Study on Synthesis and Properties of Spinel Structure Li1+xMn2-xO4 for Lithium Ion-Sieve Precursor

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Abstract:

Spinel structure Li1+xMn2-xO4 materials for lithium ion-sieve precursor were synthesized by high temperature solid state method and their adsorption properties were improved by adjusting the molar ratio of lithium to manganese. The structure, morphology and adsorption performance of the synthetic samples were characterized by XRD, SEM, and lithium ion adsorption experiments. The influences of pH value and adsorption time on adsorption capacity were discussed. The results showed that the Li1.3Mn1.7O4 material had the largest adsorption capacity and it reached up to 24.06 mg·g-1 when the pH value was 12 and the adsorption time was 10 h.

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560-563

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October 2013

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© 2013 Trans Tech Publications Ltd. All Rights Reserved

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