Study of the Morphology of Organic Hybrids of Chlorinated Polyethylene and Small Molecular Additives

Abstract:

In this paper, the organic hybrids materials consisting of polarized polymers and small molecules were prepared and the morphology properties were studied by SEM. For CPE/BPSR (60/40) hybrid, the BPSR crystals existed primarily as micro-sized particles, and the particles size distribution was large. The CPE/ZKF (60/40) hybrid was almost in the amorphous state and there was only a small amount of crystallites dispersed in the amorphous phase. Though the interfacial interaction between BPSR particles and CPE matrix was poor, one of the interesting phenomena was observed, when a small amount of BPSR was incorporated into CPE/ZKF hybrid. The domain size of BPSR was dramatically decreased and existed as nano-particles in the CPE/ZKF/BPSR composites. In the case of CPE/ZKF/BPSR composites, the three-dimensional hydrogen-bonding networks could compress and aggregate the molecularly dispersed BPSR into nano-scaled particles.

• Periodical: Applied Mechanics and Materials (Volumes 278-280)
• Pages: 483-486
• DOI: https://doi.org/10.4028/www.scientific.net/AMM.278-280.483
• Online since: January 2013
• Authors: Xin Bo Ding, Tao Liu, Bao Cheng Fu, Jian Han
• Keywords: Crystallization, Morpholoy, Organic Hybrid, Small Molecular Additives

References

[1] Shi X. Y., Bi W. N., Zhao S. G. J Appl Polym Sci 2011, 120: 1121.

[2] Wu, C.; Yamagishi, T.; Nakamoto, Y.; Ishida, S.; Nitta, K. J Polym Sci, Part B: Polym Phys 2000, 38: 2943.

[3] Wu, C. J Polym Sci, Part B: Polym Phys 2001, 39: 23.

[4] Wu, C.; Yamagishi, T.; Nakamoto, Y.; Ishida, S.; Kubota, S.; Nitta, K. J Polym Sci, Part B: Polym Phys 2000, 38: 1496.

[5] Wu, C.; Akiyama, S. J Polym Sci, Part B: Polym Phys 2004, 42: 209.

[6] Liu Q. X., Ding X. B., Yan X. Journal of Applied Polymer Science, 2009, 114(5): 2655.

[7] Zhao X. Y., Cao Y. J., Zou H., et al. J Appl Polym Sci 2012, 123: 3696.