Authors: Jeong Won Yoon, Seung Boo Jung
Abstract: The interfacial reaction between eutectic Sn-3.5Ag solder and ENIG substrate during
reflow was investigated. During the reflow, the topmost Au layer dissolved into the molten solder, and the reaction layers of Ni3Sn4/Ni-Sn-P/Ni3P formed between Sn-Ag solder and Ni-P plating layer. After the reflow at 255 for 3 min, most of Ni3Sn4 intermetallic compound (IMC) spalled off the substrate. The formation of thick Ni3P and Ni-Sn-P layers was related to the direct reaction between
solder and Ni-Sn-P layer by the IMC spalling.
554
Authors: Dae Gon Kim, Sang Su Ha, Seung Boo Jung
Abstract: The interfacial reaction and joint strength of the Pb-free flip chip solder joints were
investigated. Microstructural investigations were conducted using scanning electron microscopy (SEM), and phase analysis of the intermetallic compound (IMC) was carried out using energy dispersive spectrometer (EDS). Cu6Sn5 IMC layer was formed at the as-reflowed state, and Cu3Sn was additionally settled at the interface between the Cu6Sn5 and Cu under bump metallurgy (UBM).
Growth of the IMC layers followed the parabolic law, while the IMC layer growth was not highly affecting the mechanical properties of the solder joints. The shear force of the solder joints decreased because of the microstructural coarsening within the solder region.
550
Authors: Jong Woong Kim, Seung Boo Jung
Abstract: The effects of void formation on the joint strength and failure mode of the solder joints
were examined. A computational modeling technique, i.e., finite element modeling, was employed to investigate the effects. The effects of location, size and number of void were also investigated and compared with the case that has no void in the solder ball. When there was 1 or more voids in the solder ball, the joint strength decreased regardless of the location, size, and number of voids.
Especially, the shear force of the joints decreased about 50% when 3 voids were formed in the solder ball. From the stress analyses, the possibility of preliminary brittle interfacial failure should be lower when voids were formed in the solder ball.
546
Authors: Jeong Won Yoon, Seung Boo Jung
Abstract: The interaction between Cu/Sn-Ag and Sn-Ag/Ni interfacial reactions has been studied
during isothermal aging at 150°C for up to 1000h using a Cu/Sn-3.5Ag/ENIG sandwich solder joint.
A typical scallop-type Cu-Sn intermetallic compound (IMC) layer formed at the upper Sn-Ag/Cu
interface after reflowing. On the other hand, a (Cu,Ni)6Sn5 IMC layer was observed at the
Sn-Ag/ENIG interface. The Cu in the (Cu,Ni)6Sn5 IMC layer formed on the Ni side has to be
contributed from the dissolution of the opposite Cu metal pad or Cu-Sn IMC layer. When the
dissolved Cu arrived at the interface of the Ni pad, the (Cu,Ni)6Sn5 IMC layer formed on the Ni
interface, preventing the Ni pad from reacting with the solder. Although a long isothermal aging
treatment at 150°C was performed, any Ni was not detected in the Cu-Sn IMC layer formed on the Cu
side. Compared to the single Sn-Ag/ENIG solder joint, the formation of the (Cu,Ni)6Sn5 IMC layer of
the Cu/Sn-Ag/ENIG sandwich joint retarded effectively the consumption of the Ni from the
electroless Ni-P layer.
1001
Authors: Jong Woong Kim, Hyun Suk Chun, Sang Su Ha, Jong Hyuck Chae, Jin Ho Joo, Young Eui Shin, Seung Boo Jung
Abstract: Board-level reliability of conventional Sn-37Pb and Pb-free Sn-3.0Ag-0.5Cu solder joints
was evaluated using thermal shock testing. In the microstructural investigation of the solder joints,
the formation of Cu6Sn5 intermetallic compound (IMC) layer was observed between both solders and
Cu lead frame, but any crack or newly introduced defect cannot be found even after 2000 cycles of
thermal shocks. Shear test of the multi layer ceramic capacitor (MLCC) joints were also conducted to
investigate the effect of microstructural variations on the bonding strength of the solder joints. Shear
forces of the both solder joints decreased with increasing thermal shock cycles. The reason to the
decrease in shear force was discussed with fracture surfaces of the shear tested solder joints.
