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Online since: May 2011
Authors: Saneel K. Thakur, Deepshikha Sharma
Thakur2
1Department of Chemistry, Singhania University,
Pacheri Bari, Distt. - Jhunjhunu, Rajasthan,
India
2Department of Chemistry, Sri Sai University,
Palampur, Distt.
Recent studies indicate that structure of a-Se having two fold coordination consists of randomly mixed long polymeric Sen chains in which various portions of a chain have ring fragments [7].
As Bi is introduced to host Se-Te alloy, this may create the compositional disorder in the structure of Se-Te alloy which may further leads the change in optical, electrical and thermal properties.
Recent studies indicate that structure of a-Se having two fold coordination consists of randomly mixed long polymeric Sen chains in which various portions of a chain have ring fragments [7].
As Bi is introduced to host Se-Te alloy, this may create the compositional disorder in the structure of Se-Te alloy which may further leads the change in optical, electrical and thermal properties.
Online since: October 2012
Authors: Hai Ping Zheng, Chen Chen Zheng, Jian Xuan Shang
Occurrence structure of China rich in coal but poor in oil, it is a long-term strategy to make full use of coal resources, vigorously develop coal chemical industry, promote the balanced development of economy and society[2].
We induct 10 main kinds of influent factors of the coal chemical industry in Shaanxi province, which are industrial policy, market size, market structure, market growth rates, industrial profit rate, industrial competition strength, technical requirements, capital demand, environmental protection &safety requirements and substitute; And we also induct 10 main kinds of influent factors of the coal chemical enterprise competitiveness in Shaanxi, which are development strategy conformity degree, products association degree, natural resource to meet the satisfaction degree, human resources, market share, relative market share, marketing satisfaction, technology maturity, sales contribution rate and investment profit margins[4].
Wang :Journal of Liaoning Technical University(Natural Science) (2011)No.5,pp.11-14(in Chinese) [5] S.G.Gagarin: Coke and Chemistry,(2008)No,pp.83-84 [6] M.V.Davydov: Coke and Chemistry, (2009)No,pp.31-33
We induct 10 main kinds of influent factors of the coal chemical industry in Shaanxi province, which are industrial policy, market size, market structure, market growth rates, industrial profit rate, industrial competition strength, technical requirements, capital demand, environmental protection &safety requirements and substitute; And we also induct 10 main kinds of influent factors of the coal chemical enterprise competitiveness in Shaanxi, which are development strategy conformity degree, products association degree, natural resource to meet the satisfaction degree, human resources, market share, relative market share, marketing satisfaction, technology maturity, sales contribution rate and investment profit margins[4].
Wang :Journal of Liaoning Technical University(Natural Science) (2011)No.5,pp.11-14(in Chinese) [5] S.G.Gagarin: Coke and Chemistry,(2008)No,pp.83-84 [6] M.V.Davydov: Coke and Chemistry, (2009)No,pp.31-33
Online since: June 2020
Authors: Agris Bērziņš, Kristaps Saršūns
Molecular structure of 2-substituted 4-nitrobenzoic acid.
In this article, we summarize key aspects of solid solution formation and try to identify an approach for prediction of solid solution formation using quantum chemistry calculations.
Several ratios of native and derivative molecules have been investigated: ratios 1:0 (original structure, P21/c), 0:1 (isostructural structure, P21/c) and 3:1 (substituted structure, P1).
If we compare lattice energy of original structure to fully isostructural structure, it gives more detailed information about in which case structure will be more energy efficient (see Table 4).
Total energy changes between original structure and fully isostructural structure Isostructural to ΔE [kJ·mol-1] 2Cl-original structure 2CH3-original structure 2OH-original structure 2Cl4NBA structure - 0.4 – 6.5 2CH34NBA structure 8.9 - – 0.9 2OH4NBA structure 29.5 10.9 - The main thing to observe is that in the case of 2-hydroxy-4-nitrobenozic, the original structure is the most advantageous, and 2OH4NBA molecule can easily replace Cl or CH3 molecules in crystalline lattice.
In this article, we summarize key aspects of solid solution formation and try to identify an approach for prediction of solid solution formation using quantum chemistry calculations.
