Preparation of PZT Material with Different Zi/Ti Ratio by Sol-Gel Method

Xi Chen

doi:10.4028/www.scientific.net/AMM.238.105

Paper Titles

Research on Comprehensive Utilization of the Tail Ore
p.87

Experimental Study on Mechanical Behavior of Concrete Loading along Path (Constant Stress, Constant Strain, Increasing Strain)
p.91

Robust Statistics Analysis of Proficiency Test Result of Cement Chemical Composition
p.96

Influence of Sludge Content on Compressive Strength of Sintering Sludge-Shale Bricks
p.101

Preparation of PZT Material with Different Zi/Ti Ratio by Sol-Gel Method
p.105

Toughness Properties of Concrete Modified with Water-Borne Polyurethane
p.109

Soil Stabilizer Prepared with Saline Soil and Industrial Solid Wastes
p.118

An Improved Method to Calculate the Direction and Weight in Microplane Constitutive Model
p.121

Experimental Study on Long-Term Exposure of Concrete in Magnesium Sulfate Solution
p.129

HomeApplied Mechanics and MaterialsApplied Mechanics and Materials Vol. 238Preparation of PZT Material with Different Zi/Ti...

Preparation of PZT Material with Different Zi/Ti Ratio by Sol-Gel Method

Abstract:

Lead zirconate titanate powders (PZT) with different Zi/Ti values 52/48, 53/47, 54/46 and 55/45 were prepared by sol-gel technique. The sol was prepared by mixing stable solutions of Zr-nitrate, Pb-acetate and Ti (OC4H9)4 precursors. The decomposition of precursors above 773 K, 923 K and 1073 K for Zi/Ti value equls to 52/48; 53/47 and 54/46; 55/45 leads to the formation of pure perovskite phase, respectively. X-ray diffraction analysis was carried out to confirm the phase formation of PZT. The relationship of synthesis temperature and Zi/Ti ratio value is disscused and it is found that higher synthesis temperature is needed to prepare pure PZT with increasing Zi/Ti ratio.

You might also be interested in these eBooks

Innovation in Civil Engineering, Architecture and Sustainable Infrastructure

View Preview

Info:

Periodical:

Applied Mechanics and Materials (Volume 238)

Pages:

105-108

DOI:

https://doi.org/10.4028/www.scientific.net/AMM.238.105

Citation:

Cite this paper

Online since:

November 2012

Authors:

Xi Chen

Keywords:

PZT, Sol-Gel Method, Zi/Ti Ratio

Export:

RIS, BibTeX

Price:

Permissions CCC:

Request Permissions

Permissions PLS:

Request Permissions

Сopyright:

Citation:

References

[1] C. O. Paiva-Santos, C. F. Oliveira, W. C. Las, et al, Effect of niobia on the crystal structure and dielectric characteristics of Pb(Zr0.45Ti0.55)O3 prepared from polymeric precursor, Materials Research Bulletin, 35 (2000) 15-24.

DOI: 10.1016/s0025-5408(00)00192-6

Google Scholar

[2] M. S. J. Nunes, E. R. Leite, F. M. Pontes, et al, Microstructural and ferroelectric properties of PbZr1−xTixO3 thin films prepared by the polymeric precursor method, Materials Letters, 49 (2001) 365-370.

DOI: 10.1016/s0167-577x(00)00401-8

Google Scholar

[3] Z. C. R. Cho, L. F. Francis, D. L. Polla, Ferroelectric properties of sol–gel deposited Pb(Zr, Ti)O3/LaNiO3 thin films on single crystal and platinized-Si substrates, Materials Letters, 38 (1999) 125–130.

DOI: 10.1016/s0167-577x(98)00145-1

Google Scholar

[4] X. Dai, Z. Xu, D. Viehland, Effect of oxygen octahedron rotations on the phase stability, transformational characteristics, and polarization behavior in the lead zirconate titanate crystalline solution series, Journal of America Ceramic Society, 78 (1995) 2815-2827

DOI: 10.1111/j.1151-2916.1995.tb08059.x

Google Scholar

[5] M. Okada, K. Tominaga, Preparation and properties of (Pb,La)(Zr,Ti)O3 thin-films by metalorganic chemical vapordeposition, Journal of Applied Physics, 71 (1992) 1955–1959.

DOI: 10.1063/1.351190

Google Scholar

[6] D. S. Hagberg, D. A. Payne, Sol–gel Optics, Processing and Applications, Kluwer, Boston, 1994.

Google Scholar

[7] N. Tohge, S. Takahashi, T. Minami, Preparation of PbZrO3－PbTiO3, ferroelecteic thin films by the sol-gel process, Journal of America Ceramic Society, 74 (1991) 67-71.

DOI: 10.1111/j.1151-2916.1991.tb07298.x

Google Scholar