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Online since: July 2022
Authors: Masaru Aniya, Hiroyuki Noda
The studies of these compounds have provided fundamental understanding on the structure-property relationship.
Although some compounds deviate from the trend, from the figure we note that most I-VII, II-VI and III-V compounds having rock-salt (RS), wurtzite (WZ) and zincblende (ZB) type structure seems to follow the curved broken line.
Batsanov, Introduction to Structural Chemistry, Springer, Dordrecht, 2012
Atkins, Physical Chemistry, 6th Ed., Oxford U.
Harrison, Electronic Structure and the Properties of Solids, Freeman, San Francisco, 1980
Although some compounds deviate from the trend, from the figure we note that most I-VII, II-VI and III-V compounds having rock-salt (RS), wurtzite (WZ) and zincblende (ZB) type structure seems to follow the curved broken line.
Batsanov, Introduction to Structural Chemistry, Springer, Dordrecht, 2012
Atkins, Physical Chemistry, 6th Ed., Oxford U.
Harrison, Electronic Structure and the Properties of Solids, Freeman, San Francisco, 1980
Online since: November 2011
Authors: Hai Yan Song, Yun Xia Li, Bing Tao Liu
Especially activated sludge, its content of organic matter is high (60%-80%), particles is fine(0.02-0.2nm), density is small(1.002-1.006g ·cm-3), structure is a colloid, and it is a kind of hydrophilic sludge.
As growing awareness of environmental protection, its application will be limited, however, natural, non-toxic, easily biodegradable organic polymer flocculant chitosan will replace the synthetic polymer flocculants, become the focus of attention.Chitosan (CTS) is a weak cationic flocculent, its molecular weight from several hundred thousand to several million range, its structure contains hydroxyl and amino, so determines the chitosan to chelate, electric neutralization, adsorption and bridging role.
Zhao KunLuan, the behavioral differences between polymeric aluminum and traditional coagulants of condensing - flocculation.Environmental chemistry,1997,16(6):497-505 [3] ZhiJie.
Environmental chemistry , 2004,23(3):306-309 [4] PinJingHe, GuoWeiGu, DuZhongLi, treatment and utilization of Urban sludge.
Bingjing: Highter education press, 2004 [6] Lee C H, Liu J C.Sludge dewaterability and floc structure in dual polymer conditioning.
As growing awareness of environmental protection, its application will be limited, however, natural, non-toxic, easily biodegradable organic polymer flocculant chitosan will replace the synthetic polymer flocculants, become the focus of attention.Chitosan (CTS) is a weak cationic flocculent, its molecular weight from several hundred thousand to several million range, its structure contains hydroxyl and amino, so determines the chitosan to chelate, electric neutralization, adsorption and bridging role.
Zhao KunLuan, the behavioral differences between polymeric aluminum and traditional coagulants of condensing - flocculation.Environmental chemistry,1997,16(6):497-505 [3] ZhiJie.
Environmental chemistry , 2004,23(3):306-309 [4] PinJingHe, GuoWeiGu, DuZhongLi, treatment and utilization of Urban sludge.
Bingjing: Highter education press, 2004 [6] Lee C H, Liu J C.Sludge dewaterability and floc structure in dual polymer conditioning.
Online since: August 2011
Authors: Li Min Wang, Xue Song Li, You Yang, Yue Yang, Hua Wu
Properties of electrodeposited Ni-SiC composite coatings on MB8 wrought magnesium alloys
Xuesong Li 1, a, Limin Wang1, b,You Yang1, c, Yue Yang1, d, Hua Wu1, e *
1Key Laboratory of Advanced Structural Materials, Ministry of Education Changchun University of Technology, Changchun 130012, China
2State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China
alixuesong@mailccut.edu.cn, blmwang@ciac.jl.cn, cyangyou@mailccut.edu.cn,
dyangyue@mailccut.edu.cn, ewuhua@mail.ccut.edu.cn,
Keywords: MB8 magnesium alloys, nanocomposite coatings, electrodeposition, corrosion behavior, wear resistance
Abstract: Ni–SiC nanocomposite coatings with reinforcing SiC nano-particulates were prepared by electrodeposition on MB8 wrought magnesium alloys.
Morphology, structure and composition of the coatings were investigated.
X-ray diffraction analysis was employed to characterize the phase structure of the coatings.
It is known that Ni is not an ideal candidate material for wear resistance due to its face-centered cubic structure which will lead to adhesive wear while contacting with other metals.
