Preparation and Characterization of Protein-Montmorillonite Composites

Qian Zhu; Dai Mei Chen; Yan Liu; Xu Tao Deng; Hui Li; Zhi Jin Lu

doi:10.4028/www.scientific.net/AMM.184-185.1120

Paper Titles

Preliminary Study in Cross-Linked Gelatin/Alginate Sponges
p.1102

Preparation and Characteristic of the New Magnetic Organic–Inorganic Hybrid Molecularly Imprinted Microsphere Materials
p.1106

Preparation and Characterization of Activated Carbon Fibers from Jute Fibers by Phosphoric Acid Activation
p.1110

Preparation and Characterization of Photocatalytic TiO₂/CdS Nanocomposite Loaded on Multi-Walled Carbon Nanotues (MWCNTs)
p.1114

Preparation and Characterization of Protein-Montmorillonite Composites
p.1120

Preparation and Study to Core-Material of Microcapsule for Textiles Discoloration Finishes
p.1124

Preparation of Nano-CaCO₃/Fast-Growing Poplar Composite by the Diffusion Method
p.1129

Preparation of PVAc Particles by Dispersion Polymerization
p.1134

Preparation of Size and Morphology Controlled Gold Nanoparticles in Micro-Emulsion and in Aqueous
p.1138

HomeApplied Mechanics and MaterialsApplied Mechanics and Materials Vols. 184-185Preparation and Characterization of...

Preparation and Characterization of Protein-Montmorillonite Composites

Abstract:

Protein-montmorillonite composites were prepared by direct and stepwise intercalation of lysozyme(LYZ) into gallery of montmorillonite(MMT), and characterized by X-ray Diffraction (XRD), Thermal Gravimetric Analysis(TGA) and Atomic Force Microscopy(AFM). The direct intercalation experiment showed that with the increase of LYZ/MMT weight ratio from 1:1 to 4:1, the interlayer space of MMT increased from 4.2nm to 6.3nm, and the adsorption amount of lysozyme onto MMT increased from 1.05mg/mg to 1.84mg/mg. While in stepwise intercalation process, the adsorption of LYZ was obviously lower than that in direct intercalation experiment, indicating that the exchange reaction between lysozyme and POP-D2000 was incomplete in the stepwise intercalation reaction.

You might also be interested in these eBooks

Frontiers of Mechanical Engineering and Materials Engineering

View Preview

Info:

Periodical:

Applied Mechanics and Materials (Volumes 184-185)

Pages:

1120-1123

DOI:

https://doi.org/10.4028/www.scientific.net/AMM.184-185.1120

Citation:

Cite this paper

Online since:

June 2012

Authors:

Qian Zhu, Dai Mei Chen, Yan Liu, Xu Tao Deng, Hui Li, Zhi Jin Lu

Keywords:

Composite, Intercalation, Lysozyme, Montmorillonite

Export:

RIS, BibTeX

Price:

Permissions CCC:

Request Permissions

Permissions PLS:

Request Permissions

Сopyright:

Citation:

References

[1] J. Lin, J. C. Wei, T. Y. Juang, W. C. Tsai. Preparation of protein-silicate hybrids from polyamine intercalation of layered Montmorillonite, J. Langmuir. 23 (2007)1995-1999.

DOI: 10.1021/la062013h

Google Scholar

[2] J. H. Choy, S .Y. Kwak, Y. J. Jeong, J. S. Park. Inorganic layered double hydroxides as nonviral vectors, J. Angew. Chem. Int. Ed. 39 (2000) 4041-4045.

DOI: 10.1002/1521-3773(20001117)39:22<4041::aid-anie4041>3.0.co;2-c

Google Scholar

[3] Q. M. Gao, Q. G. Wang, J. L. Shi. Enhanced Catalytic Activity of Hemoglobin in Organic Solvents by Layered Titanate Immobilization, J. Am. Chem. Soc. 126 (2004) 14346-14347.

DOI: 10.1021/ja047224s

Google Scholar

[4] M. H. Baron, M. Revault, S. Servagent-Noinville, J. Abadie, H. Quiquampoix. Chymotrypsin Adsorption on Montmorillonite: Enzymatic Activity and Kinetic FTIR Structural Analysis, J. Colloid Interface Sci. 214 (1999) 319-332.

DOI: 10.1006/jcis.1999.6189

Google Scholar

[5] D.C. Antonio, V. Antonio. Effect of hydroxy-aluminium species on the sorption and interlayering of albumin onto montmorillonite, J. Appl. Clay Sci. 19 (2001) 59-67.

DOI: 10.1016/s0169-1317(01)00047-3

Google Scholar

[6] J. J. Lin, I. J. Chen, C. C. Chou. Critial Conformational Change of Poly (oxypropylene)dimines in layered Aluminosilicate confinement Macromol, J. Rapid Commun. 24 (2003) 492-495.

DOI: 10.1002/marc.200390073

Google Scholar

[7] C. C .Chou, F. S. Shieu, J. J. Lin. Preparation, Organophilicity, and Self-Assembly of Poly(oxypropylene)amine Clay Hybrids, J. Macromolecules. 36 (2003) 2187-2189.

DOI: 10.1021/ma025773h

Google Scholar