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Online since: October 2006
Authors: M.C. Carotta, S. Gherardi, Isidoro Giorgio Lesci, G. Martinelli, Marco Nagliati
Martinelli
1,e
1
Physics Department, Ferrara University, I-44100 Via Saragat, 1, Ferrara, Italy
2
Chemistry Department 'G.
In the hydrothermal treatment, grain size, particle morphology, crystalline phase, and surface chemistry can be controlled via processing variables such as sol composition, pH, reaction temperature and pressure, aging time, and nature of solvent and additive.
Results and discussion The crystalline structures of sol-gel (SG) and hydrothermal (HY) titania are investigated by means of XRD analysis and shown in Table 1.
It appears that the structure of SG TiO2 changes in consequence of the temperature while the crystalline phase of HY TiO2 is anatase independently of the thermal treatment.
The mild hydrothermal synthesis would be capable of yielding a more well-defined structure with less surface impurities/defects if appropriate setup is employed to ensure complete sol-gel reaction and crystallization.
In the hydrothermal treatment, grain size, particle morphology, crystalline phase, and surface chemistry can be controlled via processing variables such as sol composition, pH, reaction temperature and pressure, aging time, and nature of solvent and additive.
Results and discussion The crystalline structures of sol-gel (SG) and hydrothermal (HY) titania are investigated by means of XRD analysis and shown in Table 1.
It appears that the structure of SG TiO2 changes in consequence of the temperature while the crystalline phase of HY TiO2 is anatase independently of the thermal treatment.
The mild hydrothermal synthesis would be capable of yielding a more well-defined structure with less surface impurities/defects if appropriate setup is employed to ensure complete sol-gel reaction and crystallization.
Online since: September 2003
Authors: Shi Pu Li, S.M. Zhang, Q.S. Tang, Y.C. Han
.,
Wuhan 430070, China, email: smzhang@mail.whut.edu.cn
2
Department of Applied Chemistry, Faculty of Science, Wuhan University of Technology,
122 Luoshi Rd.
The above results indicate that the structure P-O-Si has not been formed between HAP and the silane molecules in aqueous medium, which is quietly different from the situation in organic medium such as toluent.
All the peaks above do not exist in HAP particle, which suggests that the structures of the modified HAP particle contain parts of the silane molecule.
It is well known that the Si-O-Si structure was formed by condensation reaction between Si-OH groups produced from the silane hydrolysis by H2O molecules absorbed on the surface of HAP.
Lutton: in World Chemistry Congress (Brisbone, Astralia, 1-6 July, 2001, PA56)
The above results indicate that the structure P-O-Si has not been formed between HAP and the silane molecules in aqueous medium, which is quietly different from the situation in organic medium such as toluent.
All the peaks above do not exist in HAP particle, which suggests that the structures of the modified HAP particle contain parts of the silane molecule.
It is well known that the Si-O-Si structure was formed by condensation reaction between Si-OH groups produced from the silane hydrolysis by H2O molecules absorbed on the surface of HAP.
Lutton: in World Chemistry Congress (Brisbone, Astralia, 1-6 July, 2001, PA56)
Online since: April 2015
Authors: Triastuti Sulistyaningsih, Sri Juari Santosa, Dwi Siswanta, Bambang Rusdiarso
Preparation of Magnetite-Mg/Al Hydrotalcite through Hydrothermal Process and Subsequent Calcination
Triastuti Sulistyaningsih1,2,a, Sri Juari Santosa2,b, Dwi Siswanta2,c, and Bambang Rusdiarso2,d
1Department of Chemistry, Faculty of Mathematics and Natural Sciences, Semarang State University, Semarang, Indonesia.
2Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Yogyakarta, Indonesia.
Magnetite or ferrous ferrite (FeO.Fe2O3 or Fe3O4) is an iron oxide which has an inverse spinel structure with Fe(III) ions distributed randomly between octahedral and tetrahedral sites, and Fe(II) ions in octahedral sites [6].
The characteristic peaks of both MHT-H and MHT-NH composites indicate that both of them have a layered structure with basal spacing 7.91 Å and 8.03 Å which indicated NO3- anion in interlayer [13].
The result of XRD pattern for CMHT-H and CMHT-NH shows the presence of destruction of hydrotalcite structure because of dehydration and decomposition of the anions and exhibit a transformation from the hydrotalcite into a mixed oxide with MgO like structure or rather MgO–Al2O3 solid solution MHT-H composite has a BET specific surface area (SBET) of 63.264 m²/g, larger than MHT-NH composite (2.448 m²/g).
The calcination process exhibit a transformation from the hydrotalcite into a mixed oxide with MgO like structure or rather MgO–Al2O3 solid solution and decreasing saturation magnetization.
Magnetite or ferrous ferrite (FeO.Fe2O3 or Fe3O4) is an iron oxide which has an inverse spinel structure with Fe(III) ions distributed randomly between octahedral and tetrahedral sites, and Fe(II) ions in octahedral sites [6].