Electrochimica Acta Vol.50(2005),p.4551 [8]Sheng-Lung Kuo,Yann-Cheng Chen,Ming-Der Ger,Wen-Hwa Hwu.Materials Chemistry and Physics Vol.86(2004),p.5 [9] P.
Morphology, structure and composition of the coatings were investigated.
X-ray diffraction analysis was employed to characterize the phase structure of the coatings.
It is known that Ni is not an ideal candidate material for wear resistance due to its face-centered cubic structure which will lead to adhesive wear while contacting with other metals.
Electrochimica Acta Vol.50(2005),p.4551 [8]Sheng-Lung Kuo,Yann-Cheng Chen,Ming-Der Ger,Wen-Hwa Hwu.Materials Chemistry and Physics Vol.86(2004),p.5 [9] P.
Online since: October 2010
Authors: Mikolaj Szafran, Paulina Bednarek, Tadeusz Mizerski
Saccharides derivatives in shaping of ceramic powders – new monomers and dispersants
BEDNAREK Paulina 1,a, SZAFRAN Mikolaj 1,b, MIZERSKI Tadeusz 1,c
1 Warsaw University of Technology, Faculty of Chemistry, 3 Noakowskiego St.
00-664 Warsaw, Poland
a bednarek@ch.pw.edu.pl, b szafran@ch.pw.edu.pl, c tadeuszm@ch.pw.edu.pl
Keywords: gelcasting, shaping, saccharides, deflocculation, nanoalumina
Abstract.
Introduction The gelcasting, which combines conventional moulding from slips with polymer chemistry, has become recently one of attentively studied forming methods [[] O.O.
Fig. 1b shows the structure of cellulose and the distribution of hydrogen bonds between glucose units.
Similar crosslinked structure and distribution of hydrogen bonds is expected to appear in polymeric network of 3-O-acrylic-D-glucose.
Fig.1 a) Chemical formula of 3-O-acrylic-D-glucose b) Hydrogen bonds in structure of cellulose The glass transition temperature of polymer obtained from 3Oacrylic-D-glucose measured by differential scanning calorimetry DSC is 5,5ºC.
Introduction The gelcasting, which combines conventional moulding from slips with polymer chemistry, has become recently one of attentively studied forming methods [[] O.O.
Fig. 1b shows the structure of cellulose and the distribution of hydrogen bonds between glucose units.
Similar crosslinked structure and distribution of hydrogen bonds is expected to appear in polymeric network of 3-O-acrylic-D-glucose.
Fig.1 a) Chemical formula of 3-O-acrylic-D-glucose b) Hydrogen bonds in structure of cellulose The glass transition temperature of polymer obtained from 3Oacrylic-D-glucose measured by differential scanning calorimetry DSC is 5,5ºC.
Online since: January 2013
Authors: Jian Hang Hu, Juan Qin Li, Wei Hu, Shuang Hui Deng, Hua Wang, Kun Sang
The reason of that temperature difference decreased may be that much porous structure formed after volatile precipitated from surface layer.
Porous structure strengthened heat transfer to inside layer from surface layer.
There is porous structure.
Vol. 86(2005), p.567 [8] Yimin Wu, Zengli Zhao, Haibin Li and Fang He: Journal of Fuel Chemistry and Technology.
Vol. 37(2009), p.427 (in Chinese) [9] Hong Tan, Shurong Wang , Zhongyang Luo and Kefa Cen: Journal of Fuel Chemistry and Technology.Vol.34(2006), p.61 (in Chinese) [10] J .Rath, M.G .Wolfinger, G.
Porous structure strengthened heat transfer to inside layer from surface layer.
There is porous structure.
Vol. 86(2005), p.567 [8] Yimin Wu, Zengli Zhao, Haibin Li and Fang He: Journal of Fuel Chemistry and Technology.
Vol. 37(2009), p.427 (in Chinese) [9] Hong Tan, Shurong Wang , Zhongyang Luo and Kefa Cen: Journal of Fuel Chemistry and Technology.Vol.34(2006), p.61 (in Chinese) [10] J .Rath, M.G .Wolfinger, G.
Online since: March 2013
Authors: Sundaresa V. Subramanian, Cheng Jia Shang, M. Kashif Rehman, Hatem Zurob
Introduction:
Control of hierarchical evolution of morphological and crystallographic structure is the key to obtaining high strength and good toughness at low temperature in higher grade line pipe steels.
