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Online since: May 2006
Authors: Krystyna Holderna-Natkaniec, Ireneusz Natkaniec, Dorota Nowak, Kazimierz Jurga, Andrzej Szyczewski
Structure of norethisterone molecule with used atoms notation.
The study was undertaken to establish the dynamics of protons, especially those in methyl groups by the methods of 1H NMR, inelastic incoherent neutron scattering and quantum chemistry calculations.
Calculation of the theoretical vibrational spectra by the methods of quantum chemistry ( density functional theory methods -DFT) permits determination of the frequency and intensity of the normal modes.
The low-temperature Gexp(ν) spectrum was compared with that calculated by the methods of quantum chemistry in the isolated molecule approach.
G(ν) spectra The optimisation of the molecule structure and the force field calculation (as the second derivative of the molecule energy with respect to the atom displacement) performed by the methods of quantum chemistry permitted determination of the positions of normal modes in the vibrational spectrum and the amplitude of the atoms' displacements from the equilibrium position.
The study was undertaken to establish the dynamics of protons, especially those in methyl groups by the methods of 1H NMR, inelastic incoherent neutron scattering and quantum chemistry calculations.
Calculation of the theoretical vibrational spectra by the methods of quantum chemistry ( density functional theory methods -DFT) permits determination of the frequency and intensity of the normal modes.
The low-temperature Gexp(ν) spectrum was compared with that calculated by the methods of quantum chemistry in the isolated molecule approach.
G(ν) spectra The optimisation of the molecule structure and the force field calculation (as the second derivative of the molecule energy with respect to the atom displacement) performed by the methods of quantum chemistry permitted determination of the positions of normal modes in the vibrational spectrum and the amplitude of the atoms' displacements from the equilibrium position.
Online since: February 2012
Authors: Jun Fang, Chang Ming Zhang, Yi Xu Yang
Preparation and characterization of polymer electrolyte membranes by radiation grafted copolymerization
Jun Fang1,a*, Changming Zhang1 and Yixu Yang1
Department of Chemical & Biochemical Engineering, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China
ajfang@mail.xmu.edu.cn
* Corresponding author.
The structure of the membranes was studied by Fourier transform infrared (FT-IR).
The structures of the ETFE membrane and the resulting AEM were characterized by FT-IR.
[6] Wei Li, Jun Fang, Ming Lv, Cuixue Chen, Xianjun Chi, Yixu Yang and Yanmei Zhang,Journal of Materials Chemistry,vol. 21(2011), p. 11340
The structure of the membranes was studied by Fourier transform infrared (FT-IR).
The structures of the ETFE membrane and the resulting AEM were characterized by FT-IR.
[6] Wei Li, Jun Fang, Ming Lv, Cuixue Chen, Xianjun Chi, Yixu Yang and Yanmei Zhang,Journal of Materials Chemistry,vol. 21(2011), p. 11340
Online since: October 2012
Authors: Yang Zou, Lian Qun Zhang, Yin Zhi Jiang, Huo Ying Xu
Synthesis and Crystal Structure of a new Cu2+complex
Xu Huo-Ying 1, a , Jiang Yin-Zhi1,b, Zou Yang1, c, Zhang Lian-Qun1, d
1 Department of Chemistry, Zhejiang Sci-Tech University , Hangzhou 310018,P.R.
The structure was solved by direct methods (SHELX-97) and expanded with successive Fourier technique.
The non-hydrogen atoms were refined anis-tropically and the hydrogen atoms were located and added to the structure factor calculations with their positions being fixed.
The data of hydrogen bonds is listed in Table 3.The molecular structure of the title compound with atom numbering scheme is showed in Fig.1.
Acknowledgments This work was financially supported by National Natural Science Foundation of China (No. 20901067) and Zhejiang Provincial Top Key Academic Discipline of Applied Chemistry and Eco-Dyeing & Finishing Engineering (ZYG2010004).
The structure was solved by direct methods (SHELX-97) and expanded with successive Fourier technique.
The non-hydrogen atoms were refined anis-tropically and the hydrogen atoms were located and added to the structure factor calculations with their positions being fixed.