The characteristic peaks of both MHT-H and MHT-NH composites indicate that both of them have a layered structure with basal spacing 7.91 Å and 8.03 Å which indicated NO3- anion in interlayer [13].
The result of XRD pattern for CMHT-H and CMHT-NH shows the presence of destruction of hydrotalcite structure because of dehydration and decomposition of the anions and exhibit a transformation from the hydrotalcite into a mixed oxide with MgO like structure or rather MgO–Al2O3 solid solution MHT-H composite has a BET specific surface area (SBET) of 63.264 m²/g, larger than MHT-NH composite (2.448 m²/g).
The calcination process exhibit a transformation from the hydrotalcite into a mixed oxide with MgO like structure or rather MgO–Al2O3 solid solution and decreasing saturation magnetization.
Online since: March 2010
Authors: Xiao Hong Liang, Li Xing, Bo Song, Shi Wei Chen, Jun Hui Xiang, Fu Shi Zhang
Controlled Growth and Self-Assembly of CaCO3 Superstructures
Between the Organic-Water Interfaces
Liang Xiaohong1, Xiang Junhui1,a, Zhang Fushi2, Xing Li1, Song Bo
1 and
Chen Shiwei1
1
College of Chemistry and Chemical Engineering, Graduate University of Chinese Academy of
Sciences, Beijing 100049, China
2
Department of Chemistry, Tsinghua University, Beijing 100084, China
a
xiangjh@gucas.ac.cn
Keywords: Biological mineralization; Organic-water interfaces; Surfactant Monolayer
Abstract.
Organisms are capable to fabricate very complicated hierarchical structures with superior physical and chemical characteristics.
In the depositions, a large number of flower-shaped structures were observed in the image of the down-side of the product (Fig. 1a).
When 10 ml of 50 mM hexadecyltrinethyl ammonium bromide in n-Hexane was injected on the saturated Ca(OH)2 solution, flower-shaped structure could not be gotten.
The products showed tilted hexahedron stacked structures as showed in Figure 3.
Organisms are capable to fabricate very complicated hierarchical structures with superior physical and chemical characteristics.
In the depositions, a large number of flower-shaped structures were observed in the image of the down-side of the product (Fig. 1a).
When 10 ml of 50 mM hexadecyltrinethyl ammonium bromide in n-Hexane was injected on the saturated Ca(OH)2 solution, flower-shaped structure could not be gotten.
The products showed tilted hexahedron stacked structures as showed in Figure 3.
Online since: August 2014
Authors: Mariatti Jaafar, Zuratul Ain Abdul Hamid, Banhan Lila, Mitsugu Todo, Netnapa Eawwiboonthanakit
In addition, fibril structure was observed in the PLLA/PLA microsphere blend.
This fibril structure can be related to increase ductility of the sample [7].
Fibril structure is observed in PLLA/PLA microsphere blend microstructure indicating the ductility of PLLA/PLA microsphere blend.
Somwangthanaroj., Development of Packaging Film from Bioplastic Polylactic Acid (PLA) with plasticizers, Pure and Applied Chemistry International Conference 2011. (2011) 621-625
Lopez-Manchado, Structure and properties of polylactide/natural rubber blends, Materials Chemistry and Physics. 129 (2011) 823-831.
This fibril structure can be related to increase ductility of the sample [7].
Fibril structure is observed in PLLA/PLA microsphere blend microstructure indicating the ductility of PLLA/PLA microsphere blend.
Somwangthanaroj., Development of Packaging Film from Bioplastic Polylactic Acid (PLA) with plasticizers, Pure and Applied Chemistry International Conference 2011. (2011) 621-625
Lopez-Manchado, Structure and properties of polylactide/natural rubber blends, Materials Chemistry and Physics. 129 (2011) 823-831.
Online since: February 2011
Authors: Fa Mei Feng, Li Ke Zou, Bin Xie, Jia Qing Xie
Characterization of Well-Dispersed Ceo2 Nanoparticles Prepared by a New Method of Reverse Microemulsion
Famei Fenga, Jiaqing Xieb, Like Zouc and Bin Xied
College of Chemistry and Pharmaceutical Engineering, Sichuan University of Science and Engineering, Zigong(643000) , Sichuan, P.
Introduction As is well known, metal oxide particles are widely used in various applications such as electronics, optics, industrial ceramics, biochemistry and pharmaceutical industry owing to their novel structures and the corresponding unique properties.
Therefore, the studies of the preparations, structures, properties and applications of these metal oxide nanoparticles have gained much attention in the world [1-5].
From characteristic peaks in this XRD image, CeO2 can be indexed as face centered cubic structure, which corresponds to the PDF card 81-0792.
Li et al.: Journal of Natural Gas Chemistry Vol. l8(2009), 139 [18].
Introduction As is well known, metal oxide particles are widely used in various applications such as electronics, optics, industrial ceramics, biochemistry and pharmaceutical industry owing to their novel structures and the corresponding unique properties.
Therefore, the studies of the preparations, structures, properties and applications of these metal oxide nanoparticles have gained much attention in the world [1-5].
