Optical Properties of Electrodeposited Alumina Thin Films by Using Spectroscopic Ellipsometer

Abstract:

Aluminum oxide thin films are prepared for their potential application as barrier coatings. Electrodeposition method is used for depositing alumina films. All the depositions are carried out at room temperature in the voltage range of 1-5 volts. Reaction time is also varied to observe the changes in the structure and morphology of thin films. Dense films with spherical nanoparticles ~ 200 nm are observed at 3 volts. JA Wollam spectroscopic ellipsometer is used to study the optical properties of thin films. Thickness of around 1 micrometer is observed for all the samples prepared at 3 volts. However, surface roughness was increased from 5 -12 nm by increasing the reaction time from 15 to 60 minutes. Energy band gap of ~ 3.9 eV is observed which is consistent with our previously reported alumina thin films by using sol- gel method. Refractive index of ~ 1.77 is observed at 300 nm. Low Porosity ~ 2.5% was observed for the films prepared at 3 volts for a reaction time of 30 minutes.

• Periodical: Applied Mechanics and Materials (Volume 319)
• Pages: 84-89
• DOI: https://doi.org/10.4028/www.scientific.net/AMM.319.84
• Online since: May 2013
• Authors: Majid Farzana, Riaz Saira, Naseem Shahzad
• Keywords: Alumina, Bandgap, Electro-Deposition, Optical Property, Thickness

References

[1] A.K. Sharma and N. Sridhara: Advances in Space Research Vol. 50 (2012),p.1411

[2] J.C. Williams and E. A. Starke: Acta Matrialia Vol. 51 (2003), p.5775

[3] K. fayazbakhsh and A. Abedian: Advances in Space Research Vol. 45 (2010), p.741

[4] U. Malayoglu, K. C. Tekin, U. Malayoglu and S. Shrestha: Material Science and Engineering A Vol. 528 (2011), p.7451

DOI: 10.1016/j.msea.2011.06.032

[5] A.K. Jha, K. Sreekumar and P.P. Sinha: Journal of Failure Analysis and Prevention Vol. 11 (2011), p.123

[6] Y. Kimoto: IEEE transaction on Nuclear Science Vol. 52 (2005), p.1574

[7] N.N. Jibiri, U.J.U. Nwankwo and M. Kio: Journal of Engineering Science and Technology Vol. 3 (2011), p.6532

[8] J. Konieczny, L.A. Dobrazanski, K. Labisz and J. Duszczyk: Material Processing Technology Vol. 157 (2008), p.718

[9] J. Konieczny, L.A. Dobrzanski, K. Labisz and J. Duszczyk:Journal of Materials Processing Technology Vol. 157–158(2004), p.718

[10] F. Riddar, S. Hogmark andA.K. Rudolphi:Journal of Materials Processing Technology Vol. 212 (2012), p.2272

[11] S. Wernick, R. Pinner and P.G. Sheasby: ASM International, Finishing Publication Ltd., 5th edition (2007) 289-368.

[12] F. Majid, S. Riaz, M.I. Akram, S. Atiq and S. Naseem, Advanced Science Letters, Accepted (2013)

[13] S. Riaz, S. Shamaila, B. Khan and S. Naseem: Surface Review and Letters Vol. 15 (2008) p.681