Atom Transfer Radical Polymerization of 3-O-Methacryloyl-Diacetone-D-Glucose

Abstract:

Living radical polymerization of 3-O-methacryloyl-diaceton-D-glucose was carried out by the atom transfer radical polymerization (ATRP) method with an alkyl halide/copper-complex system. The effect of initiators, catalysts, ligand, and temperature on polymerization was studied in detail. Under the optimum condition, the time-conversion first-order plot was linear and the polydispersity of giycopolymer is relatively low, indicating that the polymerization is well controlled.

• Periodical: Applied Mechanics and Materials (Volume 189)
• Pages: 3-6
• DOI: https://doi.org/10.4028/www.scientific.net/AMM.189.3
• Online since: July 2012
• Authors: Jian Bo Qu, Hui Hui Shao, Xiao Xiao Zhang
• Keywords: Atom Transfer Radical Polymerization, Glycopolymer, Living Radical Polymerization

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