Oxidation Removal of Elemental Mercury from Flue Gas by K2S2O8

Article Preview

Abstract:

The important step for increasing gaseous elemental mercury (Hg0) removal in wet scrubber systems is altering the chemical form of the Hg0 to a water-soluble oxidized species. This work focuses on the removal of elemental mercury from simulated flue gas by aqueous K2S2O8 in a bubble reactor. In the system of K2S2O8 oxidize Hg0, the reaction velocity of K2S2O8 and Hg0 is soon. Reached a higher removal rate after 10min. Increase the concentration of K2S2O8 can remarkably improve the removal rate of Hg0to 85% With the rise of import mercury concentration has increased mercury removal rate to 89.5%.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

1549-1552

Citation:

Online since:

October 2012

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2012 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] R.K. Srivastava, N. Hutson, B. Martin, F. Princiotta, J. Staudt, Control of mercury emissions from coal-fired electric utility boilers, Environ. Sci. Technol. 40 (5) (2006) 1385–1393.

DOI: 10.1021/es062639u

Google Scholar

[2] C. Senior, C.J. Bustard, B. Durham, K. Baldrey, D. Michaud, Status review of mercury control options for coal-firedpower plants, Fuel Process. Technol. 82 (2003) 89–165.

Google Scholar

[3] C.M. Cooney, Mercury control costs drop, Environ. Sci. Technol. 41 (4) (2007) 1061–1062.

Google Scholar

[4] C.E. Romero, Y. Li, H. Bilirgen, N. Sarunac, E.K. Levy, Modification of boiler operating conditions for mercury emissions reductions in coal-fired utility boilers, Fuel (2005) 1–19.

DOI: 10.1016/j.fuel.2005.04.032

Google Scholar

[5] Gibb, W.H., Clarke, F., Mehta, A.K., 2000. The fate of coal mercury during combustion. Fuel Process. Technol. 65, 365–377.

DOI: 10.1016/s0378-3820(99)00104-6

Google Scholar

[6] Paul S. Nolan, Kevin E. Redinger, Gerald T. Amrhein, Gregory A. Kudlac. Demonstration of additive use for enhanced mercury emissions control in wet FGD systems. Fuel Processing Technology 85 (2004) 587– 600.

DOI: 10.1016/j.fuproc.2003.11.009

Google Scholar

[7] Mercedes Dίaz-Somoano, Sven Unterberger, Klaus R.G. Hein. Mercury emission control in coal-fired plants: The role of wet scrubbers. Fuel Processing Technology 88 (2007) 259–263.

DOI: 10.1016/j.fuproc.2006.10.003

Google Scholar

[8] Zhongyang Luo , Changxing Hu, Jinsong Zhou, Kefa Cen. Stability of mercury on three activated carbon sorbents. Fuel Processing Technology 87 (2006) 679 – 685.

DOI: 10.1016/j.fuproc.2005.10.005

Google Scholar

[9] A.P. Jones, J.W. Hoffmann, D.N. Smith, T.J. Feeley, J.T. Murphy, DOE/NETL's phase II mercury control technology field testing program: preliminary economic analysis of activated carbon injection, Environ. Sci. Technol. 41 (4) (2007) 1365–1371.

DOI: 10.1021/es0617340

Google Scholar

[17] JohnW. Graydon, Xinzhi Zhang, DonaldW. Kirk, Charles Q. Jia. Sorption and stability of mercury on activated carbon for emission control. Journal of Hazardous Materials 168 (2009) 978–982.

DOI: 10.1016/j.jhazmat.2009.02.118

Google Scholar