Paper Titles
Effects of Freezing and Thawing on the Extraction Yields of Polysaccharides from Corn Pollen
p.3951
Experimental Study on Enzyme Desizing Process of Cold Pile up the Thick Cotton Fabrics
p.3955
Integrating Carbon Footprint into Coordination of Constant Pricing and Lot Sizing Problem
p.3959
Research on Fiber Preparation Section with Life Cycle Assessment Theory
p.3968
Solubility of Benzoic Acid in Ethanol, Benzene, Acetic Acid and Ethyl Acetate from 291.69 to 356.27 K
p.3975
Study of Porcine Blood Decoloration Technique
p.3980
Study on Replacement of EHC Using HVOF Sprayed Coatings
p.3984
Synthesis and Characterization of N-butyl-N-methylimidazolium- D-(-)-tartrate Chiral Ionic Liquid
p.3989
Waste Energy Recovery from a Silicon Smelting Furnace — Technology Design and Economic Analysis
p.3993

Solubility of Benzoic Acid in Ethanol, Benzene, Acetic Acid and Ethyl Acetate from 291.69 to 356.27 K

Article Preview

Abstract:

Using a synthetic method designed and installed with laser monitor on line, the solubility values of benzoic acid in ethanol, benzene, acetic acid and ethyl acetate were determined over the temperature range of 291.69-356.27 K. The solubility of benzoic acid in all cases investigated was found to increase with temperature. The two-parameters empirical and λh equations were used successfully to correlate experimental data of benzoic acid solubilities in organic solvents. The mean absolute error σ of 65 data points correlating by two-parameters empirical equation and λh equation was less than 1%. Finally, molar dissolution enthalpy ΔsolH of benzoic acid in organic solvents was determined with the newly obtained empirical equation parameters.

You might also be interested in these eBooks
Advances in Environmental Science and Engineering View Preview

Info:

Periodical:

Advanced Materials Research (Volumes 518-523)

Pages:

3975-3979

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.518-523.3975

Citation:

Cite this paper

Online since:

May 2012

Authors:

Wen Ting Cheng, Shuo Feng, Xiao Qin Cui, Fang Qin Cheng

Keywords:

Benzoic Acid, Molar Dissolution Enthalpy, Solubility, Two-Parameters Empirical Equation, Λh Equation

Export:

RIS, BibTeX

Price:

Permissions CCC:

Request Permissions

Permissions PLS:

Request Permissions

Сopyright:

© 2012 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

References

[1] J. S. Jin, C. L. Zhong, Z. T. Zhang and Y. Li: Fluid Phase Equilib. Vol. 226 (2004), p.9–23

Google Scholar

[2] O. Sohnel and J. Garside, in: Precipitation: Basic Principles and Industrial Application, Butterworth-Heinemann Publising, Oxford, U. K. (1992)

Google Scholar

[3] R. Mohan and A. S. Myerson: Chem. Eng. Sci. Vol. 57 (2002), p.4277–4285

Google Scholar

[4] H. Sahay, S. Kumar, S. N. Upadhyay and Y. D. Upadhya: J. Chem. Eng. Data Vol. 26 (1981), p.181–183

Google Scholar

[5] D. Q. Li, J. C. Liu, D. Z. Liu and F. A. Wang: Fluid Phase Equilib. Vol. 200 (2002), p.69–74

Google Scholar

[6] J. Thati, F. L. Nordstrom and A. C. Rasmuson: J. Chem. Eng. Data Vol. 55 (2010), p.5124–5127

Google Scholar

[7] Z. B. Li and G. P. Demopoulos: Ind. Eng. Chem. Res. Vol. 45 (2006), p.2914–2922

Google Scholar

[8] Y. Li, L. Xu, F. A. Wang, H. H. Jin and B. Z. Ren: J. Chem. Eng. Data Vol. 55 (2010), p.4098–4103

Google Scholar

[9] H. Stephen and T. Stephen, in: Solubilities of Inorganic and Organic Compounds. Pergamon Press, Oxford, Vol. 1 (1963)

Google Scholar

[10] A. Apelblat and E. Manzurola: J. Chem. Thermodyn. Vol. 33 (2001), p.147–153

Google Scholar

[11] J. Q. Zhu, Y. S. Yu and C. H. He: Fluid Phase Equilib. Vol. 155 (1999), p.85–94

Google Scholar

[12] H. Buchowski, A. Ksiazczak and S. Pietrzyk: J. Phys. Chem. Vol. 84 (1980), p.975–979

Google Scholar

[13] S. K. Tulashie, H. Lorenz and A. Seidel-Morgenstern: Cryst. Growth Des. Vol. 9 (2009), p.2387–2392.

Google Scholar

[14] A. Apelblat and E. Manzurola: J. Chem. Thermodyn. Vol. 31 (1999), p.85–91

Google Scholar