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Online since: June 2011
Authors: H.V. Atkinson, Tian Xiang Liu, Simon P.A. Gill
The results are then passed up to a grain-level simulation where the response of a statistically significant particle ensemble is simulated via the evolution of particle distributions.
The growth of embrittling phases, particularly on the grain boundary, can also reduce the ductility of the material.
The instantaneous state of a material microstructure is assumed to be characterized by the mean grain size, the mean dislocation density and the number, size, location and composition of the different precipitate phases.
In this paper we restrict our consideration to the evolution of the precipitate phases, as little change in the grain size in IN617 is observed (due to the generous coating of carbides along the grain boundaries).
The subsequent decrease in particle number is due to coarsening.
The growth of embrittling phases, particularly on the grain boundary, can also reduce the ductility of the material.
The instantaneous state of a material microstructure is assumed to be characterized by the mean grain size, the mean dislocation density and the number, size, location and composition of the different precipitate phases.
In this paper we restrict our consideration to the evolution of the precipitate phases, as little change in the grain size in IN617 is observed (due to the generous coating of carbides along the grain boundaries).
The subsequent decrease in particle number is due to coarsening.
Online since: November 2016
Authors: Rustam Kaibyshev, Andrey Belyakov, Iaroslava Shakhova, Marina Tikhonova
All these techniques resulted in pronounced grain refinement.
Currently, austenitic stainless steels are widely used for a number of structural applications [3].
This microstructure is composed of alternating nano-scale austenite and matrensite grains.
Only austenitic nano-scale grains with an average size of ~23 nm evolve during HPT (Fig. 1c).
Langdon, Twenty-five years of ultrafine-grained materials: Achieving exceptional properties through grain refinement.
Currently, austenitic stainless steels are widely used for a number of structural applications [3].
This microstructure is composed of alternating nano-scale austenite and matrensite grains.
Only austenitic nano-scale grains with an average size of ~23 nm evolve during HPT (Fig. 1c).
Langdon, Twenty-five years of ultrafine-grained materials: Achieving exceptional properties through grain refinement.
Online since: August 2014
Authors: Lei Yang, Lu Zhang, Yun Ting Lai, Zhi Feng Luo, Wei Wei Yu, Yan Li
The results indicated that the fracture of the rod is induced by the unqualified chemical composition: a large number of inclusions which distribute in grain boundaries reduce the material plasticity and toughness, and eventually cause fracture.
The segregation of s along grain boundaries can weaken the gain boundary strength and induce the embrittlement eventually.
A large number of inclusions can be observed homogeneously distributed in matrix from Fig.4.
The results indicated that matrix metallographic structure is ferrite and pearlite, and the grade of grain size is 7-9, whether horizontal or vertical section.
(3)A large number of inclusions which distribute in grain boundaries reduce the material plasticity and toughness, and eventually cause fracture.
The segregation of s along grain boundaries can weaken the gain boundary strength and induce the embrittlement eventually.
A large number of inclusions can be observed homogeneously distributed in matrix from Fig.4.
The results indicated that matrix metallographic structure is ferrite and pearlite, and the grade of grain size is 7-9, whether horizontal or vertical section.
(3)A large number of inclusions which distribute in grain boundaries reduce the material plasticity and toughness, and eventually cause fracture.
Online since: March 2004
Authors: Xin Hua Wu, D. Hu, M.H. Loretto
Alloy development and grain size control
After isothermal forging the grain size is reduced to about 120µm because the borides formed on casting are broken up and pin grain boundaries during recystallisation and during grain growth.
The grain size found in ingots of Ti46Al8Nb1B is about 150µm and in this case appropriate thermomechanical processing can lead to grain refinement to produce grains of about 100µm [5].
This type of microstructure is developed because the massive gamma is full of crystal defects which increase the number of potential sites for the precipitation of alpha which can precipitate on all four {111} planes in the gamma, yielding the complex type of microstructure shown in Figure 2.
It is likely that pre-yield cracking will not be an issue in this type of alloy since it is very fine grained, with a grain size of about 10µm.
After isothermal forging the grain size is reduced to about 120µm because the borides formed on casting are broken up and pin grain boundaries during recystallisation and during grain growth.
The grain size found in ingots of Ti46Al8Nb1B is about 150µm and in this case appropriate thermomechanical processing can lead to grain refinement to produce grains of about 100µm [5].
This type of microstructure is developed because the massive gamma is full of crystal defects which increase the number of potential sites for the precipitation of alpha which can precipitate on all four {111} planes in the gamma, yielding the complex type of microstructure shown in Figure 2.
