Characterization of Gamma Irradiated Isotactic Polypropylene by Mixtures of Hindered Amine/Organo-Phosphite Stabilizers

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Abstract:

In this work, the effect of γ-irradiation on neat polypropylene (PP) and PP with the stabilizers have been studied by means of wide-angle X-ray diffraction (WAXD) and tensile properties. There is a new reflex 300, β-phase, appeared in irradiated neat PP sample, compared with non-irradiated neat PP sample. When T/S ratio are 0.1 wt%/0.1 wt% and 0.1 wt%/0.3 wt% of PP, the reflex 300 of irradiated PP with different radiation doses all increased. However T/S content is 0.1 wt%/0.5 wt% of PP, the reflex 300 is not appeared. Among the samples which contain stabilizers, the stabilization of PP against γ-irradiation increased, compared with neat PP.

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297-300

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October 2013

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© 2014 Trans Tech Publications Ltd. All Rights Reserved

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[1] A.F. Booth. Sterilization of medical devices. Buffalo Grove, Illinois: Interpharm Press; (1979).

Google Scholar

[2] M. Deng, S.W. Shalaby. J. Appl. Polym. Sci. Vol. 28 (1995), pp.2111-2119.

Google Scholar

[3] M Sturdevant. Plast. Eng. Vol. 47 (1991), pp.27-32.

Google Scholar

[4] S.A.S. Alariqi, A.P. Kumar, R.P. Singh, et al.: Polym. Degrad. Stab. Vol. 91 (2006), pp.2451-2464.

Google Scholar

[5] S.A.S. Alariqi, A.P. Kumar, R.P. Singh, et al.: Polym. Degrad. Stab. Vol. 92 (2007), pp.299-309.

Google Scholar

[6] P.P. Klemchuk, P.L. Horng. Polym. Degrad. Stab. Vol. 34 (1991), pp.333-346.

Google Scholar

[7] A. Shamshad, A.A. Basfar. Radiat. Phys. Chem. Vol. 57 (2000), pp.447-450.

Google Scholar

[8] P. Zipper, S. Djoumaliisky. Macromol. Symp. Vol. 181 (2002), pp.421-426.

Google Scholar

[9] S.V. Meille, S. Bruckner, W. Porzio. Macromolecules. 23 (1990), pp.4114-4121.

Google Scholar

[10] R. Bernstein, S.M. Thornberg, R.L. Clough, et al. Polym. Degrad. Stab. Vol. 93 (2008), pp.854-870.

Google Scholar