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Online since: October 2011
Authors: Ji Shou Zhao, Li Yan, Kun Huang, Jing Chen
Key Laboratory of Ethnic Medicine Resource Chemistry,State Ethnic Affairs Commission & Ministry of Education,Yunnan University of Nationalities, Kunming 650031, PR China
2.
College of Chemistry and Material Engineering, Yunnan University, Kunming 650092, PR China 3.
College of Chemistry and Molecule Engineering, Peking University, Beijing100871, PR China aemail:zhaojishou@163.com, bemail:yanli5901@126.com, c email: hkwn2005@163.com Keywords: Platinum group metals; Pressure cyanidation; dissolution; Palladium; rotating disk Abstracts: At room temperature and pressures, the reaction between sodium cyanide and platinum group metals (PGMs) does not occur because of poor kinetics.
(5) The dissolution mechanism involves the structure and bonding mechanism of cyanide and oxygen adsorbed on palladium atom.
College of Chemistry and Material Engineering, Yunnan University, Kunming 650092, PR China 3.
College of Chemistry and Molecule Engineering, Peking University, Beijing100871, PR China aemail:zhaojishou@163.com, bemail:yanli5901@126.com, c email: hkwn2005@163.com Keywords: Platinum group metals; Pressure cyanidation; dissolution; Palladium; rotating disk Abstracts: At room temperature and pressures, the reaction between sodium cyanide and platinum group metals (PGMs) does not occur because of poor kinetics.
(5) The dissolution mechanism involves the structure and bonding mechanism of cyanide and oxygen adsorbed on palladium atom.
Online since: September 2013
Authors: Feng Wen Yu, Jian Bing Ji, Long Chao Gao, Guo Dong Zhang, Wei Jin Wang
Since the difference of molecular structures between sodium oleate and sodium stearate, the entirely different distributions of products were obtained.
Industrial and Engineering Chemistry, 1947, 39, 1543–1548
Chemistry & Bioengineering, 2008, 4(25), 1-6.
Industrial and Engineering Chemistry, 1950, 10(42), 2141-2145
Industrial and Engineering Chemistry, 1947, 39, 1543–1548
Chemistry & Bioengineering, 2008, 4(25), 1-6.
Industrial and Engineering Chemistry, 1950, 10(42), 2141-2145
Online since: February 2014
Authors: Iqbal Fauzi, Deana Wahyuningrum, I. Made Arcana
Synthesis and Characterization of Solid Polymer Electrolyte from N-Succinyl Chitosan and Lithium Perchlorate
Iqbal Fauzi1,a, I Made Arcana1,b, and Deana Wahyuningrum2,c
1Inorganic and Physical Chemistry Research Division, Faculty of Mathematics and Natural Sciences, Institut Teknologi Bandung, Indonesia
2Organic Chemistry Research Division, Faculty of Mathematics and Natural Sciences, Institut Teknologi Bandung, Indonesia
aiqbalfauzi@s.itb.ac.id, barcana@chem.itb.ac.id, cdeana@chem.itb.ac.id (corresponding authors)
Keywords: chitosan, lithium perchlorate, N-succinyl chitosan, polymer electrolyte
Abstract.
Values of conductivity (a) and mechanical strength (b) of polymer solid electrolyte Based on the diagrams in Fig. 2(a) it showed that the addition of succinyl groups in chitosan structure tends to increase the conductivity value of chitosan.
[8] Mujianto, Synthesis and Modification of Chitosan from Shrimp Waste Skin For Enhanced Oil Recovery Applications, Master Thesis, Department of Chemistry, Institute of Technology Bandung, 2012.
Values of conductivity (a) and mechanical strength (b) of polymer solid electrolyte Based on the diagrams in Fig. 2(a) it showed that the addition of succinyl groups in chitosan structure tends to increase the conductivity value of chitosan.
[8] Mujianto, Synthesis and Modification of Chitosan from Shrimp Waste Skin For Enhanced Oil Recovery Applications, Master Thesis, Department of Chemistry, Institute of Technology Bandung, 2012.
Online since: August 2014
Authors: Lukáš Kalina, David Matoušek, František Šoukal
Utilization of XPS analysis for the characterization of mechanochemical activation in polymer-cement composite materials
Lukáš Kalina1,a, David Matoušek1,b and František Šoukal1,c
1 Brno University of Technology, Faculty of Chemistry, Materials Research Centre
Purkyňova 118, 612 00 Brno, Czech Republic
akalina@fch.vutbr.cz, bxcmatousekd@fch.vutbr.cz, csoukal@fch.vutbr.cz
Keywords: X-ray photoelectron spectroscopy (XPS), mechanochemical activation, polymer-cement composite
Abstract.
However, the studies on the chemistry and the microstructure of the calcium aluminate MDF materials recognized the chemical reactions occurring between the polymer (the polyvinyl alcohol/acetate) and the inorganic ions produced when the cement dissolved in water [4].
The spectrum of calcium Ca 2p shows two different chemical states which is consistent with the structure of this phase [8].