It is likely that pre-yield cracking will not be an issue in this type of alloy since it is very fine grained, with a grain size of about 10µm.
Online since: July 2020
Authors: Xiang Li, Liang Zhao, Qian Huang, Hua Yin Sun
A large number of intragranular pores and a small number of overall pores was observed in Ca-PSZ, resulting in this material having the lowest bulk density.
The grain size of Ca-PSZ is non-uniform, and most of the grains, those with an average grain diameter of around 6 μm, are densely packed, however, there are also some irregular grains, with an average grain diameter of around 10 μm, and a large number of pores, resulting in the low bulk density of the material.
The average grain size of Mg-PSZ is larger, with an average grain diameter of around 7 μm, and the grain shape is irregular.
Y-PSZ has a uniform grain size, with an average grain diameter of around 5 μm, and sharp edges.
No abnormal grain growth was observed for the sample, the grain bonding is compact, and a small number of pores exist in the material.
The grain size of Ca-PSZ is non-uniform, and most of the grains, those with an average grain diameter of around 6 μm, are densely packed, however, there are also some irregular grains, with an average grain diameter of around 10 μm, and a large number of pores, resulting in the low bulk density of the material.
The average grain size of Mg-PSZ is larger, with an average grain diameter of around 7 μm, and the grain shape is irregular.
Y-PSZ has a uniform grain size, with an average grain diameter of around 5 μm, and sharp edges.
No abnormal grain growth was observed for the sample, the grain bonding is compact, and a small number of pores exist in the material.
The Preparation and Properties of Alumina Ceramics through a Two-Step Pressureless Sintering Process
Online since: May 2018
Authors: Jian Feng Yang, Chang Suo Yuan, Qiang Zhi, Ya Ming Zhang, Xu Dong Wang, Zi Jing Wang
Higher T1 temperature and extended soaking time caused larger grain size, which accompanied with the Ostwald ripening of the grain and led to non-uniformity of grain size distribution.
This was mainly because of the pinning of the grain boundary by MgO as the second phase, which inhibited the grain growth to get grain refinement.
So there were more residual pores in the grain, and the grain heterogeneity was obvious.
With the increase of the soaking time, it could be seen from Fig.5 (b) and Fig.5 (c) that the small grains were gradually disappeared and the number of the grain with larger size increased, which also proved that the Ostwald ripening phenomenon occurred in the long soaking time.
The grain boundary was pinned by MgO as the second phase, resulting in hindrance of grain growth and grain refinement
This was mainly because of the pinning of the grain boundary by MgO as the second phase, which inhibited the grain growth to get grain refinement.
So there were more residual pores in the grain, and the grain heterogeneity was obvious.
With the increase of the soaking time, it could be seen from Fig.5 (b) and Fig.5 (c) that the small grains were gradually disappeared and the number of the grain with larger size increased, which also proved that the Ostwald ripening phenomenon occurred in the long soaking time.
The grain boundary was pinned by MgO as the second phase, resulting in hindrance of grain growth and grain refinement
Online since: October 2008
Authors: Stuart Hampshire
Sintered SiAlONs are of two types with different microstructural features [22, 25]: (1) β-sialon
grains plus glass, (2) β sialon grains plus crystalline YAG.
As the grain boundary composition changes, the aspect ratios of β grains vary and grain coarsening also occurs as sintering time or temperature is increased.
Effects of Grain Boundary Glass on Properties.
Grain boundary chemistry affects interfacial bond strengths.
Other practical advantages of high toughness values (KIc = 7-10 MPa.m1/2) include resistance to machining damage and improved fatigue behavior, KIc increasing with the volume fraction of elongated grains and proportional to (grain size) 1/2, an effect due to "crack wake mechanisms", such as crack bridging, grain rotation and grain pullout.
As the grain boundary composition changes, the aspect ratios of β grains vary and grain coarsening also occurs as sintering time or temperature is increased.
Effects of Grain Boundary Glass on Properties.
Grain boundary chemistry affects interfacial bond strengths.
Other practical advantages of high toughness values (KIc = 7-10 MPa.m1/2) include resistance to machining damage and improved fatigue behavior, KIc increasing with the volume fraction of elongated grains and proportional to (grain size) 1/2, an effect due to "crack wake mechanisms", such as crack bridging, grain rotation and grain pullout.
