Structure Transition and Electrocaloric Effect of Pb(Zr1-xTix)O3 at High Field

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We investigated the structure transition and the electrocaloric effect in PbZr1-xTixO3 (PZT) with x=0.7, 0.8 and 0.9. The results show that 50 MV/m can make the structural transition be a continuous one. When x=0.7, 0.8 and 0.9 at the zero field, the first order structural transition occurs at T0=685, 687, and 698 K, respectively. Upon a strong electric field, the first order structural transition comes to the second one, which leads to lower the change of specific heat. The structural transition temperature is shifted at high temperature with increasing electric field. The maximum electrocaloric effect is present occurs at about 200 K above the corresponding Curie temperature. With increasing composition of Ti, the electrocaloric effect is enlarged, together with increasing structure transition temperatures.

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September 2013

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© 2013 Trans Tech Publications Ltd. All Rights Reserved

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[1] A. S. Mischenko, Q. Zhang, J. F. Scott, W. W. Whatmore, and N. D. Mathur: Science Vol. 311 (2006), p.1270.

Google Scholar

[2] A. S. Mischenko, Q. Zhang, J. F. Scott, W. W. Whatmore, and N. D. Mathur: Appl. Phys. Lett. Vol. 89 (2006), p.242912.

Google Scholar

[3] A. F Devonshire: Philos. Mag. Vol. 40 (1949), p.1040.

Google Scholar

[4] A. F. Devoshire: Philos. Mag., Vol. 42 (1951), p.1065.

Google Scholar

[5] J. Zhang, A.A. Heitmann, S.P. Alpay, G.A. Rossetti. Jr.: J. Mater. Sci Vol 44 (2009), p.5263.

Google Scholar

[6] Yinglong Wang, Tongru Wei, Baoting Liu, Lizhi Zhu, and Guangsheng Fu: Journal of Functional Materials Vol. 7 (2008), p.1115.

Google Scholar