Fig. 2 C 1s and Al 2p curve fitted XPS spectra of mechanochemicaly activated phases Conclusion The XPS analysis provides very successful method for the study of the composition and interphase structure of surface layers at the molecular level.
However, the studies on the chemistry and the microstructure of the calcium aluminate MDF materials recognized the chemical reactions occurring between the polymer (the polyvinyl alcohol/acetate) and the inorganic ions produced when the cement dissolved in water [4].
The spectrum of calcium Ca 2p shows two different chemical states which is consistent with the structure of this phase [8].
Fig. 2 C 1s and Al 2p curve fitted XPS spectra of mechanochemicaly activated phases Conclusion The XPS analysis provides very successful method for the study of the composition and interphase structure of surface layers at the molecular level.
Online since: July 2011
Authors: Gui Yang Liu, Li Li Zhang, Bao Sen Wang, Ying He, Jun Ming Guo
Low-temperature self-mixing combustion synthesis of spinel LiMn2O4: effect of igniting temperatures
Guiyang Liu1, a, Junming Guo2, Baosen Wang1, Ying He1, Zhang LiLi1
1College of Science, Honghe University, Mengzi Yunnan, China 661100
2Key Laboratory of Ethnic Medicine Resource Chemistry,State Ethnic Affairs Commission & Ministry of Education,Yunnan University of Nationalities, Kunming Yunnan, China 650031
aliuguiyang@tsinghua.org.cn
Keywords: Low-temperature self-mixing combustion synthesis, lithium ion batteries, spinel
Abstract.
The possible reasons are generally believed to originate from the Jahn-Teller distortion of the cubic spinel structure of LiMn2O4 during discharging with increasing Mn3+ in the structure, the gradually dissolution of Mn3+ to electrolyte via disproportionation reaction and the decomposition of organic solvent at higher potentials [3].
Acknowledgements The present work was supported by the National Natural Science Foundation of China (No.51062018) and by the Key Subject of Materials Physics and Chemistry of Honghe University.
The possible reasons are generally believed to originate from the Jahn-Teller distortion of the cubic spinel structure of LiMn2O4 during discharging with increasing Mn3+ in the structure, the gradually dissolution of Mn3+ to electrolyte via disproportionation reaction and the decomposition of organic solvent at higher potentials [3].
Acknowledgements The present work was supported by the National Natural Science Foundation of China (No.51062018) and by the Key Subject of Materials Physics and Chemistry of Honghe University.
Online since: July 2012
Authors: Feng Qi Zhao, Ming Wei Ji, Li Xiong Zhang, Juan Xu, Zhen Ye Ma
Synthesis of CoO and Co3O4 nanoparticles by salt-assisted
combustion method
Mingwei Ji1a, Zhenye Ma *1,2b, Juan Xu2c, Lixiong Zhang*1d, Fengqi Zhao3e
1 State Key Laboratory of Material-Oriented Chemical Engineering, Nanjing University of Technology, Nanjing 210009
2 College of Chemistry and Material Science, Nanjing Normal University,Nanjing, 210097
3 Science and technology on combustion and explosion laboratory, Xi’ an modern Chemistry Institute, Xi’ an 710065
amingweiji@126.com, bmzynjust@163.com, cxujuannanshida@163.com, dlixzhang@njut.edu.cn, ezhaofqi@163.com
Keywords: CoO, Co3O4, salt-assisted combustion, ammonium perchlorate (AP)
Abstract.
Moreover, SAED image reveals unsatisfied crystalline structure.
Conclusions In this work, different structures of CoO and Co3O4 nanoparticles have been prepared by a simple salt-assisted combustion method.
Moreover, SAED image reveals unsatisfied crystalline structure.
Conclusions In this work, different structures of CoO and Co3O4 nanoparticles have been prepared by a simple salt-assisted combustion method.
Online since: September 2014
Authors: Anna Nikolaevna Grishina, Anton Borisovich Satyukov, Evgeniy Valerjevich Korolev
Obviously, the concentration factor has a significant influence on the chemical composition, structure and properties of the products of synthesis.
Shabanova, Investigation of the Mechanism of Hardening of Hydration Products of Barium Cements, Problems of Chemistry and Chemical Technology. 1 (2003) 51-56 (in Russian)
Chukin, Surface Chemistry and Structure of Fumed Silica, Paladin LLC, Moscow, 2008
Shabanova, Investigation of the Mechanism of Hardening of Hydration Products of Barium Cements, Problems of Chemistry and Chemical Technology. 1 (2003) 51-56 (in Russian)
Chukin, Surface Chemistry and Structure of Fumed Silica, Paladin LLC, Moscow, 2008
Online since: February 2014
Authors: Xiang Jie Niu, Yan E Duan, Hua Li
Fig. 2 Wireless data receiver circuit
3 Software design
3.1 Software structure
The system will detect the water quality periodically and at other time it will be standby.
(4) Avoid network answer procedure TCP optimization protocol can reduce the times of interactive process in the wide area network in which the speed-up devices are used to replace the servers in branch structures for answering the information from client ends to ensure the answer information transmit in local networks. 3.3 System monitoring application platform The web page system application platform software contains monitoring maps, monitoring items’ data, monitoring curves, alert and technique support and inquire.
