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HomeApplied Mechanics and MaterialsApplied Mechanics and Materials Vols. 275-277A Mn(II) Metal-Organic Framework Constructed from...

A Mn(II) Metal-Organic Framework Constructed from a Tetrahedral Silicon-Cored Ligand

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Abstract:

A novel metal-organic framework, MnCl₂(BIPS)₂•2CH₃OH•2H₂O (1) were synthesized from MnCl2 and a tetrahedral silicon-cored ligand, Me₂Si(p-C₆H₄-imdazol-1-yl)₂ (BIPS) under the slow diffusion method. The structure was determined by single-crystal X-ray diffraction. Complex 1 is a 2D sheet structure constructed from 1D chains with 34-atom metallamacrocycles.

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Applied Mechanics and Materials I

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Periodical:

Applied Mechanics and Materials (Volumes 275-277)

Pages:

2367-2370

DOI:

https://doi.org/10.4028/www.scientific.net/AMM.275-277.2367

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Online since:

January 2013

Authors:

Qing Yu Ma, Rui Fang Guan, Guo Zhong Li, Deng Xu Wang

Keywords:

Imidazole, Metal-Organic Frameworks, Silicon-Cored, Tetrahedral Ligands

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© 2013 Trans Tech Publications Ltd. All Rights Reserved

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