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Research of Arylic-Terminated Hyperbranched Polyester Modified Styrene-Acrylic Emulsion
Abstract:
Hhyperbranched polyester (HBPE) was synthesized with trimethylol propane and 2,2-dimethylol propionic acid, and arylic-terminated hyperbranched polyester (AHBP) was got by modified its terminal groups with maleic anhydride.AHBP used as copolymerization monomer on modification of styrene-acrylic emulsion. Results show that AHBP could be used for emulsion polymerization,with the increase of dosage,gel fraction in the process of polymerization gradually increased,emulsion stability of calcium ions increased nearly three times, viscosity of emulsion most decreased by 29%,and hardness of emulsion film increased by 1 grade from 2B to B.
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380-384
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Online since:
September 2013
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© 2013 Trans Tech Publications Ltd. All Rights Reserved
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