Catalytic Pyrolysis of Bamboo Residues for Composite Biochar and Bamboo Oil

Article Preview

Abstract:

This study attempted to recycle bamboo waste, based on catalytic pyrolysis (TiO2 as catalyst), to produce composite TiO2-bamboo charcoal and bamboo oil simultaneously. The yield and characteristics of TiO2-bamboo charcoal were investigated by thermogravimetry, elemental analysis and SEM. The results indicated that the yield of bamboo charcoal decreased with the increase of temperature, and the influence of catalyst was not distinct; after adding TiO2, the H/C and O/C ratios of charcoal were increased from 18.81% and 3.74% to 26.05% and 4.09% respectively, and the particles of TiO2 were adhered to bamboo charcoal with a very porous structure. Using GC-MS, the composition of bamboo oil was analyzed and the results showed that there were about 9-10 compounds with contributed to more than 2% area, and phenol was the most compound detected in all of the samples.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

921-925

Citation:

Online since:

January 2014

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2014 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] Liang, C. Research progress of the utilization of bamboo biomass energy. World bamboo rattan; 8(5)(2010 ), 1-5.

Google Scholar

[2] Jung, S.H., Kang, B.S., Kim, J.S. Production of bio-oil from rice straw and bamboo sawdust under various reaction conditions in a fast pyrolysis plant equipped with a fluidized bed and a char separation system. J. Anal. Appl. Pyrolysis; 82(2)(2008).

DOI: 10.1016/j.jaap.2008.04.001

Google Scholar

[3] Kantarelis, E., Liu, J., Yang, W., et al. Sustainable valorization of bamboo via high-temperature steam pyrolysis for energy production and added value materials. Energy Fuels, 24(11)(2010), 6142-6150.

DOI: 10.1021/ef100875g

Google Scholar

[4] Scurlock, J.M.O., Dayton, D.C., Hames, B. Bamboo: An overlooked biomass resource? Biomass Bioenergy; 19(4)(2000), 229-244.

DOI: 10.1016/s0961-9534(00)00038-6

Google Scholar

[5] Kim, K.H., Kim, T.S., Lee, S.M., et al. Comparison of physicochemical features of biooils and biochars produced from various woody biomasses by fast pyrolysis. Renew Energy, 50(2013), 188-195.

DOI: 10.1016/j.renene.2012.06.030

Google Scholar

[6] Raveendran, K. ,Ganesh, A. ,Khilar, K. C. Influence of mineral matter on biomass pyrolysis characteristics.Fuel; 74(12)(1995), 1812-1822.

DOI: 10.1016/0016-2361(95)80013-8

Google Scholar

[7] Wang, J. ,Zhang M.X. ,Chen M.Q. ,et al.Catalytic effects of six inorganic compounds on pyrolysis of three kinds of biomass.Thermochim. Acta; 44(1)(2006), 110-114.

Google Scholar

[8] Cao X.D., Harris W. Properties of dairy-manure-derived biochar pertinent to its potential use in remediation. Bioresour. Technol 2010; 101, 5222-5228.

DOI: 10.1016/j.biortech.2010.02.052

Google Scholar

[9] Denyes, M.J., Langlois, V.S., Rutter, A., et al . The use of biochar to reduce soil PCB bioavailability to Cucurbita pepo and Eisenia fetida. Sci. Total Environ 2012; 15(437), 6-82.

DOI: 10.1016/j.scitotenv.2012.07.081

Google Scholar

[10] Tan, Z., Xiang, J., Su, S., et al. Enhanced capture of elemental mercury by bamboo-based sorbents. J. Hazard. Mater; 239-240(2012), 160-166.

DOI: 10.1016/j.jhazmat.2012.08.053

Google Scholar

[11] Chuang C.S., Wang, M.K., Ko C.H., et al. Removal of benzene and toluene by carbonized bamboo materials modified with TiO2. Bioresour. Technol; 99(2008), 954-958.

DOI: 10.1016/j.biortech.2007.03.003

Google Scholar

[12] Sun, F.B.; Yu, Y.; Jiang, Z.H., et al. Nano TiO2 modification of bamboo and its antibacterial and mildew resistance performance, Spectroscopy and spectral analysis; 30 (4)(2010): 1056-1060.

Google Scholar

[13] Wang, X., Liu, Y., Hu, Z., et al. Degradation of methyl orange by composite photocatalysts nano-TiO2 immobilized on activated carbons of different porosities. J. Hazard. Mater; 169(1-3, 30)(2009), 1061-1067.

DOI: 10.1016/j.jhazmat.2009.04.058

Google Scholar

[14] Ghani, Wan, A.W.A.K.G., Ayaz, M., Gabriel D.S. et al. Biochar production from waste rubber-wood-sawdust and its potential use in C sequestration: Chemical and physical characterization. Ind. Crops Prod; 44, (2013) 18-24.

DOI: 10.1016/j.indcrop.2012.10.017

Google Scholar

[15] Wang J., Cui Y., Wang Z.Y., et al. Comparison of two sample pretreatment methods for volatile composition analysis of bamboo oil.Food Sci; 32(2011), 198-201.

Google Scholar

[16] Wang, H.F., Wang, J.L., Wang, C. et al. Effect of bamboo vinegar as an antibiotic alternative on growth performance and fecal bacterial communities of weaned piglets. Livest sci; 144(1) (2012), 173-180.

DOI: 10.1016/j.livsci.2011.11.015

Google Scholar