Thermogravimetric Study of the Effect of Particle Size on the Spontaneous Combustion of Indonesian Low Rank Coal

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Low-temperature oxidation of two Indonesian low rank coals was characterized by Thermogravimetric analysis (TGA). The effect of particle size on the spontaneous combustion of coal was examined. Coals were classified to-599+299, -299+249, -249-150, -150+76 and-76 μm size groups and through non-isothermal method scanned from 24 to 600°C at heating rate 5°C/min with air flow rate 50 mL/min. DTA thermogram shows that the transition temperatures decrease by decreasing the particle size. Furthermore, the weight loss increases by decreasing particle size. It is indicated that the propensity of coal to spontaneous combustion increase with decreasing particle size. The moisture loss activation energy and oxidation activation energy were calculated by an integral method using the Coats-Redfern formula. The results show that the propensity for spontaneous combustion of two coal samples (judged by the activation energy) increases by decreasing particle size.

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101-105

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June 2013

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© 2013 Trans Tech Publications Ltd. All Rights Reserved

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[1] Clemens AH, Matheson TW, Rogers DE. Low temperature oxidation studies of dried New Zealand coals. Fuel 1991;70:215–21.

DOI: 10.1016/0016-2361(91)90155-4

Google Scholar

[2] Krishnaswamy S, Bhat R, Gunn R, Agarwal PK. Low temperature oxidation of coal. Fuel 1996;75:333–43.

DOI: 10.1016/0016-2361(95)00180-8

Google Scholar

[3] Wang H, Dlugogorski BZ, Kennedy EM. Coal oxidation at low temperatures: oxygen consumption, oxidation products, reaction mechanism and kinetic modelling. Prog Energy Combust 2003;29:487–513.

DOI: 10.1016/s0360-1285(03)00042-x

Google Scholar

[4] Wang H, Dlugogorski BZ, Kennedy EM. Pathways for production of CO and CO in low-temperature oxidation of coal. Energy Fuel 2003;17:150–8

DOI: 10.1021/ef020095l

Google Scholar

[5] Pis JJ, Cagigas A, Simon P, Lorenzana JJ. Effect of aerial oxidation of coking xoals on the technological properties of the resulting cokes. Fuel Process Technol 1988;20:307–16.

DOI: 10.1016/0378-3820(88)90029-x

Google Scholar

[6] Song C, Saini AK, Schobert HH. Effects of drying and oxidation of Wyodak subbituminous coal on its thermal and catalytic liquefaction. Spectroscopic characterization and products distribution. Energy Fuel 1994;8:301–12.

DOI: 10.1021/ef00044a003

Google Scholar

[7] Schmal D. Spontaneous heating of stored coal. In: Nelson CR, editor. Chemistry of coal weathering. Amsterdam: Elsevier; 1989. p.133–215

Google Scholar

[8] Xiangliang M., Ruizhi C, Guoguang W, Hongfeng X, Jiamei Z, Zhihua W., Thermogravimetric study of the effect of a PVA oxygen-insulating barrier on the spontaneous combustion of coal. Mining Science and Technology 2010; 20: 0882-0885

DOI: 10.1016/s1674-5264(09)60300-8

Google Scholar