MFI Zeolite Membrane from Rice Husk for Biofuels Production

Article Preview

Abstract:

High silica MFI zeolite membrane was synthesized by hydrothermal method at 313 K on asymetri pore structure alpha alumina substrate, utilizing natural rice husk as the sources of silica. The top layer of substrate was about 0.1 µm. The calcination was conducted at 773 K to remove the organic template. This membrane has a good stability at high temperature and in organic solvent. The membrane structure was identified by X-ray diffraction (XRD). The permeation of some pure gases was carried out to detect pinhole or cracking by studying mass transfer mechanism in the membrane. The pervaporation performance of as-synthesized membrane showed good results. This process was able to produce fuel grade bioethanol (99.2%) with the separation factor about 14.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

104-108

Citation:

Online since:

April 2012

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2012 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] Caro, J., Noack, M., Zeolite membranes–Recent developments and progress, Micropor. Mesopor. Mater. 115 (2008) p.215–233.

DOI: 10.1016/j.micromeso.2008.03.008

Google Scholar

[2] Yeung K.L., Wong L., Sun W., et al. Patent Number(s): WO2007095859-A1; US2007280878-A1; CN101389374-A. (2007).

Google Scholar

[3] Mitra, A., Wang, Z., Cao, T., Wang, H., Huang, L., Yan, Y., J. Electrochem. Soc. 149 (2002) B472–B478.

Google Scholar

[4] Haile, T., Nakhla, H., A Novel Zeolite Coating for Protection of Concrete Sewers from Biological Sulfuric Acid Attack, Geomicrobiologi Journal 25 (2008) 322–331.

DOI: 10.1080/01490450802258428

Google Scholar

[5] Bedi, R.S., Beving, D.E., Zanello, L.P., Yan, Y.S., Acta Biomater. 5 (2009) p.3265–3271.

Google Scholar

[6] Pina, M.P., Mallada, R., Arruebo, M., Urbiztondo, M., Navascués, N., de la Iglesia, O., J. Santamaria, Microporous and Mesoporous Materials, Microporous and Mesoporous Materials 144 (2011) p.19–27.

DOI: 10.1016/j.micromeso.2010.12.003

Google Scholar

[7] Prasetyoko, D., Ramli, Z., Endud, S., Hamdan, H., and Sulikowski, B., Conversion of rice husk ash to zeolite beta, Waste Management 26 (2006) p.1173–1179.

DOI: 10.1016/j.wasman.2005.09.009

Google Scholar

[8] Barrer, R.M., 1982. Hydrothermal Chemistry of Zeolites. Academic Press, New York, USA.

Google Scholar

[9] Caro, J., Noack, M., Kölsch, P., Zeolite membranes: from the laboratory scale to technical applications, Adsorpt.J. Int. Adsorpt. Soc. 11 (2005) p.215–227.

DOI: 10.1007/s10450-005-5394-9

Google Scholar

[10] Bhavornthanayod, C., and Rungrojchaipon, P., Synthesis of Zeolite A Membrane from Rice Husk Ash, Journal of Metals, Materials and Minerals, Vol. 19 No. 2 pp.79-83, 2009].

Google Scholar

[11] International Rice Research Institute (IRRI), World Rice Statistics, http: /irri. org/about-rice/world-rice-statistics.

DOI: 10.19103/as.2016.0003.18

Google Scholar

[12] Kapur, P.C. (1985). Production of reactive bio-silica from the combustion of rice husk in a tube-in-basket (TiB) burner. Powder Technol., 44: pp.63-67.

DOI: 10.1016/0032-5910(85)85022-1

Google Scholar

[13] Williams, P.T. and Nugranad N. (2000). Comparison of products from the pyrolysis and catalytic pyrolysis of rice husks. Energy, 25: 493-513.

DOI: 10.1016/s0360-5442(00)00009-8

Google Scholar

[14] Huang, S., Jing, S., Wang, J., Wang, Z., and Jin, Y. (2001). White silica obtained from rice husk in fluidized propellant bed. Powder Technol., 117: 232-238; Park, B.D. (2003).

DOI: 10.1016/s0032-5910(00)00372-7

Google Scholar

[15] Sun, L. and Gong, K. (2001). Silicon-based material from rice husks and their applications. Ind. Eng. Chem. Res., 40: 5, 861-5, 877.

Google Scholar

[16] Liou, T.H. (2004). Preparation and Characterization of nano-strucutred silica from rice husk. Mat. Sci. Eng. A, 364: pp.313-323.

Google Scholar

[17] Khemthong, P., Prayoonpokarach, S., and Wittayakun, J., Synthesis and Characterization of Zeolite LSX from Rice Husk Silica, Suranaree J. Sci. Technol. 14(4) (1997), pp.367-379.

DOI: 10.1007/s11814-008-0142-y

Google Scholar

[18] Jufriadi and Saputra, H., Preparation and Characterization of Zeolite MFI Membrane for Use in Biofuels Purification, in Proceedings of Conference on Engineering Technology Empowerment via R&D (ETERD 2010).

Google Scholar