Several ratios of native and derivative molecules have been investigated: ratios 1:0 (original structure, P21/c), 0:1 (isostructural structure, P21/c) and 3:1 (substituted structure, P1).
If we compare lattice energy of original structure to fully isostructural structure, it gives more detailed information about in which case structure will be more energy efficient (see Table 4).
Total energy changes between original structure and fully isostructural structure Isostructural to ΔE [kJ·mol-1] 2Cl-original structure 2CH3-original structure 2OH-original structure 2Cl4NBA structure - 0.4 – 6.5 2CH34NBA structure 8.9 - – 0.9 2OH4NBA structure 29.5 10.9 - The main thing to observe is that in the case of 2-hydroxy-4-nitrobenozic, the original structure is the most advantageous, and 2OH4NBA molecule can easily replace Cl or CH3 molecules in crystalline lattice.
Online since: March 2014
Authors: Li Li Lv, Bao Liu, Dong Mei Zhao, Yu Hong Du
The electrodes had lamellar structure, which could contribute to the adsorption of gold nanoparticles on electrode surface.
Obviously, GO possesses folding surface and relatively thin layer structure, which is due to the ultrasonic in post-treatment.
The structure of AG becomes flakiness and thicker than that of GO because of the modification of amidogen.
The GO has obvious lamellar structure and fold surface.
Kamat: The Journal of Physical Chemistry C vol. 113(2009), p. 7990 [3] Q.M.
Obviously, GO possesses folding surface and relatively thin layer structure, which is due to the ultrasonic in post-treatment.
The structure of AG becomes flakiness and thicker than that of GO because of the modification of amidogen.
The GO has obvious lamellar structure and fold surface.
Kamat: The Journal of Physical Chemistry C vol. 113(2009), p. 7990 [3] Q.M.
Online since: July 2011
Authors: Kun Kun Han, Yu Zhou, Jing Jia Wen, Jian Hua Zhu
Novel CO2 capturer derived from SBA-15 monolith coated with amine
Kunkun Han, Yu Zhou, Jingjia Wen, Jianhua Zhu*
Key Laboratory of Mesoscopic Chemistry of the Ministry of Education, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, China, E-mail: jhzhu@mail.nju.edu.cn
Keywords: SBA-15 monolith; 3D net-linked; CO2 adsorption; Environment protection
Abstract A new strategy of preparing the efficient CO2 adsorbent without further molding is reported in this article.
However, these in situ coating TEPA composites did not have the well ordered mesoporous structure; besides, it is unknown whether the monolith coated with TEPA in post-modification can exhibit such high adsorptive capability.
Results and Discussion Structure characterization Figure 1A unveils the macroscopic appearance of SM sample, while SBA-15 presents the powdery appearance.
Also, they yielded a narrow pore-size distribution with a mean value of around 9.0 nm from the adsorption progress, mirroring the almost same textual structure of SM to SBA-15 (Fig. 3A, Table 1).
However, this composite is still less active in adsorption of CO2 than our previously reported in situ coated mesoporous composite (170 mg g-1, [6]), because of the different type of host pore structure and different coating procedure of TEPA guest that strongly affect the final function of adsorbent.
However, these in situ coating TEPA composites did not have the well ordered mesoporous structure; besides, it is unknown whether the monolith coated with TEPA in post-modification can exhibit such high adsorptive capability.
Results and Discussion Structure characterization Figure 1A unveils the macroscopic appearance of SM sample, while SBA-15 presents the powdery appearance.
Also, they yielded a narrow pore-size distribution with a mean value of around 9.0 nm from the adsorption progress, mirroring the almost same textual structure of SM to SBA-15 (Fig. 3A, Table 1).
However, this composite is still less active in adsorption of CO2 than our previously reported in situ coated mesoporous composite (170 mg g-1, [6]), because of the different type of host pore structure and different coating procedure of TEPA guest that strongly affect the final function of adsorbent.
Online since: September 2014
Authors: Marcus Vinícius Lia Fook, Thiago Bizerra Fideles, M.E.R.R.M. Cavalcanti, Ana C.B.M. Fook, Greyce Yane Honorato Sampaio
The Fig. 1(a) illustrates the structure of chitosan.
