Synthesis of High Solid Content Acrylic-Polyurethane Hybrid Emulsions with Low Viscosity

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Abstract:

The emulsion polymerization of methyl methacrylate (MMA) with butyl acrylate (BA) using aqueous polyurethane dispersion as seed was undertaken to prepare acrylic-polyurethane (PUA) hybrid emulsions with high solid content. The concentrations of the anionic groups were varied by adding different amount of dimethylolpropionic acid (DMPA). The emulsions with a similar bimodal particle size distribution (PSD) were obtained. The viscosity of the emulsions is about 350 mPa.s while the solid content is about 55%.

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41-44

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December 2012

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© 2013 Trans Tech Publications Ltd. All Rights Reserved

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DOI: 10.1021/ma200073d

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