Photo-Degradation of Acid Red 18 by Using TiO2/SO42- Nanoparticles under UV Light

Jian Feng Wang; Jin Hai Zhao; Xue Xue Liu; Shou Heng Zhang; Dong Yan Wei; Li Han

doi:10.4028/www.scientific.net/AMM.189.52

Paper Titles

Corrosion Behavior of Copper in Halide Solutions
p.36

Research on the Control of Oxide and Nitride Inclusions in Steelmaking
p.40

Recovery of Lubricating Oil for Cold Strip Rolling
p.44

Temperature Sensibility of Epoxy-Matrix Carbon Fiber Smart Layer
p.48

Photo-Degradation of Acid Red 18 by Using TiO₂/SO₄^2- Nanoparticles under UV Light
p.52

The Present Situation and the Development Trend of New Materials Used in Automobile Lightweight
p.58

Effect of Deposition Conditions on the Characterization of Cu(In,Ga)Se₂ Precursor Films by Sputtering Process
p.63

Research of Adsorption Performance of V (V) and Mo (VI) on Collagen Fiber Immobilized Bayberry Tannin
p.69

Extraction Behavior of Rare Earths in Ion Liquid Extraction System Using 1-Butyl-3-Methyl-Imidazolium Hexafluorophosphate and 5,7-Dichloro-8-Hydroxy Quinoline
p.75

HomeApplied Mechanics and MaterialsApplied Mechanics and Materials Vol. 189Photo-Degradation of Acid Red 18 by Using...

Photo-Degradation of Acid Red 18 by Using TiO₂/SO₄^2- Nanoparticles under UV Light

Abstract:

Photocatalyst TiO₂/SO₄^2- nanoparticles were synthesized by sol-gel method via hydrolysis of pure titanium isopropoxide in n-propanol and acetylacetone solution. The hydrolysis rate and condensation rate of titanium isopropoxide were controlled by concentrated sulfuric acid. Its catalytic activities on the photo-degradation of acid red 18 which is acid azo dyes were studied experimentally and theoretically. The catalysts were characterized by XRD (X-ray diffraction), IR (infrared radiation), BET surface area and SEM (scanning electron microscope). The effects of various catalytic degradation factors of nanocrystalline TiO₂/SO₄^2- were discussed in the present paper, which included solution pH, initial concentration of acid red 18, UV irradiation time and the reaction temperature. The results showed that the photo-catalytic activity of this material was obvious signiﬁcantly when pH is 7.0; degradation temperature is 25 °C and irradiation time is 90 minutes for different concentration acid red 18 solutions.

You might also be interested in these eBooks

View Preview

Info:

Periodical:

Applied Mechanics and Materials (Volume 189)

Pages:

52-57

DOI:

https://doi.org/10.4028/www.scientific.net/AMM.189.52

Citation:

Cite this paper

Online since:

July 2012

Authors:

Jian Feng Wang, Jin Hai Zhao, Xue Xue Liu, Shou Heng Zhang, Dong Yan Wei, Li Han

Keywords:

Acid Red 18, Nanoparticle, Photo-Degradation, TiO₂/SO₄^2-

Export:

RIS, BibTeX

Price:

Permissions CCC:

Request Permissions

Permissions PLS:

Request Permissions

Сopyright:

Citation:

References

[1] Y. Yu, C.Y. Jimmy, C. Cho-Yin et al, Enhancement of adsorption and photocatalytic activity of TiO2 by using carbon nanotubes for the treatment of azo dye, Appli. Catal., B. 2005 61 (1-2) 1–11.

Google Scholar

[2] J. Wang, Y.F. Jiang, Z.H. Zhang et al, Investigation on the sonocatalytic degradation of acid red B in the presence of nanometer TiO2 catalysts and comparison of catalytic activities of anatase and rutile TiO2 powders, Ultrason. Sonochem. 2007 14 (5) 545–551.

DOI: 10.1016/j.ultsonch.2006.09.004

Google Scholar

[3] R. Camarillo, J. Rincón, Photocatalytic Discoloration of Dyes: Relation between Effect of Operating Parameters and Dye Structure, Chem. Eng. Technol. 2011 34(10) 1675–1684.

DOI: 10.1002/ceat.201100063

Google Scholar

[4] J. Grzechulska-Damszel, M. Tomaszewska, A.W. Morawski, Integration of photocatalysis with membrane processes for puriﬁcation of water contaminated with organic dyes, Desalination. 2009 241 (1-3) 118-126.

DOI: 10.1016/j.desal.2007.11.084

Google Scholar

[5] S. Mozia, M. Tomaszewska, A. W. Morawski, Photodegradation of azo dye Acid Red 18 in a quartz labyrinth ﬂow reactor with immobilized TiO2 bed, Dyes Pigm. 2007 75 (1) 60-66.

DOI: 10.1016/j.dyepig.2006.05.012

Google Scholar

[6] X.C. Wang, C.Y. Jimmy, P. Liu et al, Probing of photocatalytic surface sites on SO42−/TiO2 solid acids by in situ FT-IR spectroscopy and pyridine adsorption, J. Photochem. Photobiolo., A. 2006 179 (3) 339–347.

DOI: 10.1016/j.jphotochem.2005.09.007

Google Scholar

[7] H.L. Yin, Z.Y. Tan, Y.T. Liao et al, Application of SO42-/TiO2 solid superacid in decontaminating radioactive pollutants, J. Environ. Radioact. 2006 87 (2) 227-235.

DOI: 10.1016/j.jenvrad.2005.11.009

Google Scholar

[8] H. Yang, R. Lu, L. Wang, Study of preparation and properties on solid superacid sulfated titania–silica nanomaterials, Mater. Lett. 2003 57 (5-6) 1190–1196.

DOI: 10.1016/s0167-577x(02)00954-0

Google Scholar