The main functions of the system control platform can display, inquire and control the water quality data information of the water source, collect the data for some specific parameter, periodically collect variable parameters according to pre-set time intervals, generate alert for the highly polluted water areas and response accordingly. 4 Experiment and analysis The system is applied in some large-scale poultry rearing district for water quality monitoring with 20 sensors, 1 monitoring substations, and 1 remote web monitoring main station which can respectively monitor PH Value, Total phosphorus concentration, chemistry oxygen consumption(COD), and ammonia concentration in the river.
Table 1 Experimental data Time Frame PH Value Total phosphorus Concentration Chemistry Oxygen consumption Ammonia Concentration 0-4 7.2 4.2 216 45.2 5-8 7.1 4.1 220 40.3 9-12 7.6 4.3 236 44.1 13-16 7.0 4.1 209 40.5 16-20 8.1 4.2 211 41.2 21-24 8.5 4.4 212 40.8 The system collects the sensors data of the water quality periodically storing in table format which can be directly downloaded to generate EXCEL format as shown in figure 3.
(4) Avoid network answer procedure TCP optimization protocol can reduce the times of interactive process in the wide area network in which the speed-up devices are used to replace the servers in branch structures for answering the information from client ends to ensure the answer information transmit in local networks. 3.3 System monitoring application platform The web page system application platform software contains monitoring maps, monitoring items’ data, monitoring curves, alert and technique support and inquire.
The main functions of the system control platform can display, inquire and control the water quality data information of the water source, collect the data for some specific parameter, periodically collect variable parameters according to pre-set time intervals, generate alert for the highly polluted water areas and response accordingly. 4 Experiment and analysis The system is applied in some large-scale poultry rearing district for water quality monitoring with 20 sensors, 1 monitoring substations, and 1 remote web monitoring main station which can respectively monitor PH Value, Total phosphorus concentration, chemistry oxygen consumption(COD), and ammonia concentration in the river.
Table 1 Experimental data Time Frame PH Value Total phosphorus Concentration Chemistry Oxygen consumption Ammonia Concentration 0-4 7.2 4.2 216 45.2 5-8 7.1 4.1 220 40.3 9-12 7.6 4.3 236 44.1 13-16 7.0 4.1 209 40.5 16-20 8.1 4.2 211 41.2 21-24 8.5 4.4 212 40.8 The system collects the sensors data of the water quality periodically storing in table format which can be directly downloaded to generate EXCEL format as shown in figure 3.
Online since: August 2014
Authors: Lin Dong, Ze Xin Yang, Meng Wang, Huan Li
Every year, many new technologies were reported in green and sustainable chemistry, which were regarded as a major scientific discipline [7-8].
Fig. 4a showed a diffuse diffraction pattern, without the sharp diffraction peak of crystalline SiO2, only at a 2θ (22°) there was a wide diffraction peaks, which indicated that the sample was mainly amorphous structure.
Comparing the XRD pattern of silica power and crystal silica showed that the sample was amorphous silica powder structure.
[8] Abderrahim Solhy, Abdelhakim Elmakssoudi, Rachid Tahir, et al., Green Chemistry. 12 (2010) 2261- 2267.
Fig. 4a showed a diffuse diffraction pattern, without the sharp diffraction peak of crystalline SiO2, only at a 2θ (22°) there was a wide diffraction peaks, which indicated that the sample was mainly amorphous structure.
Comparing the XRD pattern of silica power and crystal silica showed that the sample was amorphous silica powder structure.
[8] Abderrahim Solhy, Abdelhakim Elmakssoudi, Rachid Tahir, et al., Green Chemistry. 12 (2010) 2261- 2267.
Online since: February 2021
Authors: Dalia Mahmood Jamil, Raghda Alsayeed, Huda Ghalib Salman, Mohammed H. Al-Mashhadani
Al-Mashhadani1,d
1Department of chemistry, Collage of Science, Al -Nahrain University, Baghdad, Iraq
araghda.alasayeed@ced.nahrainuniv.edu.iq, bDmj@ced.nahrainuniv.edu.iq, chuda.ghalib@ced.nahrainuniv.edu.iq, dmohamed.hussain@ced.nahrainuniv.edu.iq
Keywords: Schiff base, Synthesis, Trimethoprim, Pseudomonas aeruginosa, biological activity.
The components have very notice thought in operation and company chemistry.
Table 1: Magnetic moment, and the suggested structure for complexesfor Fe(III) and Cd(II) Complex Magnetic moment Suggest structure Cd(II) paramagnetic Tetrahedral Fe(III) paramagnetic Tetrahydral Conclusion The drug is a hexa compound with cadmium ion (II) while high complexes form tetra with iron ion.
The components have very notice thought in operation and company chemistry.
Table 1: Magnetic moment, and the suggested structure for complexesfor Fe(III) and Cd(II) Complex Magnetic moment Suggest structure Cd(II) paramagnetic Tetrahedral Fe(III) paramagnetic Tetrahydral Conclusion The drug is a hexa compound with cadmium ion (II) while high complexes form tetra with iron ion.