Oxidation Chlorination of Thiophene in Coking Benzene

Min Yan Ling; Hou He Chen

doi:10.4028/www.scientific.net/AMM.130-134.1066

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HomeApplied Mechanics and MaterialsApplied Mechanics and Materials Vols. 130-134Oxidation Chlorination of Thiophene in Coking...

Oxidation Chlorination of Thiophene in Coking Benzene

Abstract:

Thiophene is a typical thiophenenic sulfur compound that exists in coking benzene. In this paper, investigate oxidation chlorination of thiophene in coking benzene. Potassium permanganate was combined with hydrochloric acid for a new KMnO₄/HCl system of oxidation desulfurization. The preliminary results show that the thiophene in the benzene cannot be deep oxidized desulfurization alone potassium permanganate solution even at acetum. The thiophene in the coking benzene could be mostly converted by using KMnO₄/HCl system. In suitable reaction conditions thiophene’s removal rate can reach more than 93%.

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Periodical:

Applied Mechanics and Materials (Volumes 130-134)

Pages:

1066-1069

DOI:

https://doi.org/10.4028/www.scientific.net/AMM.130-134.1066

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Online since:

October 2011

Authors:

Min Yan Ling, Hou He Chen

Keywords:

Coking Benzene, Oxidation Desulfurization, Thiophene

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