The data of hydrogen bonds is listed in Table 3.The molecular structure of the title compound with atom numbering scheme is showed in Fig.1.
Acknowledgments This work was financially supported by National Natural Science Foundation of China (No. 20901067) and Zhejiang Provincial Top Key Academic Discipline of Applied Chemistry and Eco-Dyeing & Finishing Engineering (ZYG2010004).
Online since: October 2011
Authors: Mohd Hamdi Bin Abd Shukor, Sharifah Adzila Syed Abu Bakar, Iis Sopyan
Rotation speed and milling time affected the obtained powders with nanocrystallite HA structure.
Gan: Journal of Materials Chemistry Vol. 9 (1999) p. 1635-1639 [12] I.
Hamdi: Indian Journal of Chemistry Vol. 47A (2008), p. 1626-1631 [13] A.S.F.
Sopyan: Indian Journal of Chemistry Vol. 48A (2009), p. 1492-1500 [14] B.
BO: Inorganic Chemistry Vol. 13 (1974), p. 207–214 [25] D.
Gan: Journal of Materials Chemistry Vol. 9 (1999) p. 1635-1639 [12] I.
Hamdi: Indian Journal of Chemistry Vol. 47A (2008), p. 1626-1631 [13] A.S.F.
Sopyan: Indian Journal of Chemistry Vol. 48A (2009), p. 1492-1500 [14] B.
BO: Inorganic Chemistry Vol. 13 (1974), p. 207–214 [25] D.
Online since: May 2011
Authors: Yun Wu Zheng, Zhi Feng Zheng, Yuan Bo Huang, Hao Feng
Ono et al.[19] reported a possible chemistry of phenol assisted liquefaction: cellulose is degraded to cello-oligosaccharides and glucose by sulfuric acid catalyst, then its pyranose ring structure is subject to decomposition and then recombination of its decomposed fragments and phenols would occur in the process of liquefaction.
Therefore, it is possible to adjust the structure and properties of the end resulting liquefied products by controlling these reaction conditions.
Mun: Journal of Industrial and Engineering Chemistry, Vol.8 (2002), p. 359
Ling: Chemistry and Industry of Forest Products, Vol.27 (2007), p. 31
Jang: Journal of Industrial and Engineering Chemistry, Vol.15 (2009), p. 743
Therefore, it is possible to adjust the structure and properties of the end resulting liquefied products by controlling these reaction conditions.
Mun: Journal of Industrial and Engineering Chemistry, Vol.8 (2002), p. 359
Ling: Chemistry and Industry of Forest Products, Vol.27 (2007), p. 31
Jang: Journal of Industrial and Engineering Chemistry, Vol.15 (2009), p. 743
Online since: July 2011
Authors: Xiang Nan Sun, Yong Ji Weng, Yin Chun Hu, Qiong Zhou
This cable structure arises from the comparison of integration between CNT-PA6 and PA6-PA6.
When the bond between CNTs and matrix is stronger, the cable structure may be found.
Macromolecular Chemistry and Physics.
Akhmetov: General and Inorganic Chemistry (Mir Publishers 1983)
Journal of Materials Chemistry.
When the bond between CNTs and matrix is stronger, the cable structure may be found.
Macromolecular Chemistry and Physics.
Akhmetov: General and Inorganic Chemistry (Mir Publishers 1983)
Journal of Materials Chemistry.
Online since: November 2015
Authors: Bin Fei, Lai Lai So, Liang He, K.K.L. Cheuk, John H. Xin
DOPA has two main functional groups of catechol and ethylamine, which are also found in the chemical structure of dopamine.
Fig. 1 Chemical structures of the compounds used in this study.
Thus, their subsequent polymerization chemistry was altered and the demonstrated color appearances on wool fabrics were easily tuned.
It is promising to be as an alternative to the conventional dyeing in view of green dyeing process and sustainability of textile chemistry.
[10] Lee, H., et al., Mussel-inspired surface chemistry for multifunctional coatings, Science. 2007. 318: p. 426-430
Fig. 1 Chemical structures of the compounds used in this study.
