Nitric Acid Activated Carbon Aerogels for Supercapacitors

Article Preview

Abstract:

The electrochemical performances of resorcinol–formaldehyde-based carbon aerogels can be significantly enhanced by nitric acid activation.FT-IR spectra and SEM images reveal the constitution and morphology of samples .The electrochemical performances of materials were tested by cyclic voltammetry,galvanostatic charge/discharge test ,electrochemical impedance spectroscopy and cyclic test. The results show that activation does not influence the molecular structure of carbon aerogels,which maintains their nano-porous structure. Activation increases the specific capacitance by 50% and improves the conductivity of carbon aerogels,resulting in fenfect cycling stability. So nitric acid activated carbon aerogels is an ideal electrode material for supercapacitors.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

158-164

Citation:

Online since:

February 2013

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2013 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] J.S. Huang, B G. Sumpter,V. Meunier, A Universal Model for Nanoporous Carbon Supercapacitors Applicable to Diverse Pore Regimes, Carbon Materials, and Electrolytes,J. Chem. Eur. J. 2008, 14, 6614-6626.

DOI: 10.1002/chem.200800639

Google Scholar

[2] A. Balducci, R. Dugas, P. Taberna, et al. Passerini. High temperature carbon-carbon supercapacitor using ionic liquid as electrolyte.,J. Power Sources 165 (2007) 922.

DOI: 10.1016/j.jpowsour.2006.12.048

Google Scholar

[3] R. Kotz , M. Carlen, Principles and applications of electrochemical capacitors,J. Electrochimica Acta 45 (2000) 2483-2498.

DOI: 10.1016/s0013-4686(00)00354-6

Google Scholar

[4] Amini, N.; Aguey-Zinsou, K. F.; Guo, Z. X, Processing of strong and highly conductive carbon foams as electrode[J]. Carbon 2011, 49, 3857.

DOI: 10.1016/j.carbon.2011.05.022

Google Scholar

[5] S.U. Kim, K. H. Lee, Carbon nanofiber composites for the electrodes of electrochemical capacitors, J. Chemical Physics Letters 400 (2004) 253-257.

DOI: 10.1016/j.cplett.2004.10.124

Google Scholar

[6] J.B. Wang, X.Q. Yang, D.C. Wu , et al. The porous structures of activated carbon aerogels and their effects on electrochemical performance,J. Journal of Power Sources 185 (2008) 589- 594.

DOI: 10.1016/j.jpowsour.2008.06.070

Google Scholar

[7] Q. XIE, X.L. ZHANG,Q.R. CHEN, et al. Influence of surface modification by nitric acid on the dispersion of copper nitrate in activated carbon,J. NEW CARBON MATERIALS, 2013, 18, 3.

Google Scholar

[8] N.P. Liu; J Shen.; D. Liu, Activated high specific surface area carbon aerogels for EDLCs, Microporous Mesoporous Materials. 2012, 10. 1016/j. micromeso. 2012. 09. 009.

DOI: 10.1016/j.micromeso.2012.09.009

Google Scholar

[9] D.H. LONG, J. ZHANG,J.H. YANG, Preparation and microstructure control of carbon aerogels produced using m-cresol mediated sol-gel polymerization of phenol and furfural, J. New Carbon Materials, 2008, 23(2): 165-170.

DOI: 10.1016/s1872-5805(08)60020-7

Google Scholar

[10] B.S. SHEN, W.J. FENG,J.W. LANG, Nitric Acid Modification of Graphene Nanosheets Prepared by Arc-Discharge Method and Their Enhanced Electrochemical Properties,J. Acta Phys. -Chim. Sin. 2012, 28 (7), 1726-1732.

Google Scholar

[11] D.W. WANG , F. LI , M. LIU , Improved capacitance 0f SBA 一 15 templated mesoporous carbons after modification with ntric acid oxidation,J. NEW CARBON MATERIALS, 2007, 24, 4.

DOI: 10.1016/s1872-5805(08)60002-5

Google Scholar