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HomeApplied Mechanics and MaterialsApplied Mechanics and Materials Vol. 431Industrial Fresh Fluorgypsum Catalyzed Beckmann...

Industrial Fresh Fluorgypsum Catalyzed Beckmann Rearrangement of Ketoximes

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Abstract:

Industrial fresh fluorgypsum was found to be an efficient solid acid catalyst (10 % gmmol^-1 loading) for Beckmann rearrangement, which promoted conversion of various ketoximes to the corresponding amides or lactams in toluene at reflux temperature. This is the first example of the application of the fluorgypsum as catalyst in organic synthesis, which opens up a new aspect for the utility of the solid waste fluorgypsum.

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Mechanical Engineering, Industrial Materials and Industrial Electronics

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Periodical:

Applied Mechanics and Materials (Volume 431)

Pages:

14-19

DOI:

https://doi.org/10.4028/www.scientific.net/AMM.431.14

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Online since:

October 2013

Authors:

Jiang Sheng Li*, Yuan Xue, Ce Liu, Wen Jiang, Dong Hua Liu, Yue Qiao, Chen Yu Wang

Keywords:

Amides, Beckmann Rearrangement, Fluorgypsum, Oximes

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© 2013 Trans Tech Publications Ltd. All Rights Reserved

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