For Libraries For Publication Open Access Downloads About Us Contact Us
Paper Titles
Analysis and Application of Electronic Instrument Transformer in Digital Substation
p.141
Running Analysis of Substation Integrated Automation System in Unattended
p.145
Study on Effect of Micro-Power System Operation and Market Environment
p.149
Component Characteristic of Lignite Semi-Coke Hydrogasification Residue
p.153
Conversion of Glucose to 5-hydroxymethylfurfural with Tetraethylammonium Bromide and Chromium (III) Chloride as Catalysts
p.157
Simulation Study on Amplitude of the Overhead Line Based on Simulink
p.161
Prediction of Energy Usage Intensity of the Commercial Blocks in the Urban Areas of Taiwan
p.167
Developing an Evaluation Framework for Solar Building from the Viewpoint of Sustainable and Ecological Cities
p.171
Energy Consumption Analysis of Animation-Park in Sino-Singapore Tianjin Eco-City
p.176

Conversion of Glucose to 5-hydroxymethylfurfural with Tetraethylammonium Bromide and Chromium (III) Chloride as Catalysts

Article Preview

Abstract:

Tetraethylammonium bromide (TEAB) and chromium (III) chloride (CrCl3) were used synergistically to catalyze the conversion of glucose to 5-hydroxymethylfurfural (HMF). The effects of solvent, catalyst loading, reaction temperature and reaction time on the HMF yields were investigated. The results indicated that using 70 mol% TEAB and 12 mol% CrCl3 in a 10 wt% fructose solution in N,N-dimethylacetamide (DMAC) gave the highest HMF yield of 72.7 % after 90 min at 120 °C

You might also be interested in these eBooks
Energy Engineering and Environmental Engineering View Preview

Info:

Periodical:

Applied Mechanics and Materials (Volumes 316-317)

Pages:

157-160

DOI:

https://doi.org/10.4028/www.scientific.net/AMM.316-317.157

Citation:

Cite this paper

Online since:

April 2013

Authors:

Hai Yan Zhang, Xue Jun Liu, Ning Ai, Yong Nie, Jian Bing Ji

Keywords:

5-Hydroxymethylfurfural (HMF), Chromium (III) Chloride, Glucose, Tetraethylammonium Bromide

Export:

RIS, BibTeX

Price:

Permissions CCC:

Request Permissions

Permissions PLS:

Request Permissions

Сopyright:

© 2013 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

References

[1] Y. Roman-Leshkov, C.J. Barrett, Z.Y. Liu and J.A. Dumesic, Nature, 447 (2007) 982.

Google Scholar

[2] J.N. Chheda and J.A. Dumesic, Catalysis Today, 123 (2007) 59.

Google Scholar

[3] J.N. Chheda, G.W. Huber and J.A. Dumesic, Angewandte Chemie, 46 (2007) 7164.

Google Scholar

[4] G.W. Huber, J.N. Chheda, C.J. Barrett and J.A. Dumesic, Science, 308 (2005) 1446.

Google Scholar

[5] T. Ståhlberg, S. Rodriguez-Rodriguez, Chemistry-A European Journal,17(2011)1456.

Google Scholar

[6] M. Ohara, A. Takagaki, S. Nishimura and K. Ebitani, Appl Catal a-Gen, 383 (2010) 149.

Google Scholar

[7] Q. Cao, X.C. Guo, J. Guan, X.D. Mu and D.K. Zhang, Appl Catal a-Gen, 403 (2011) 98.

Google Scholar

[8] X.L. Tong and Y.D. Li, ChemSusChem, 3 (2010) 350.

Google Scholar

[9] C. Wang, L. Fu, X. Tong, Q. Yang and W. Zhang, Carbohydr Res, 347 (2012) 182.

Google Scholar

[10] Z.H. Zhang and Z.B. Zhao, Bioresource technology, 102 (2011) 3970.

Google Scholar

[11] X. Qi, M. Watanabe, T.M. Aida and R.L. Smith, Bioresource technology, 109 (2012) 224.

Google Scholar

[12] H. Zhao, J.E. Holladay, H. Brown and Z.C. Zhang, Science, 316 (2007) 1597.

Google Scholar

[13] Z. Yuan, C.C. Xu, S. Cheng and M. Leitch, Carbohydr Res, 346 (2011) 2019.

Google Scholar

[14] C.V. McNeff, D.T. Nowlan, L.C. McNeff, Appl Catal a-Gen, 384 (2010) 65.

Google Scholar

© 2025 Trans Tech Publications Ltd. All rights are reserved, including those for text and data mining, AI training, and similar technologies. For open access content, terms of the Creative Commons licensing CC-BY are applied.
Scientific.Net is a registered trademark of Trans Tech Publications Ltd.