Thus, their subsequent polymerization chemistry was altered and the demonstrated color appearances on wool fabrics were easily tuned.
It is promising to be as an alternative to the conventional dyeing in view of green dyeing process and sustainability of textile chemistry.
[10] Lee, H., et al., Mussel-inspired surface chemistry for multifunctional coatings, Science. 2007. 318: p. 426-430
Online since: August 2011
Authors: Zhong Chen, Yan Feng Wu, Kun Wang, Yong Gao, Chun Hui Du
So controlling of the crystal structure of PVDF membranes became very important.
Recent years,ionic liquids (ILs) are attracting much attention for applications in many fields of chemistry and industry due to their chemical stability, thermal stability, low vapor pressure and high ionic conductivity properties.
For the pure PVDF membranes, a more dense structure was found, and no obvious pore structure appeared at surface of the membranes.
As for the cross-section structure of the membrane, with the addition of ionic liquid, large finger-like pore structure formed, and a more sponge-like structure also appeared at the bottom surface of the membrane (M2 and M3).
Otherwise, the enhanced pore structure also increased the hydrophobic of PVDF membranes.
Recent years,ionic liquids (ILs) are attracting much attention for applications in many fields of chemistry and industry due to their chemical stability, thermal stability, low vapor pressure and high ionic conductivity properties.
For the pure PVDF membranes, a more dense structure was found, and no obvious pore structure appeared at surface of the membranes.
As for the cross-section structure of the membrane, with the addition of ionic liquid, large finger-like pore structure formed, and a more sponge-like structure also appeared at the bottom surface of the membrane (M2 and M3).
Otherwise, the enhanced pore structure also increased the hydrophobic of PVDF membranes.
Online since: May 2012
Authors: Jin He Jiang
Study of The Inorganic Ion Exchanger Li3Mn0.25Ti0.5O3
Jinhe Jiang
MicroScale Science Institute , Department of Chemistry and Chemical Engineering ,Weifang University, Weifang, 261061,China
Corresponding author.
The structure of compound metal oxide Li3Mn0.25Ti0.5O3crystallized at 800˚C was much perfect.
As shown, the structure of LiMnTi-800(H) is nearly constant, which is spinel oxide type too.
LiMn2O4 doped elements on the structure and properties [J].
Journal of Physics and Chemistry of Solids , 2007, 68: 780-784.
The structure of compound metal oxide Li3Mn0.25Ti0.5O3crystallized at 800˚C was much perfect.
As shown, the structure of LiMnTi-800(H) is nearly constant, which is spinel oxide type too.
LiMn2O4 doped elements on the structure and properties [J].
Journal of Physics and Chemistry of Solids , 2007, 68: 780-784.
Online since: August 2018
Authors: Guy Vereecke, Farid Sebaai, Sylvain Baudot, Fumihiro Amemiya, Kana Komori, Frank Holsteyns, Xiu Mei Xu
The key elements that induce pattern collapse during a drying step are the capillarity forces between structures and the adhesion forces which are dependent of the surface energy of the structures [1-2].
To continue the wet clean after Fin etch on structures having even higher aspect ratios, a drying technique using a surface functionalization chemistry (SFC) has been evaluated and introduced.
A qualitative analysis of the collapsed structures vs non collapsed structures is shown in figure 1.
Typically, 24 structures are measured over 13 locations (312 inspected structures in total).
Using a clean with the SFC implies the implementation of a post treatment which has to preserve the FIN structures to remove organic contamination that may cause gate leakage while preserving the FIN structures.
To continue the wet clean after Fin etch on structures having even higher aspect ratios, a drying technique using a surface functionalization chemistry (SFC) has been evaluated and introduced.
A qualitative analysis of the collapsed structures vs non collapsed structures is shown in figure 1.
Typically, 24 structures are measured over 13 locations (312 inspected structures in total).
Using a clean with the SFC implies the implementation of a post treatment which has to preserve the FIN structures to remove organic contamination that may cause gate leakage while preserving the FIN structures.