Effects of Activating Solution and Liquid/Solid Ratio on Engineering Properties of Metakaolin-Based Geopolymer

Article Preview

Abstract:

In this paper, the metakaolin is used as the raw material with aluminosilicate compounds to produce the geopolymer. The effects of three levels of two major controlling factors, the degree of polymerization of the activating solution (weight ratio of SiO2 to Na2O) of 0.4, 0.7 and 1.0 and the weight ratio of liquid to solid (L/S) of 0.7, 0.85 and 1.00 on the engineering properties of geopolymer are investigated. The experimental results show that, at age of 28 days, the compressive strength increases from the lowest 37.33 MPa (SiO2/Na2O = 0.4 and L/S = 0.7) to the highest 71.21 MPa (SiO2/Na2O = 0.7 and L/S = 0.7). While, the thermal conductivity increases from the lowest 0.39 w/mk (SiO2/Na2O = 0.4 and L/S = 1.0) to the highest 0.761 w/mk (SiO2/Na2O = 1.0 and L/S = 0.7).

You might also be interested in these eBooks

Info:

Periodical:

Pages:

4101-4104

Citation:

Online since:

October 2012

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2012 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] Xu, H. and Van Deventer, J. S. J., "The geopolymerisation of alumino-silicate minerals," International Journal Minerals Process, Vol.59, No. 3 (2000), pp.247-266.

DOI: 10.1016/s0301-7516(99)00074-5

Google Scholar

[2] Davidovits, J., "Geopolymer Chemistry and Applications," Institut Géopolymère, Saint-Quentin, France (2008), pp.19-36.

Google Scholar

[3] Yunsheng, Z. J., Wang, Y. C., Xu, D. L. and Li, S., "Mechanical performance and hydration mechanism of geopolymer composite reinforced by resin," Materials Science and Engineering: A, Vol.527, No. 24-25 (2010), pp.6574-6580.

DOI: 10.1016/j.msea.2010.06.069

Google Scholar

[4] Zhang, Y., Wei, S., and Zongjin, L., "Composition design and microstructural characterization of calcined kaolin-based geopolymer cement," Applied Clay Science, Vol.47, No. 3-4 (2010), pp.271-275.

DOI: 10.1016/j.clay.2009.11.002

Google Scholar

[5] Van Jaarsveld, J. G. S., and Van Deventer, J. S. J., "Effect of the alkali metal activator on the properties of fly ash-based geopolymers," Industrial Engineering Chemical Research, Vol.38, No. 10 (1999), pp.3932-3941.

DOI: 10.1021/ie980804b

Google Scholar

[6] Komnitsas, K., Zaharaki, D. and Perdikatsis, V., "Effect of synthesis parameters on the compressive strength of low-calcium ferronickel slag inorganic polymers," Journal of Hazardous Materials, Vol. 161, No. 2-3 (2009), pp.760-768.

DOI: 10.1016/j.jhazmat.2008.04.055

Google Scholar

[7] Mindess, S., Young, J. F. and Darwin, D., "Concrete," 2nd Edition, Prentice Hall (2002).

Google Scholar