters when nanocomposite structure is achieved and defining of the interactive mechanisms between the grains of present phases in magnetic matrix which have influence on the magnetic properties [6-9].
By appropriate heat treatment the grain sizes of present phases are limited to nanoscale and optimal phase composition is formed providing nanocomposite structure Fe3B/Nd2Fe14B and/or α-Fe/Nd2Fe14B.
Experimental results relevant for the formation of nanocomposite structure and defining of the interactive intergranular mechanism, which have dominant influence on the magnetic properties of investigated Nd-Fe-B alloy after the applied heat treatment regime, are presented and discussed.
Determined amount of the soft and the hard magnetic phase and experimentally obtained mean grain size, which was on a nanoscale (<30nm), together with experimentally calculated remanence ratio Jr/Js = 0.6 suggest that nanocomposite structure Fe3B/Nd2Fe14B was formed after optimal heat treatment of the investigated Nd4.3Fe76.2B19.5 alloy.
Online since: December 2013
Authors: Anika Zafiah M. Rus, N.N. Mat Hassan, M.A. Bainun Akmal
c b a d e f Figure 2 : Morphology structures of; (a) pure synthetic polymer foam and synthetic polymer foam doping with (b) 20% (c) 40% (d) 60% (e) 80% and (f) 100% of TiO2.
Based on the previous study [1], this variation may be due to the factor of porosity as well as morphological structure, and filler of the foam being developed.
Journal of Chemistry, Hindawi Publishing Corporation Vol. 2013 (2013) [7] M.R.
High performance structures and composites for high performance structures and materials.
Online since: February 2018
Authors: Ieva Putna-Nimane, Juris Kostjukovs, Jūlija Karasa, Solvita Kostjukova, Matiss Pals, Ilva Nakurte
Determination and Toxicology Studies of Quaternary Ammonium Salts in Solution after Organoclay Processing Matiss Pals1,a*, Ieva Putna-Nimane2,b, Juris Kostjukovs1,c, Jūlija Karasa1,d, Solvita Kostjukova3,e, Ilva Nakurte1,f 1Department of Chemistry, University of Latvia, Jelgavas 1, Riga, LV-1004, Latvia 2Latvian Institute of Aquatic Ecology, Voleru 4, Riga, LV-1007, Latvia 3Alina Ltd., Pulkveza Brieza 8-1, Riga, LV-1010, Latvia amatiss232@gmail.com, bieva.putna@lhei.lv, cjukos45@gmail.com, djulija.karasa@lu.lv, esolvita.kostjukova@gmail.com, filva.nakurte@gmail.com Keywords: Organoclays, quaternary ammonium salts, ODTMAC, UHPLC - TOF/MS method, toxicity, Daphnia magna Abstract.
Based on obtained data, it was concluded that ODMAC are not extracted from organoclay structure using pure water, therefore materials containing organoclays are completely safe to use outdoors, with no or low impact on environment.
Next step was ODMAC extraction from organoclay structure using stronger extraction solvent.
Fig. 2 shows that it was possible to extract at least 17% of all ODMAC from organoclay structure using isopropanol during 1 h.
It was found that ODMAC is not extracted from organoclay structure and poolwood material using pure water.