Regeneration Effect of Fluoride-Rich Granular Activated Alumina on Desorption Regent NaOH Solution

Article Preview

Abstract:

As an effective adsorbent, granular activated alumina (GAA) has been widely used in defluoridation. In order to reduce cost and operate environment-friendly, the adsorbent should be regenerated. In this paper, column experiment was done to characterize the fluoride removal properties and to develop an optimal method to regenerate fluoride-rich modified activated alumina (MGAA). The MGAA can be regenerated by utilizing sodium hydroxide solution desorption, deionized water washing and ferric sulfate reactivation and then used for futher defluoride operation. The influence of the concentration of desorption agent (NaOH solution) and desorbing time on desorption rate and the adsorption capacity of regenerated MGAA were studied. The optimal desorption condition was: 1% NaOH solution for desorption agent, desorbing time in 1.5h.In addition, when the regenerated MGAA was used again for column adsorption test, its adsorption capacity reached 94% of that of original sorbent in 1mg/L outlet fluoride concentration.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

653-656

Citation:

Online since:

April 2013

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2013 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] Lv L, He J, Wey M, Duan X, Kinetic studies on fluoride removal by calcined layered double hydroxides,Ind.Eng.Chem.Res. 45 (2006) 8623-8628.

DOI: 10.1021/ie050363d

Google Scholar

[2] Raichur AM, Basu MJ, Adsorption of fluoride onto mixed rare earth oxides, Separation and Purification Technology. 24 (2001) 121-127.

DOI: 10.1016/s1383-5866(00)00219-7

Google Scholar

[3] Turner BD, Binning P, Stipp SLS, Fluoride removal by calcite: Evidence for fluorite precipitation and surface adsorption, Environ. Sci. Technol. 39 (2005) 9561-9568.

DOI: 10.1021/es0505090

Google Scholar

[4] Vaaramaa K, Lehto J, Removal of metals and anions from drinking water by ion exchange, Desalination. 155 (2003) 157-170.

DOI: 10.1016/s0011-9164(03)00293-5

Google Scholar

[5] Joshi SV, Mehta SH, Rao AP, Rao AV, Estimation of sodium fluoride using HPLC in reverse osmosis experiments, Water Treat. 7 (1992) 207-211.

Google Scholar

[6] Simons R, Trace element removal from ash dam waters by nanofiltration and diffusion dialysis, Desalination. 89 (1993) 325-341.

DOI: 10.1016/0011-9164(93)80145-d

Google Scholar

[7] Amor Z, Bariou B , Mameri N, Toky M , Nicolas S, Elmidaoui S, Fluoride removal from brackish water by electrodialysis, Desalination. 133 (2000) 215-223.

DOI: 10.1016/s0011-9164(01)00102-3

Google Scholar

[8] Ruiz T, Persin F, Hichour M, Sandeaux J, Modelisation of fluoride removal in Donnan dialysis, Journal of Membrane Science. 212 (2003) 113-121.

DOI: 10.1016/s0376-7388(02)00489-1

Google Scholar