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Online since: September 2016
Authors: John L. Jorstad
Fine eutectic structure.
Passing somewhat overcooled surface and undercooled interior slurry through restricted openings (akin to the ingate to a die) will achieve shear, hot deformation of the alpha phase, homogenization of temperature, chemistry and structure and the target average temperatures.
Online since: March 2012
Authors: A. Adamus, J. Jozwiakowska, R.A. Wach, D. Suarez-Sandoval, K. Ruffieux, J.M. Rosiak
IN VITRO DEGRADATION OFΒ-TRICALCIUM PHOSPHATE REINFORCED POLY(L-LACTIC ACID) A.Adamus1,a, J.Jozwiakowska1,b, R.A.Wach1,c *, D.Suarez-Sandoval2,d, K.Ruffieux2,e, J.M.Rosiak1,f (1)Institute of Applied Radiation Chemistry, Technical University of Lodz, Wroblewskiego15, 93-590 Lodz, Poland (2)Degradable Solutions AG, Wagistrasse 23, CH-8952 Schlieren, Switzerland aaadamus@mitr.p.lodz.pl, bjoannaj@mitr.p.lodz.pl, cwach@mitr.p.lodz.pl (*corresponding author), ddsuarez@degradable.ch, eruffieux@degradable.ch, frosiakjm@mitr.p.lodz.pl Keywords: degradation, poly(L-lactic acid), β-tricalcium phosphate.
It is one of the few polymers in which the stereochemical structure can be modified by polymerizing a controlled mixture of the L- or D-isomers to obtain high molecular weight amorphous or crystalline polymers[1].Poly-L-lactide (PLLA) is a semicrystalline thermoplastic that is widely used in biomedical applications, owing to its good biocompatibility and inherent biodegradability [2].
Addition of bioactive ceramic fillers, may potentially improve osteoconductivity, i.e. the provision of a suitable substrate for bone growth on a surface, into pores or channels[13-14].Composites of PLLA with bioactive ceramics have beenexamined in order to enhance either mechanical properties, degradation rate and osteoconductivity [15].A recent trend is to exploit the improved properties of polymer/ bioceramic nanocomposites in which the modifier particles are of a similar size to those in natural bone, which consists essentially of around 50 or more wt% ceramic nanocrystals, comparable to natural HA in the composition and structure, embedded in a polymer matrix [16-18].
Online since: March 2012
Authors: Vijayaraghavan Reena, Sivan Velmathi
Synthesis, Characterization and Investigation of the Third Order Nonlinear Optical Properties of Pyrrole Schiff Bases Sivan Velmathi1,a*and Vijayaraghavan Reena1,b 1Organic and Polymer Synthesis Laboratory, Department of Chemistry, National Institute of Technology, Tiruchirappalli, Tamil Nadu -620 015, INDIA *avelmathis@nitt.edu, bvreenagupta@yahoo.co.in Keywords: Schiff bases, Negative Third Order Non Linearity, Z-Scan method and Optical Power Limiting.
Results and discussion Fig. 1 Structure of two Schiff bases 1,2-PDDI and 1,3-PDDI The Schiff bases 1,2-PDDI and 1,3-PDDI (Fig 1) were synthesized by the condensation of pyrrole -2- carboxaldehyde with 1,2-phenylene diamine and 1,3-phenylene diamine respectively.
In the case of 13C NMR spectroscopy CH=N carbon came as a sharp peak at d 145-150 ppm.Mass spectral analysis confirms the molecular structure of the compounds synthesized without any ambiguity.
Online since: October 2007
Authors: Akio Hirose, Hiroaki Tatsumi, Yusuke Akada, Takuto Yamaguchi
After that, X-ray diffraction (XRD) analyses using Cu-Ka radiation for the samples were performed in order to identify the chemical composition and the crystal structure, and the samples were observed using a field emission scanning electron microscope (FE-SEM).
Fitch, "Decomposition of silver carbonate - the crystal structure of two high-temperature modifications of Ag2CO3" Inorganic Chemistry, Volume 41, pp.3628-3637, 2002 [4] Y.
Online since: July 2005
Authors: Gaofeng Qan
Nevertheless, there are only a few appropriate techniques for the wrought products, due to the lack of detailed knowledge of the available mechanisms in internal structures of hexagonal close packed lattice for large plastic deformation [1, 2].
Thermal Activation Analysis on Yield And Strengthening.A well known thermal power law equation on the reaction rate is expressed as Arrhenius Equation [8, 9]: ) exp( 0 RT vQ A dt d σ ε − −= (3) where ε& = dεεεε/dt is the strain rate, A and Q0 are material constant related with the material composition, atomic structure and deformation mechanism, and activation energy, respectively.