Fig. 1: Structure of (a) chitosan and (b) genipin.
This structure is able to retain a higher amount of water.
Peng: Journal of Polymer Science Part A: Polymer Chemistry Vol. 43 (10) (2005), p. 1985
Pudney: Journal of Polymer Science Part A Polymer Chemistry Vol. 41 (24) (2003), p. 3941
Fig. 1: Structure of (a) chitosan and (b) genipin.
This structure is able to retain a higher amount of water.
Peng: Journal of Polymer Science Part A: Polymer Chemistry Vol. 43 (10) (2005), p. 1985
Pudney: Journal of Polymer Science Part A Polymer Chemistry Vol. 41 (24) (2003), p. 3941
Online since: June 2013
Authors: Qiang Shen, Xiao Juan Jiang, Guo Qiang Luo, Mei Juan Li, Lian Meng Zhang
Simultaneously, the characteristic peak at approximately 38.3o, 44.4o, 64.5o and 77.6o are correspond to the Ag structure, which is due to the Ag nanoparticles are formed form Ag+ ions.
The GO is a thin sheet with a smooth surface (Fig.3a), the Ag nanoparticles homogeneous dispersion in the RGO sheets (Fig.3b, 3c, 3d), and this may be attributed to PVP adsorption on the surface of GO by strong Π-Π interaction due to the pyrrolidone of PVP close to the structure of GO [17], the PVP can protect the Ag nanoparticles via N and O coordinate with silver and form the protection layer [23].
Cui: The Journal of Physical Chemistry C.
Li: Journal of Physical Chemistry B.
Wang: Materials Chemistry and Physics.
The GO is a thin sheet with a smooth surface (Fig.3a), the Ag nanoparticles homogeneous dispersion in the RGO sheets (Fig.3b, 3c, 3d), and this may be attributed to PVP adsorption on the surface of GO by strong Π-Π interaction due to the pyrrolidone of PVP close to the structure of GO [17], the PVP can protect the Ag nanoparticles via N and O coordinate with silver and form the protection layer [23].
Cui: The Journal of Physical Chemistry C.
Li: Journal of Physical Chemistry B.
Wang: Materials Chemistry and Physics.
Online since: October 2011
Authors: Sha Zhang, Xue Chuan Wang, Liang Zhou
Study on the Pollution Characteristics of Pb and Zn in
Atmospheric Particulate
Xuechuan Wang1,a, Sha Zhang1,b, Liang Zhou2,c
1 Key Laboratory of Chemistry and Technology for Light Chemical Industry, Ministry of Education, Shaanxi University of Science & Technology, Xi’an Shaanxi, China
2 Xi'an Municipal Research Institute of Environmental Protection, Xi’an Shaanxi, China
awangxc@sust.edu.cn, bshasha20686@163.com, cliangzi.zhou@163.com
Key words: TSP, Pb, Zn, total content, chemical form, bioavailability
Abstract.
In the recent years, the energy structure, industrial structure, quantity of vehicle and other factors which directly related to heavy metal pollution in TSP of Xi’an were changed greatly.
Vol. 72 (1994), p. 227-235 [2] Adamson I Y R, Prieditis H: Toxicology and Applied Pharmacology Vol. 166 (2000), p. 111-119 [3] Mathew R H, Leon R H: Atmospheric Environment Vol. 39 (2005), p. 1417-1430 [4] Tao Lou: Instrumentation and analysis and monitoring Vol. 2 (2006), p. 37-38 [5] Tessier A: Analysis Chemistry Vol. 51 (1979), p. 844-851 [6] Xin Wang, Qixing Zhou: Journal of Agro-Environment Science Vol. 22 (2003), p. 541-545 [7] Qiandan Feng, Zhi Dang, Weilin Huang: Environmental Science Vol. 29 (2008), p. 569-575 [8] Adriano D C, in: Trace elements in terrestrial environments: biogeochemistry, bioavailability and risks of metals, edtied by Springer-Verlag, New York (2001) [9] Yongxiang Han, Qiang Zhang, Guangrong Dong: Chinese Desert Vol. 26 (2006), p. 307-311 [10] Hui Chang, Shaojin Yang: Environmental Chemistry Vol. 19 (2000), p. 485-499
In the recent years, the energy structure, industrial structure, quantity of vehicle and other factors which directly related to heavy metal pollution in TSP of Xi’an were changed greatly.
