Numerical Study on NO Mechanism during High Temperature Air Combustion of Natural Gas

Article Preview

Abstract:

A full nitric oxide mechanism including thermal NO, prompt NO, N2O intermediate model and NO reduction model through reburning was used to calculate the NO formation during high temperature air combustion of natural gas in industrial furnace. The turbulent transportation was simulated by Reynolds stress model (RSM) and a modified Eddy-Break-Up (EBU) combustion model was applied to model the combustion process. A three-step reaction scheme of the natural gas combustion reaction was considered. Experimental data from published literature was adopted to validate the present models. Numerical results showed that thermal NO formation mechanism and reburning NO reduction mechanism were the dominant NO models. Reburning NO reduction could not be ignored. Prompt NO gave a small contribution to NO emission and the N2O intermediate model for NO formation was of little importance.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

609-614

Citation:

Online since:

July 2012

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2012 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] Tsuji H, Gupta A, Hasegawa T. High Temperature Air Combustion. New York: CRS Press; (2003).

Google Scholar

[2] Wünning JA, Wünning JG. Flameless oxidation to reduce thermal NO-formation. Prog Energy Combust Sci, 1997, 23: 81–94.

DOI: 10.1016/s0360-1285(97)00006-3

Google Scholar

[3] Cavaliere, M. de Joannon, Mild combustion. Prog Energy Combust Sci, 2004, 30: 329–66.

Google Scholar

[4] Choi G, Katsuki M. Advanced low NOX combustion using highly preheated air. Energy Convers Mgmt, 2001, 42: 639-52.

DOI: 10.1016/s0196-8904(00)00074-1

Google Scholar

[5] Dormire J C. Benefits of applying regenerative burner technology to continuous reheat furnace. AISE Steel Technol, 2000, 77: 55-7.

Google Scholar

[6] Mancini M, Weber R, Bollettini U. Predicting NOx emissions of a burner operated in flameless oxidation mode. Proc Combust Institute, 2002, 29: 1155-63.

DOI: 10.1016/s1540-7489(02)80146-8

Google Scholar

[7] Orsino S, Weber R, Bollettini U. Numerical simulation of combustion of natural gas with high-temperature air. Combust Sci Technol, 2002, 168: 1–34.

DOI: 10.1080/00102200108907848

Google Scholar

[8] Yang W, Blasiak W. Mathematical modeling of NO emissions from high-temperature air combustion with nitrous oxide mechanism. Fuel Process Technol, 2005, 86: 943–57.

DOI: 10.1016/j.fuproc.2004.10.005

Google Scholar

[9] Ishii T, Zhang C, Sugiyama S. Numerical simulations of highly preheated air combustion in an industrial furnace. J. Energy Resource Technol , 1998, 120: 276–284.

DOI: 10.1115/1.2795048

Google Scholar

[10] Su Y, Chen C, Su A. Simulation of high temperature air combustion with modified Eddy-Break-Up combustion model. Energy Procedia , 2012, 14: 127-132.

DOI: 10.1016/j.egypro.2011.12.906

Google Scholar

[11] Yang W, Blasiak W. Numerical simulation of properties of a LPG flame with high-temperature air. Int J Thermal Sci, 2005, 44: 973-985.

DOI: 10.1016/j.ijthermalsci.2005.03.001

Google Scholar