As an analogy, for the same materials under a rational assumption that the series specimens all have the exactly same chemistry and microstructure, and the strain rate is constant in all tests, two typical stress levels could be discussed with the above thermal activation theory, say, proof stress and ultimate strength.
Online since: July 2012
Authors: Zhen Chen, Ying Ying Fan, Deng Hui Liao, Hong Quan Zhu, Qiang Lin
It was mainly used to control the crystal grain size and change the structure of materials in the preparation process of nano-materials.However, the reports on the preparation of anode materials with AEO-7 are limited [13,14].
As shown in Fig.2, the surface of the unmodified PbO2 electrode had obvious pinhole defects, rough surface , loose structure and and dissimilar crystal sizes .
Ivliana: Journal of Electroanalytical Chemistry 15(1983), p.241 [12]M.
Online since: November 2020
Authors: Aleksey Y. Zhizhchenko, Aleksandr Vladimirovich Nepomniaschiy, Aleksandr A. Kuchmizhak, Eugeny Mitsai, Alexander V. Dostovalov, Kirill A. Bronnikov
., Vladivostok 690041, Russia 2Institute of Chemistry FEB RAS, 159 Pr-t. 100-letiya Vladivostoka, Vladivostok 690022, Russia 3Institute of Automation and Electrometry of the SB RAS, 1 Acad.
At faster scanning speed, no surface modification was found indicating threshold character of the modification process, while at slower scanning speed providing stronger overlapping between incoming pulses the formation of periodical modulation of surface profile, laser induced periodic surface structures (LIPSS), were appeared.
Spicer, Electronic structure of amorphous Si from photoemission and optical studies, Phys.
Online since: February 2021
Authors: Francis Darwin T. Eugenio, Bryan B. Pajarito
Introduction Metals are primarily used as a material for structures due to their inherent strength.
Composition of WPS before and after comminution measured by XRF Before Comminution After Comminution Element Concentration [ppm] Element Concentration [ppm] Ca 245 ± 20.9 Ca 140 ± 15 Cl 369 ± 83.6 Cl 318 ± 73.7 Cu 27.6 ± 1.6 Cu 7.5 ± 0.7 Fe 397 ± 8.9 Fe 2573 ± 19.8 Ga Not detected Ga 0.6 ± 0.2 Mn Not detected Mn 10.9 ± 2.2 Pb 0.6 ± 0.4 Pb 0.5 ± 0.3 Sb 81.3 ± 30.5 Sb 99.2 ± 29.8 Sr 2.2 ± 0.5 Sr 2.5 ± 0.5 Ti 7963 ± 76.7 Ti 4658 ± 53.2 Zn 97.6 ± 3 Zn 125 ± 2.9 Chemical Structure of WPS.
Bruice: Organic Chemistry, 5th Edition (Pearson, USA 2007)
Online since: May 2011
Authors: Prasad P. Prabhu, K.B. Prakash, Deepak N. Mudgal
The modern sky scrappers and the recent earthquakes demand high strength and high ductility in the concrete structure.
It uses extensively the pozzolnic properties of highly refined silica fume and optimization of the Portland cement chemistry to produce the highest strength hydrates [1].
CONCLUSION Based on the experimentation conducted, following conclusions can be drawn 1) Use of mono-fibers and hybrid fibers in SFC considerably reduces the strength deterioration due to chloride attack. 2) Overall performance of the Strength properties of SFC produced with different hybrid Fibers such as (SF+GIF), (SF+WCSF), (SF+HDPEF) and (SF+PPF) are better as compared to SFC produced with respective mono Fibers and without any fiber during chloride attack. 3) Strength characteristics of SFC with (SF+GIF) and (SF+WCSF) have yielded higher strength characteristics as compare to (SF+HDPEF) and (SF+PPF) even under chloride attack. 4) SFC produced with hybrid Fibers can be used in earthquake resistant structure, which is characterized by more energy absorption.
Online since: February 2013
Authors: De Jiang Li, Ying Zheng Liu, Yin Peng Zhou, Bin Chen, Xiao Qin Zeng, Wen Jiang Ding
Generally, Mg alloys have poor workability due to their h.c.p crystal structure.
The phase structure and morphology were characterized by transmission electron microscopy (TEM JEOL 2010 operated at an acceleration voltage of 200 kV).
Kamado, Chemistry of nanoscale precipitates in Mg-2.1Gd-0.6Y-0.2Zr (at.%) alloy investigated by the atom probe technique, Mater.