Synthesis and Performance of a Modified Polyether-Type Superplastizer by Hydroxypropylmethyl Cellulose

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Propylmethyl cellulose monoester of maleic acid (MAPMC) was synthesized with Propylmethyl cellulose and Maleic anhydride. A modified polyether-type superplastizer (PES) was prepared from ally polyoxyethylenether, Maleic anhydride, acrylic acid and MAPMC through a free radical polymerization. MAPMC and PES were recorded by FTIR. The fluidity of cement paste were investigated, the hydration process of cement for PES were characterized via Hydration Heat Tester. The results indicate that PES superplastizers can improve the fluidity of mortars and more capable of preventing slump loss, the hydroxy group of PES has no negative impact on cement hydration .

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21-25

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November 2012

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© 2012 Trans Tech Publications Ltd. All Rights Reserved

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[1] Alshamsi, A. M. Efficiency of the use of set-retarding superplasticizers in hot climates. Arab Gulf. J. Sci. Res. 12(1994) 433–448.

Google Scholar

[2] Akin, Altun I., & Yesim, Sert. Utilization of weathered phosphogysum as set retarder in Portland cement. Cem. Concr. Res. 34(2004) 677-680.

DOI: 10.1016/j.cemconres.2003.10.017

Google Scholar

[3] Tzouvalas, G., Dermatas, N., & Tsimas, S. Alternative calcium sulfate-bearing materials as cement retarders Part I. Anhydrite. Cem. Concr. Res. 34(2004) 2113-2118.

DOI: 10.1016/j.cemconres.2004.03.020

Google Scholar

[4] Ozkul H., Saglam A R., Parlak N. The utilization of beet molasses as a retarding and water-reducing admixture for concrete . Cem. Concr. Res. 35(2005)874-882.

DOI: 10.1016/j.cemconres.2004.04.036

Google Scholar

[5] Chandara C., Azizi K., Azizli M., et al. Use of waste gypsum to replace natural gypsum as set retarders in portland cement. Waste Manage. 29(2009)1675-1679.

DOI: 10.1016/j.wasman.2008.11.014

Google Scholar

[6] Grierson L.H., Knight J.C., Maharaj R. The role of calcium ions and lignosulphonate plasticiser in the hydration of cement. Cem. Concr. Res. 35(2005) 631-636.

DOI: 10.1016/j.cemconres.2004.05.048

Google Scholar

[7] Nadif A., Hunkeler D., Käuper P. Sulfur-free lignins from alkaline pulping tested in mortar for use as mortar additives. Bioresour. Technol. 84 (2002)49-55.

DOI: 10.1016/s0960-8524(02)00020-2

Google Scholar

[8] Bensted J., Callaghan I C., Lepre A. Comparative study of the efficiency of various borate compounds as set-retarders of class Goil well cement. Cem. Concr. Res. 21(1991)663-668.

DOI: 10.1016/0008-8846(91)90117-z

Google Scholar

[9] Cheung J., Jeknavorian A., Roberts L. , Silva D. Impact of admixtures on the hydration kinetics of Portland cement. Cem. Concr. Res. 41(2011)1289-1309.

DOI: 10.1016/j.cemconres.2011.03.005

Google Scholar

[10] Vinatier C., Magne, D., Weiss P., C. Trojani, et al. A silanized hydroxypropyl methylcellulose hydrogel for the three-dimensional culture ofchondrocytes. Biomaterials . 26(2005)6643–6651.

DOI: 10.1016/j.biomaterials.2005.04.057

Google Scholar

[11] Vieira M.C., Klemmb D., Einfeldt L., Albrecht G. Dispersing agents for cement based on modified polysaccharides. Cem. Concr. Res. 35(2005)883-890.

DOI: 10.1016/j.cemconres.2004.09.022

Google Scholar

[12] Zhang D. -F., Ju B. -Z., Zhang S. -F., Yang J. -Z. The study on the synthesis and action mechanism of starch succinate half ester as water-reducing agent with super retarding performance. Carbohydr. Polym. 71(2008)80–84.

DOI: 10.1016/j.carbpol.2007.05.020

Google Scholar

[13] Vieira, M. C., Klemm, D., Einfeldt, L. Dispersing agents for cement based on modified polysaccharides. Cem. Concr. Res. 35(2005)883–890.

DOI: 10.1016/j.cemconres.2004.09.022

Google Scholar

[14] Cheng F., Hou Gui-li. Synthesis and properties of sulfonated starch as superplasticizer. Fine Chem. 23(2006)711–716.

Google Scholar