Online since: September 2013
Authors: Li Jing Qi, Wen Yan Liu, Hai Yan Wang
Grain size of NiO and SDC could be estimated from the diffraction peaks according to Scherrer equation expressed as[5]:
Table 1 Cell parameter and grain size of NiO and SDC Sample Cell parameters Volume Average grain size A(×10-1nm) V(×10-3nm3) D(nm) NiO SDC NiO SDC NiO SDC NiO400-SDC400 3.965 5.427 62.4 159.9 30.1 15.6 NiO600-SDC600 3.969 5.428 62.6 160.0 56.5 19.7 NiO800-SDC800 3.969 5.430 62.6 160.1 63.4 44.8 The grain size of NiO powders calcined at 400, 600 and 800℃ is 30.1, 56.5 and 63.4nm, and the size of SDC is 15.6, 19.7 and 44.8 nm.
As shown in Table 1, there is grain growth with calcining temperatures from XRD lines broadening.
Thus, the high performance of this anode seems to be attributable to the increase in the number of active sites at the boundary between Ni, SDC and H2 gas.
As shown schematically, the Ni grains form a skeleton with well-connected SDC grains finely distributed over the Ni grains surfaces.
Table 1 Cell parameter and grain size of NiO and SDC Sample Cell parameters Volume Average grain size A(×10-1nm) V(×10-3nm3) D(nm) NiO SDC NiO SDC NiO SDC NiO400-SDC400 3.965 5.427 62.4 159.9 30.1 15.6 NiO600-SDC600 3.969 5.428 62.6 160.0 56.5 19.7 NiO800-SDC800 3.969 5.430 62.6 160.1 63.4 44.8 The grain size of NiO powders calcined at 400, 600 and 800℃ is 30.1, 56.5 and 63.4nm, and the size of SDC is 15.6, 19.7 and 44.8 nm.
As shown in Table 1, there is grain growth with calcining temperatures from XRD lines broadening.
Thus, the high performance of this anode seems to be attributable to the increase in the number of active sites at the boundary between Ni, SDC and H2 gas.
As shown schematically, the Ni grains form a skeleton with well-connected SDC grains finely distributed over the Ni grains surfaces.
Online since: January 2012
Authors: E.N. Popova, E.P. Romanov, E.A. Dergunova, A.E. Vorobyova, S.M. Balaev, I.L. Deryagina
A zone of fine grains is located next to the columnar ones, and at an interface with the bronze matrix much coarser grains are seen.
The Nb3Sn grains in continuous diffusion layers get larger by a factor of 1.5 and the grain size scattering broadens (Fig. 3, Table 1).
As seen from Table 1, Ti does not result in grain refinement of superconducting layers, which we already observed in a number of previous studies [8,11,16].
Parameters of Nb3Sn grain size distribution No.
There is a zone of columnar grains adjacent to the residual Nb, a zone of fine equiaxed grains and some amount of coarser grains at an interface with the bronze matrix, which is typical of bronze-processed wires.
The Nb3Sn grains in continuous diffusion layers get larger by a factor of 1.5 and the grain size scattering broadens (Fig. 3, Table 1).
As seen from Table 1, Ti does not result in grain refinement of superconducting layers, which we already observed in a number of previous studies [8,11,16].
Parameters of Nb3Sn grain size distribution No.
There is a zone of columnar grains adjacent to the residual Nb, a zone of fine equiaxed grains and some amount of coarser grains at an interface with the bronze matrix, which is typical of bronze-processed wires.
Online since: March 2007
Authors: Isabel Gutiérrez, Amaia Iza-Mendia, M. Díaz-Fuentes
�-fibre
grains (ND-fibre grains) are, in general terms, more fragmented than �-fibre grains (RD-fibre
grains).
This technique enables the orientation of deformation bands, the misorientation across them, the orientation of the new recrystallized grains and the misorientation of those grains with the adjacent matrix grains to be determined.
In zones 3 and 4 a great number of low angle boundaries (<15°) parallel to RD originate, which intersect with the microbands running perpendicular, as can be seen in the image quality map.
The orientations of the recrystallized grains numbered from 1 to 9 in the figure and the misorientation angle/axis with respect to neighboring zones are gathered in Fig. 3-c.
Conf. on Rex. and Grain Growth, Trans.
This technique enables the orientation of deformation bands, the misorientation across them, the orientation of the new recrystallized grains and the misorientation of those grains with the adjacent matrix grains to be determined.
In zones 3 and 4 a great number of low angle boundaries (<15°) parallel to RD originate, which intersect with the microbands running perpendicular, as can be seen in the image quality map.
The orientations of the recrystallized grains numbered from 1 to 9 in the figure and the misorientation angle/axis with respect to neighboring zones are gathered in Fig. 3-c.
Conf. on Rex. and Grain Growth, Trans.