633
Authors: Chang Yong Lee, Won Bae Lee, Yun Mo Yeon, Keun Song, Jeong Hoon Moon, Jung Gu Kim, Seung Boo Jung
Abstract: The microstructure and mechanical properties of spot friction stir welded A 5052 alloy
were investigated with insertion depth of welding tool. As the insertion depth of welding tool
increased, the size of stirring zone increased and the thickness of upper sheet decreased. The value of
shear load was the lowest at the shallowest insertion depth and increased to the highest value of 3.35
kN at a 1.6mm of insertion depth. An increase in the pin insertion depth beyond 1.6mm did not result
in further increase in the lap shear load. Spot friction stir welded joints showed shear fracture mode at
shallower insertion depths and fracture mode changed to plug fracture mode as the insertion depth
was deeper.
345
Authors: Ja Myeong Koo, Seung Boo Jung
Abstract: The interfacial reactions and bump shear properties of the electroplated Sn-37Pb (in wt.%)
solder bumps with the Ni under bump metallization (UBM) were investigated as a function of the
number of reflows. A continuous facetted Ni3Sn4 intermetallic compound (IMC) layer was formed at
the interface between the solder bump and the Ni UBM during reflow. The thickness of the Ni3Sn4
IMC layer was 0.41 μm after 1 reflow, and then the thickness of the IMC layer increased with
increasing the number of reflows. The shear properties of the bumps indicated the maximum values
after 1 reflow, and then decreased with increasing the number of reflows. The fracture surfaces of the
bumps showed ductile failure characteristics after 1 reflow, and then the fraction of the brittle fracture,
induced by the IMC formed at the interface, increased with increasing the number of reflows.
181
Authors: Dae Gon Kim, Hyung Sun Jang, Jong Woong Kim, Seung Boo Jung
Abstract: In the present work, we investigated the interfacial reactions and shear properties between Sn-3.0Ag-0.5Cu flip chip solder bump and Cu UBM after multiple reflows. The quantitative analyses of the intermetallic compound layer thickness as a function of the number of reflows were performed. After six reflows, the reaction product could be distinguished by two intermetallic compounds: Cu3Sn adjacent to the substrate and Cu6Sn5 which was the dominant phase. The thickness of total
intermetallic compound layers increased with the number of reflows. The shear strength value did not significantly change as a function of the number of reflows. Nearly all of the test specimens showed ductile failure mode, and this could be well explained with the results of FEM analyses.
863
Authors: Jong Woong Kim, Sun Kyu Park, Seung Boo Jung
Abstract: Ball shear test was investigated in terms of effects of important test parameters, i.e. shear height and shear speed, with an experimental and non-linear finite element analysis for evaluating the solder joint integrity of area array packages. A Pb-free solder composition was examined in this work: Sn-3Ag-6Bi-2In. The substrate was a common SMD (Solder Mask Defined) type with solder bond pad openings of 460㎛ in diameter. It could be observed that increasing shear height, at fixed shear
speed, has the effect of decreasing shear force, while the shear force increased with increasing shear speed at fixed shear height. Too high shear height could cause some bad effects on the test results such as unexpected high standard deviation values or shear tip sliding from the solder ball surface. The low shear height conditions were favorable for screening the type of brittle interfacial failures or the degraded layers in the interfaces.
851
Authors: Ja Myeong Koo, Young Ho Lee, Sun Kyu Kim, Myung Yong Jeong, Seung Boo Jung
Abstract: The mechanical and electrical properties of the Sn-3.5Ag solder/Cu BGA packages were investigated as a function of number of reflows. A continuous scallop-shaped Cu6Sn5 intermetallic compound (IMC) layer was formed at the solder/Cu interface upon 1 reflow process. After 3 reflows, very thin layer of Cu3Sn IMC was observed at the Cu6Sn5/Cu interface. As the number of reflows increased, the thickness of these IMCs increased with a cube root of reflow time. Shear force slightly increased up to 4 reflows and then gradually decreased with increasing the number of reflows. The maximum shear force was 11.7N when the thickness of the IMC layers was 3.7㎛. The fracture surfaces of all the specimens showed ductile failure characteristics up to 4 reflows, and then the fraction of the brittle IMC fracture increased with the number of reflows. The electrical resistance of the BGA packages increased with the number of reflows.
801