In this work, Fe-Zn coating on copper is obtained by electroless plating. The surface mor -phologies and composition of the coatings has been investigated using scanning electronic microscope (SEM) and energy dispersive spectroscopy(EDS). Corrosion behavior of Fe-Zn coating in3.5% NaCl solution is gaved a further insight. The impedance diagram indicates that corrosion resistance of coating is better. The open circuit potential of Fe-Zn coating is at about -1V. Self-corrosion potential of Fe-Zn coating in 3.5%NaCl solution shifts in the positive direction first and then shifts from -0.622V to -0.603V with increasing heat-treated temperature, while corresponding self-corrosion current decreases at first and then. increases Corrosion resistance of coating is the best when heat-treated temperature is 300°C.