Vol. 72 (1994), p. 227-235 [2] Adamson I Y R, Prieditis H: Toxicology and Applied Pharmacology Vol. 166 (2000), p. 111-119 [3] Mathew R H, Leon R H: Atmospheric Environment Vol. 39 (2005), p. 1417-1430 [4] Tao Lou: Instrumentation and analysis and monitoring Vol. 2 (2006), p. 37-38 [5] Tessier A: Analysis Chemistry Vol. 51 (1979), p. 844-851 [6] Xin Wang, Qixing Zhou: Journal of Agro-Environment Science Vol. 22 (2003), p. 541-545 [7] Qiandan Feng, Zhi Dang, Weilin Huang: Environmental Science Vol. 29 (2008), p. 569-575 [8] Adriano D C, in: Trace elements in terrestrial environments: biogeochemistry, bioavailability and risks of metals, edtied by Springer-Verlag, New York (2001) [9] Yongxiang Han, Qiang Zhang, Guangrong Dong: Chinese Desert Vol. 26 (2006), p. 307-311 [10] Hui Chang, Shaojin Yang: Environmental Chemistry Vol. 19 (2000), p. 485-499
Online since: May 2016
Authors: A.M. Mustafa Al Bakri, Soo Jin Tan, Cheng Yong Heah, Yun Ming Liew, Hussin Kamarudin
The comparison between XRD spectra of aluminium metal powder and aluminium can showed difference at peaks at 2θ around 30° and 40° which indicate that the amorphous and crystalline structure of aluminium can.
Alum has amorphous structure.
[6] Elias, A.J., A Collection of Interesting General Chemistry Experiments. 2002: Universities Press (India) Private Limited. 74 - 77
[7] Kotz, J., et al., Chemistry and Chemical Reactivity. 9 ed. 2014: Cengage Learning
Jurs, Principles of Chemistry: The Molecular Science. 2009: Cengage Learning
Alum has amorphous structure.
[6] Elias, A.J., A Collection of Interesting General Chemistry Experiments. 2002: Universities Press (India) Private Limited. 74 - 77
[7] Kotz, J., et al., Chemistry and Chemical Reactivity. 9 ed. 2014: Cengage Learning
Jurs, Principles of Chemistry: The Molecular Science. 2009: Cengage Learning
Online since: February 2014
Authors: B. Abu Kassim Mohd Eqram, Bt. Mohd Zaid Hayyiratul Fatimah, Chong Fai Kait
The effect of Cu-Fe doping on the band structure and band gap energy is shown by the DR-UV-Vis spectra (Fig. 1).
The characteristic peaks at 2θ = 25.34°, 33.79°, 47.8°, 53.8° and 55.0° represent the crystalline structure of anatase and the peak at 2θ = 27.40° corresponded to the rutile phase of TiO2.
Zhang: Transition Metal Chemistry Vol. 35, No. 8 (2010), p.933
Gaber: Journal of Photochemistry and Photobiology A: Chemistry Vol. 114, No. 3 (1998), p. 213
Ibusuki: Journal of Photochemistry and Photobiology A: Chemistry Vol. 149, No. (1–3) (2002), p. 183
The characteristic peaks at 2θ = 25.34°, 33.79°, 47.8°, 53.8° and 55.0° represent the crystalline structure of anatase and the peak at 2θ = 27.40° corresponded to the rutile phase of TiO2.
Zhang: Transition Metal Chemistry Vol. 35, No. 8 (2010), p.933
Gaber: Journal of Photochemistry and Photobiology A: Chemistry Vol. 114, No. 3 (1998), p. 213
Ibusuki: Journal of Photochemistry and Photobiology A: Chemistry Vol. 149, No. (1–3) (2002), p. 183