From characteristic peaks in this XRD image, CeO2 can be indexed as face centered cubic structure, which corresponds to the PDF card 81-0792.
Li et al.: Journal of Natural Gas Chemistry Vol. l8(2009), 139 [18].
Online since: January 2012
Authors: Zhen Zhou, Yong Qin, Jing Hou, Li Jie Wang
Introduction
Casein is an important component of dairy products, it mainly comprises 4 phosphorylated monomers (αS1-casein, αS2-casein, β-casein, κ-casein) which form micelle-like structure in aggregate style.
Because the structure of casein is extremely complex, the casein has many unique physicochemical properties and biological functions.
Dynamic light scattering as an important means of studying polymer molecular structure can directly determine the parameters of macromolecules in solution such as diffusion coefficient, particle size and distribution, and has the advantages of no interference with the sample, informative, simple and fast, it also has played an important role in the characterization of protein structure [2], analysis of aggregate process [3] and interaction [4,5].
Chinese Journal of Analytical Chemistry.
Journal ofAnalytical Chemistry. 2007,35(6):809 [7] C.
Because the structure of casein is extremely complex, the casein has many unique physicochemical properties and biological functions.
Dynamic light scattering as an important means of studying polymer molecular structure can directly determine the parameters of macromolecules in solution such as diffusion coefficient, particle size and distribution, and has the advantages of no interference with the sample, informative, simple and fast, it also has played an important role in the characterization of protein structure [2], analysis of aggregate process [3] and interaction [4,5].
Chinese Journal of Analytical Chemistry.
Journal ofAnalytical Chemistry. 2007,35(6):809 [7] C.
Online since: January 2016
Authors: Anthony Centeno, A.T. Hamid Toloue, M.T. Ahmadi
In recent years, graphene on Au has been fabricated and shows stable absorption of biomolecule with carbon-based ring structures [15].
The structure of the proposed SPR biosensor is depicted in Fig. 2, where the graphene layer covers a gold thin film.
[6] Homola, J., Present and future of surface plasmon resonance biosensors, Analytical and Bioanalytical Chemistry. 377 (3) (2003) 528 - 539
R., Geim, A.K., Fine structure constant defines visual transparency of graphene, Science. 320 (5881) (2008) 1308 - 1308
Recent advances in the development of graphene-based surface plasmon resonance (SPR) interfaces, Analytical and Bioanalytical Chemistry. 405(5) (2013) 1435 - 1443
The structure of the proposed SPR biosensor is depicted in Fig. 2, where the graphene layer covers a gold thin film.
[6] Homola, J., Present and future of surface plasmon resonance biosensors, Analytical and Bioanalytical Chemistry. 377 (3) (2003) 528 - 539
R., Geim, A.K., Fine structure constant defines visual transparency of graphene, Science. 320 (5881) (2008) 1308 - 1308
Recent advances in the development of graphene-based surface plasmon resonance (SPR) interfaces, Analytical and Bioanalytical Chemistry. 405(5) (2013) 1435 - 1443
Online since: September 2010
Authors: Z. Weltsch, A. Lovas
The
melts solidify in the form of single phase solid solutions, with fcc crystal structure (inherited from
the Ag host).
Consequently, the reason of varying slope Θ(T) is the consequence of the change in bulk electronic structure, caused by the host metal replacement.
B Massalski: Structure of solid solutions, Physical Metallurgy, Ch. 4, (1983)
Wenzel: Industrial & Engineering Chemistry Research 28, 988 (1936)
Allen: Surface Tension in Liquid Metals, in Liquid Metals (Chemistry and Physics) ed.
Consequently, the reason of varying slope Θ(T) is the consequence of the change in bulk electronic structure, caused by the host metal replacement.
B Massalski: Structure of solid solutions, Physical Metallurgy, Ch. 4, (1983)
Wenzel: Industrial & Engineering Chemistry Research 28, 988 (1936)
Allen: Surface Tension in Liquid Metals, in Liquid Metals (Chemistry and Physics) ed.
Online since: July 2017
Authors: Yasuhiko Hayashi, Paneer Selvam Karthik, Zaw Lin, Venkata Abhinav Korada, Masaki Hada, Takeshi Nishikawa
Introduction
Self-assembly is observed in supramolecular chemistry ever since its recognition [1].
Molecular self-assembly has complex factors and infinitesimal molecular interactions governing the congregation for structures.
In fullerene chemistry, self-assembly is being extensively studied since last decade [2, 3].
In this experiment mwcnts were integrated into fullerene nps to form hybrid networked structures.
Johnson: Crystal Structure and Growth Mechanism of Unusually Long Fullerene (C60) Nanowires, J.
Molecular self-assembly has complex factors and infinitesimal molecular interactions governing the congregation for structures.
In fullerene chemistry, self-assembly is being extensively studied since last decade [2, 3].
In this experiment mwcnts were integrated into fullerene nps to form hybrid networked structures.
Johnson: Crystal Structure and Growth Mechanism of Unusually Long Fullerene (C60) Nanowires, J.