Determination of N-Butyl Pyridine Tetrafluoroborate in Water Using UV–Spectrum

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Abstract:

BP-BF4 ionic liquid is prepared by the double decomposition reaction of BPC and NaBF4. The ionic liquid at room temperature used in the experiment has a significSubscript textant absorption determined by UV spectrum within the range of 200-400nm, the maximum absorption wavelength of BP-BF4 ionic liquid is 256nm. The standard working curve of BP-BF4 ionic liquid is Subscript texty=0.02852x+0.02406 (R=0.99933). The recovery rate of BP-BF4 ionic liquid which is between 99.6% and 102.2%, is measured by standard addition method in water. The quantitative analysis of BP-BF4 ionic liquids in water using ultraviolet spectroscopy is simple, accurate and reliable.

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135-138

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February 2013

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© 2013 Trans Tech Publications Ltd. All Rights Reserved

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[1] A. E. Visser, R. P. Swatloski, K. D. Rogers, Vol, 39 (2000) 3596.

Google Scholar

[2] J. G. Huddleston, R. D, Vol, 16 (1998) 1765.

Google Scholar

[3] A. C. Ronald, A. K. Lowell, E. L. Am. Chem. Soc., Vol, 126 (1979) 1644.

Google Scholar

[4] S. Z. E. Abedin, M. PÖlleth, S. A. Meiss. Green Chemistry, Vol, 9 (2007) 549.

Google Scholar

[5] C . Villagran, R. A. Bartsch. Electroanal Chem. Vol, 588 (2006) 27.

Google Scholar

[6] L. Glasser, Thermochim. Acta., Vol, 421 (2004) 87.

Google Scholar

[7] D. R. McFarlane, J. Sun, J. Golding. Electrochimica Acta., Vol, 45 (2000) 1271.

Google Scholar

[8] M. J. Earle, P. B. McCormac, K. R. Seddon. Green Chem, Vol, 2 (2000) 261.

Google Scholar

[9] D.B. Macleod. Trans. Faraday Soc., Vol, 19 (1923) 38.

Google Scholar

[10] K. R. Seddon. Chem. Technol. Biotech., Vol, 68 (1997) 351.

Google Scholar

[11] S. T. Handy . Current Org. Chem. Vol, 9 (2005) 959.

Google Scholar

[12] G. Carrera, J. Aires-de-Sousa. Green Chem., Vol, 7 (2005) 20.

Google Scholar

[13] P. K. Bhowmik, H. Han, J. J. Cebe. Liquid Crystals, Vol, 30(2003) 1433.

Google Scholar

[14] L. A. Blanchard, D. Hancu, E. J. Beckman Nature, Vol, 399(6731) 28.

Google Scholar

[15] A. E. Visser, R. P. Swatloski, K. D. Rogers. Ind. Eng. Res., Vol, 39 (2000) 3596.

Google Scholar