Structure-property correlation studies in high niobium ( 0.1wt%Nb) microalloyed steels have underscored the importance of (i) refining the austenite grain size prior to pancaking, (ii) accumulating adequate strain in the pancaked austenite grains to increase the potential nucleation sites for grain refinement of transformation product through phase transformation, and (iii) promoting high density and dispersion of high angle boundaries by phase transformation through control of accelerated cooling and coiling temperature.
Structure-property correlation of niobium microalloyed line pipe steels involves the integration of three processing modules comprising of grain refinement of austenite during roughing and prevention of grain coarsening between roughing and finish rolling ( Module-1), strain accumulation during pancaking of austenite in finish rolling through preventing recrystallization by pinning of boundary by strain induced precipitation of NbC and solute drag effect due to niobium dissolved in the matrix ( Module-2), and control of density and dispersion of high angle boundaries to prevent brittle fracture nucleation through phase transformation of pancaked austenite by accelerated continuous cooling and interrupted hold at coiling temperature ( Module-3).
Atom probe measurements were carried out on API X80 base plate of chemistry containing 0.06 C, 1.7 Mn, 0.095 Nb (all in wt%), produced by Steckle Mill Rolling.
Thus, 0.1wt%Nb addition in the base chemistry design allows adequate solute niobium of 0.04wt% to be present to prevent the boundary break away.
Structure-property correlation studies in high niobium ( 0.1wt%Nb) microalloyed steels have underscored the importance of (i) refining the austenite grain size prior to pancaking, (ii) accumulating adequate strain in the pancaked austenite grains to increase the potential nucleation sites for grain refinement of transformation product through phase transformation, and (iii) promoting high density and dispersion of high angle boundaries by phase transformation through control of accelerated cooling and coiling temperature.
Structure-property correlation of niobium microalloyed line pipe steels involves the integration of three processing modules comprising of grain refinement of austenite during roughing and prevention of grain coarsening between roughing and finish rolling ( Module-1), strain accumulation during pancaking of austenite in finish rolling through preventing recrystallization by pinning of boundary by strain induced precipitation of NbC and solute drag effect due to niobium dissolved in the matrix ( Module-2), and control of density and dispersion of high angle boundaries to prevent brittle fracture nucleation through phase transformation of pancaked austenite by accelerated continuous cooling and interrupted hold at coiling temperature ( Module-3).
Atom probe measurements were carried out on API X80 base plate of chemistry containing 0.06 C, 1.7 Mn, 0.095 Nb (all in wt%), produced by Steckle Mill Rolling.
Thus, 0.1wt%Nb addition in the base chemistry design allows adequate solute niobium of 0.04wt% to be present to prevent the boundary break away.
Online since: June 2014
Authors: Qin Fang Lu, Tao Yang
Study on Preparation of a New-type Catalyst
and its Catalytic Activity
QinFang Lu1, a *, Tao Yang 2,b
1, 2College of chemistry and Environmental Engineering, Jiujiang University, Jiujiang 332005
aLqf161@sohu.com, b470014169@qq.com
Keywords: mesoporous TiO2; visible light; perlite; methylene blue
Abstract: To improve the utilization rate of visible light in the degradation of the dye wastewater, the supported mesoporous TiO2 catalyst with perlite as the carrier was prepared.
Introduction Compared with nanometer TiO2, mesoporous TiO2 possessed the advantages of bigger specific surface and pore volume, better thermo stabilization and hydrothermal stability, well developed and organized pore structure, uniform and adjustable pore diameter, and the property of more convenience to be modified on the surface, for which it was considered as a higher-efficient photocatalytic material[1-3].
If the calcination time was too short, the template was not totally removed, and part of TiO2 was still not crystallized, which would influence the catalytic activity; if the calcination time was too long, although the template had been totally removed, the pore structure of the catalyst would be damaged in the high temperature environment for a long time, which would result in the collapse of the pore aperture, the decrease of the specific surface area and finally the decrease of the catalytic activity.
The optimal calcination time was 1.5 hours, under this condition the degradation rate of the methylene blue solution reached 73.59% in 4 hours; (2) Multi-loading was favorable for the increase of the catalytic activity, and the degradation effect was the optimal under 3 loading times and the porous structure was found in the perlite.
Environmental Chemistry, 26(2007) 735~739
Introduction Compared with nanometer TiO2, mesoporous TiO2 possessed the advantages of bigger specific surface and pore volume, better thermo stabilization and hydrothermal stability, well developed and organized pore structure, uniform and adjustable pore diameter, and the property of more convenience to be modified on the surface, for which it was considered as a higher-efficient photocatalytic material[1-3].
