Study of the Damping Properties of an CPE/ZKF/BPSR Organic Nanocomposites

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A novel organic nanocomposite consisting of chlorinated polyethylene (CPE), 2, 2’-methylene-bis-(4-methyl-6-cyclohexylphenol) (ZKF) and 4, 4’-thio-bis-(3-methyl-6-6tert-butyl- phenol) (BPSR) was prepared in this article. It was found that the presence of three-dimensional supra-molecular intermolecular hydrogen-bonding interactions was useful to not only compress and aggregate the molecularly dispersed ZKF and BPSR into nano-scaled particles, but also partially block the generated nanoparticles and effectively prevent them from over aggregation into large particles. The DMA results showed that there was a critical concentration for BPSR. When BPSR content was beyond the critical value, a novel loss peak was observed because of the formation of ZKF-BPSR-rich phase. These may imply that CPE/ZKF/BPSR nanocomposites possessing both high loss peak and controllable loss peak position can be more efficient in damping performance.

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479-482

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January 2013

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© 2013 Trans Tech Publications Ltd. All Rights Reserved

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