If the calcination time was too short, the template was not totally removed, and part of TiO2 was still not crystallized, which would influence the catalytic activity; if the calcination time was too long, although the template had been totally removed, the pore structure of the catalyst would be damaged in the high temperature environment for a long time, which would result in the collapse of the pore aperture, the decrease of the specific surface area and finally the decrease of the catalytic activity.
The optimal calcination time was 1.5 hours, under this condition the degradation rate of the methylene blue solution reached 73.59% in 4 hours; (2) Multi-loading was favorable for the increase of the catalytic activity, and the degradation effect was the optimal under 3 loading times and the porous structure was found in the perlite.
Environmental Chemistry, 26(2007) 735~739
Online since: October 2014
Authors: Xue Fei Jia, Ning Bu, Shang Gao, Tao Li
It examines the functionality of software by its interfaces without peering into its internal structures.
As black box testing requires no internal structures, it could be used to design a cross-platform system for sensitive data leakage detection.
Jónsson, in: Theoretical Methods in Condencsed Phase Chemistry, edited by S.D.
Schwartz, volume 5 of Progress in Theoretical Chemistry and Physics, chapter, 10, Kluwer Academic Publishers (2000)
Algorithms and Data Structures.
As black box testing requires no internal structures, it could be used to design a cross-platform system for sensitive data leakage detection.
Jónsson, in: Theoretical Methods in Condencsed Phase Chemistry, edited by S.D.
Schwartz, volume 5 of Progress in Theoretical Chemistry and Physics, chapter, 10, Kluwer Academic Publishers (2000)
Algorithms and Data Structures.
Online since: June 2015
Authors: Konstantinos Zekentes, Fernando Lloret, M.P. Villar, L. Liu, Daniel Araujo
Zekentes1,e
1Institute of electronic Structure and Laser, FORTH, Vassilika Vouton, Heraklion, Greece
2Dpto.
To evaluate structure and chemical modifications of their shape, scanning electron microscopy (SEM) and conventional transmission electron microscopy (TEM) is used.
Si and SiC in a core-shell structure [4] has showed technical benefits as high efficiency photoluminescence, it is almost triple than Si nanowires [5].
It seems difficult to obtain monocrystalline Si-SiC core-shell NWs without defects like voids, SFs and low residual doping with the low cost "chemistry-driven" methods used up to now [6].
Looking now to the energy-loss region of the K edge of the carbon (from 280 to 320 eV), the spectra in positions 2-4 show differences in the peaks, indicating chemistry changes.
To evaluate structure and chemical modifications of their shape, scanning electron microscopy (SEM) and conventional transmission electron microscopy (TEM) is used.
Si and SiC in a core-shell structure [4] has showed technical benefits as high efficiency photoluminescence, it is almost triple than Si nanowires [5].
It seems difficult to obtain monocrystalline Si-SiC core-shell NWs without defects like voids, SFs and low residual doping with the low cost "chemistry-driven" methods used up to now [6].
Looking now to the energy-loss region of the K edge of the carbon (from 280 to 320 eV), the spectra in positions 2-4 show differences in the peaks, indicating chemistry changes.
Online since: July 2011
Authors: Feng Feng Li, Ming Xi Zhang, Yi Shen, Du Jiao, Gui Qin Hou, Hong Sheng Li
School of Light Industy, Hebei United University, Tangshan 063000, China
2.Key Laborary for Inorganic Non-metallic Materialogy of Hebei Province, School of Materials Science and Engineering, Hebei United University, Tangshan 063009, China
Keywords: Nanosilica; iron tailing; chemical deposition method; structure
Abstract.
Effect of electrolytes and surfactants on physicochemical properties and porous structure of hydrated silicas Colloids and Surfaces A: Physicochemical and Engineering Aspects, 1997, 125(2-3):121-130
[11] Jin Y H, Li A, Hazelton S G., et a1.Amorphous silica nanohybrids: Synthesis, properties and applications [J].Coordination Chemistry Reviews, 2009, 253(23-24):2998-3014
Effect of electrolytes and surfactants on physicochemical properties and porous structure of hydrated silicas Colloids and Surfaces A: Physicochemical and Engineering Aspects, 1997, 125(2-3):121-130
[11] Jin Y H, Li A, Hazelton S G., et a1.Amorphous silica nanohybrids: Synthesis, properties and applications [J].Coordination Chemistry Reviews, 2009, 253(23-24):2998-3014